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Mechanical Engineering Faculty Publications
PFSA membranes; PEM fuel cells; Nafion®; membrane; Liquid water; Rubber elasticity; Deformation behavior
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Full-Text Articles in Engineering
Constitutive Response And Mechanical Properties Of Pfsa Membranes In Liquid Water, Ahmet Kusoglu, Yaliang Tang, Melissa Lugo, Anette M. Karlsson, Michael H. Santare, Simon Cleghorn, William B. Johnson
Constitutive Response And Mechanical Properties Of Pfsa Membranes In Liquid Water, Ahmet Kusoglu, Yaliang Tang, Melissa Lugo, Anette M. Karlsson, Michael H. Santare, Simon Cleghorn, William B. Johnson
Mechanical Engineering Faculty Publications
The mechanical properties and swelling behavior of perfluorosulfonic acid (PFSA) membranes in liquid water have been investigated using a custom-built, temperature-controlled water bath. Interestingly, the theoretical models of Mooney-Rivlin and Ogden for rubber elasticity are shown to reproduce the major features of the experimentally obtained stress-strain relationships. In addition, stress relaxation of the membrane subjected to a fixed strain at room temperature fits time-dependent constitutive models used to describe nonlinear rubber elasticity. Thus, the experimental results suggest that even though PFSA is not an elastomer, the constitutive models developed for rubber-like behavior can be used for describing the ex situ …