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Full-Text Articles in Engineering
Electrochemical Conversion Of Methane To Ethylene In A Solid Oxide Electrolyer, Changli Zhu, Shisheng Hou, Xiuli Hu, Jinhai Lu, Fanglin Chen, Kui Xie
Electrochemical Conversion Of Methane To Ethylene In A Solid Oxide Electrolyer, Changli Zhu, Shisheng Hou, Xiuli Hu, Jinhai Lu, Fanglin Chen, Kui Xie
Faculty Publications
Conversion of methane to ethylene with high yield remains a fundamental challenge due to the low ethylene selectivity, severe carbon deposition and instability of catalysts. Here we demonstrate a conceptually different process of in situ electrochemical oxidation of methane to ethylene in a solid oxide electrolyzer under ambient pressure at 850 °C. The porous electrode scaffold with an in situ-grown metal/oxide interface enhances coking resistance and catalyst stability at high temperatures. The highest C2 product selectivity of 81.2% together with the highest C2 product concentration of 16.7% in output gas (12.1% ethylene and 4.6% ethane) is achieved while the methane …
Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu
Size-Controlled Large-Diameter And Few-Walled Carbon Nanotube Catalysts For Oxygen Reduction, Xianliang Wang, Qing Li, Hengyu Pan, Ye Lin, Yujie Ke, Haiyang Sheng, Mark T. Swihart, Gang Wu
Faculty Publications
We demonstrate a new strategy for tuning the size of large-diameter and few-walled nitrogen-doped carbon nanotubes (N-CNTs) from 50 to 150 nm by varying the transition metal (TM = Fe, Co, Ni or Mn) used to catalyze graphitization of dicyandiamide. Fe yielded the largest tubes, followed by Co and Ni, while Mn produced a clot-like carbon morphology. We show that morphology is correlated with electrocatalytic activity for the oxygen reduction reaction (ORR). A clear trend of Fe > Co > Ni > Mn for the ORR catalytic activity was observed, in both alkaline media and more demanding acidic media. The Fe-derived N-CNTs exhibited …
Distributions Of Noble Metal Pd And Pt In Mesoporous Silica, J. Arbiol, A. Cabot, J. R. Morante, Fanglin Chen, Meilin Liu
Distributions Of Noble Metal Pd And Pt In Mesoporous Silica, J. Arbiol, A. Cabot, J. R. Morante, Fanglin Chen, Meilin Liu
Faculty Publications
Mesoporous silica nanostructures have been synthesized and loaded with Pd and Pt catalytic noble metals. It is found that Pd forms small nanoclusters (3–5 nm) on the surface of the mesoporous structure whereas Pt impregnation results in the inclusion of Pt nanostructures within the silica hexagonal pores (from nanoclusters to nanowires). It is observed that these materials have high catalytic properties for CO–CH4 combustion, even in a thick film form. In particular, results indicate that the Pt and Pd dispersed in mesoporous silica are catalytically active as a selective filter for gas sensors.