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High Co2 Permeation Flux Enabled By Highly Interconnected Three-Dimensional Ionic Channels In Selective Co2 Separation Membranes, Lingling Zhang, Nansheng Xu, Xue Li, Siwei Wang, Kevin Huang, William H. Harris, Wilson K. S. Chiu

Faculty Publications

Abatement of CO₂ emissions from existing fossil-fueled power plants is currently the sole near-term solution to stabilize CO₂ concentration in the atmosphere. Separation and capture of CO₂from process streams of these power plants is the first step toward this effort. In this paper, we report a high flux membrane consisting of highly and efficiently interconnected three-dimensional ionic channels prepared from a combined “co-precipitation” and “sacrificial-template” synthesis. The membranes exhibit remarkable CO₂ permeation characteristic, achieving a CO₂ flux density two orders of magnitude higher than other similar systems reported in the literature. The experimental results …