Engineering Commons^™

A Novel Self-Assembled Cobalt-Free Perovskite Composite Cathode With Triple-Conduction For Intermediate Proton-Conducting Solid Oxide Fuel Cells, Hua Tong, Min Fu, Yang Yang, Fanglin Chen, Zetian Tao

Faculty Publications

A traditional composite cathode for proton-conducting solid oxide fuel cells (H-SOFCs) is typically obtained by mixing cathode materials and proton conducting electrolyte of BaCe_0.7Y_0.2Z_r0.1O_3–δ (BZCY), providing chemical and thermal compatibility with the electrolyte. Here, a series of triple-conducing and cobalt-free iron-based perovskites as cathodes for H-SOFCs is reported. Specifically, BaCe_xFe_1–xO_3–δ (x = 0.36, 0.43, and 0.50) shows various contents of two single phase perovskites with an in situ heterojunction structure as well as triple conductivity by tailoring the Ce/Fe ratios. The cell performance with the optimized BaCe_{0.36 …}