Engineering Commons^™

A Bismuth Attack At Grain-Boundaries Of Ceria-Based Electrolytes, Tianrang Yang, Kevin Huang

Faculty Publications

Bismuth is a common additive of commercial silver pastes for enhancing metallization effect; silver paste is also commonly used in high-temperature electrochemical cells as a current collector or contact layer. We here report that the minor amount of bismuth in commercial silver pastes can transport to the interface of electrode/Gd-doped CeO₂ (GDC) electrolyte and seriously corrode grain-boundaries (GBs) of the GDC electrolyte, a commonly used intermediate-temperature electrolyte, causing significant ionic conductivity degradation. A comprehensive electron microscopic analysis reveals that the Bi-corrosion takes place along GBs of GDC electrolyte acting as “washing flux” agent, causing grain separation and thus blocking …

Topological Conduction And Investigation On Multi Occurrence Of Dirac Cone, Mustahseen Mobashwer Indaleeb

Theses and Dissertations

The unique phenomena in acoustic metamaterial at the Dirac-like cone, and at the exceptional spawning ring could transform the field of engineering with multiple new applications that were never possible before. Localized conical dispersion called Dirac cone at the Brillouin Zone boundaries are the well-known phenomena demonstrated by photonics and phononic metamaterials. However, Dirac cone-like dispersion at the center of the Brillouin zone (where wave number, k = 0) [1] is rare and only happens due to accidental degeneracy at finite frequencies in two-dimensional periodic crystals (PCs), with or without microarchitectures. Accidental degeneracies are generally the ‘sweet spots’ where the …

Experimental Investigation Of Two-Phase (Gas/Liquid) Flow In Intermediate Sized, Horizontal And Inclined Pipes, Noble C. Anumbe

Theses and Dissertations

Multiphase flow models and correlations are indispensable tools for the design and operation of vital flow systems that power various industries. The development, validation and tuning of these flow models & correlations depend on the availability of reliable and accurate data. This dissertation reports on an experimental campaign that not only generated crucial two-phase flow data but also evaluated the effect of inclination angle on several flow parameters of interest. The report details the experimental investigation of upward, adiabatic, co-current two-phase (gas/liquid) flow through a 101.6 mm inner diameter (ID) pipe. Experimental data for the investigation were acquired using an …

Ultrasonic Analysis And Tools For Quantitative Material State Awarness Of Engineered Materials, Subir Patra

Theses and Dissertations

The objective of this research is to devise new methods and tools to generate real time awareness of the material state of composite and metallic structures through ultrasonic nondestructive evaluation (NDE) and structural health monitoring (SHM) at its very early stage of failure. To device new methodology it is also important to verify the method through virtual experiments and hence computational NDE is getting popular in the recent years. In this thesis, while experimental methodology is developed to understand the material state at its early stage of failure, a new peridynamic based Peri-Elastodynamic (PED) computational method is also developed for …

Nonlocal Damage Mechanics For Quantification Of Health For Piezoelectric Sensor, Amit Shelke, Anowarul Habib, Umar Amjad, Ullrich Pietsch, Sourav Banerjee

Faculty Publications

In this paper, a novel method to quantify the incubation of damage on piezoelectric crystal is presented. An intrinsic length scale parameter obtained from nonlocal field theory is used as a novel measure for quantification of damage precursor. Features such as amplitude decay, attenuation, frequency shifts and higher harmonics of guided waves are commonly-used damage features. Quantification of the precursors to damage by considering the mentioned features in a single framework is a difficult proposition. Therefore, a nonlocal field theory is formulated and a nonlocal damage index is proposed. The underlying idea of the paper is that inception of the …

Experimental Investigation Of Impact Localization In Composite Plate Using Newly Developed Imaging Method, Mohammad Faisal Haider, Asaad Migot, Md Yeasin Bhuiyan, Victor Giurgiutiu

Faculty Publications

This paper focuses on impact localization of composite structures, which possess more complexity in the guided wave propagation due to the anisotropic behavior of composite materials. In this work, a composite plate was manufactured by using a compression molding process with proper pressure and temperature cycle. Eight layers of woven composite prepreg were used to manufacture the composite plate. A structural health monitoring (SHM) technique was implemented with piezoelectric wafer active sensors (PWAS) to detect and localize the impact on the plate. There were two types of impact event that were considered in this paper (a) low energy impact event …

The Performance Of Syngas-Fueled Sofcs Predicted By A Reduced Order Model (Rom): Temperature And Fuel Composition Effects, Xinfang Jin, Anthony Ku, Atul Verma, Brandon Ohara, Kevin Huang, Surinder Singh

Faculty Publications

An electrochemical reduced order model (ROM) has been developed in this study to simulate the performance of syngas-fueled anode-supported SOFCs with coupled bulk chemical reactions and multi-species gas diffusion in the electrodes. Experimental V-I curves with syngas fuel were used to validate the model to ensure its high fidelity. The model was used to investigate the effects of fuel composition and temperature on the electrochemical performance of the cell, chemical reaction rate and concentration distributions of gaseous species across the anode. The results show that H₂ electro-oxidation dominates the overall cell performance, and that CO contributes to the performance …

Pedestrian Injury Severity Analysis In Motor Vehicle Crashes In Ohio, Majbah Uddin, Fahim Ahmed

Faculty Publications

According to the National Highway Traffic Safety Administration, 116 pedestrians were killed in motor vehicle crashes in Ohio in 2015. However, no study to date has analyzed crashes in Ohio in order to explore the factors contributing to the pedestrian injury severity resulting from motor vehicle crashes. This study fills this gap by investigating the crashes involving pedestrians exclusively in Ohio. This study uses the crash data from the Highway Safety Information System, from 2009 to 2013. The explanatory factors include the pedestrian, driver, vehicle, crash, and roadway characteristics. Both fixed- and random-parameters ordered probit models of injury severity (where …

Uncertainty Evaluation In The Design Of Structural Health Monitoring Systems For Damage Detection, Christine Schubert Kabban, Richard Uber, Kevin Lin, Bin Li, Md Yeasin Bhuiyan, Victor Giurgiutiu

Faculty Publications

The validation of structural health monitoring (SHM) systems for aircraft is complicated by the extent and number of factors that the SHM system must demonstrate for robust performance. Therefore, a time- and cost-efficient method for examining all of the sensitive factors must be conducted. In this paper, we demonstrate the utility of using the simulation modeling environment to determine the SHM sensitive factors that must be considered for subsequent experiments, in order to enable the SHM validation. We demonstrate this concept by examining the effect of SHM system configuration and flaw characteristics on the response of a signal from a …

Optimization Of Microfluidic Chip Fabrication Via Femtosecond Laser Ablation, Kenneth Aycock

Senior Theses

Microfluidic devices have become staple tools in biomedical research and have a promising future as low cost, point-of-care (POC) diagnostic devices. Despite the advancements in microfluidic device technology, the manipulation and fabrication of these systems can be tedious and expensive. Repeatable techniques in which computer-aided designs are translated into microfluidic systems in a matter of minutes are highly desirable both for researchers and manufacturers. Laser ablation of tape substrates has shown promise in producing cost-effective, rapidly manipulable devices, but the work done thus far has utilized continuous wave lasers that perform suboptimally due to the relatively short wavelengths used and …

Highly Efficient Electrochemical Reforming Of Ch4/Co2 In A Solid Oxide Electrolyser, Jinhai Lu, Changli Zhu, Changchang Pan, Wenlie Lin, John P. Lemmon, Fanglin Chen, Chunsen Li, Kui Xie

Faculty Publications

Reforming CH₄ into syngas using CO₂ remains a fundamental challenge due to carbon deposition and nanocatalyst instability. We, for the first time, demonstrate highly efficient electrochemical reforming of CH₄/CO₂ to produce syngas in a solid oxide electrolyser with CO₂ electrolysis in the cathode and CH₄ oxidation in the anode. In situ exsolution of an anchored metal/oxide interface on perovskite electrode delivers remarkably enhanced coking resistance and catalyst stability. In situ Fourier transform infrared characterizations combined with first principle calculations disclose the interface activation of CO₂ at a transition state between a CO …

Atomic Layer Deposition On Porous Materials: Problems With Conventional Approaches To Catalyst And Fuel Cell Electrode Preparation, Tzia Ming Onn, Rainer Küngas, Paolo Fornasiero, Kevin Huang, Raymond J. Gorte

Faculty Publications

Atomic layer deposition (ALD) offers exciting possibilities for controlling the structure and composition of surfaces on the atomic scale in heterogeneous catalysts and solid oxide fuel cell (SOFC) electrodes. However, while ALD procedures and equipment are well developed for applications involving flat surfaces, the conditions required for ALD in porous materials with a large surface area need to be very different. The materials (e.g., rare earths and other functional oxides) that are of interest for catalytic applications will also be different. For flat surfaces, rapid cycling, enabled by high carrier-gas flow rates, is necessary in order to rapidly grow thicker …

An Experimental Study On Static And Dynamic Strain Sensitivity Of Embeddable Smart Concrete Sensors Doped With Carbon Nanotubes For Shm Of Large Structures, Andrea Meoni, Antonella D'Alessandro, Austin Downey, Enrique García-Macías, Marco Rallini, A. Luigi Materazzi, Luigi Torre, Simon Laflamme, Rafael Castro-Triguero, Filippo Ubertini

Faculty Publications

The availability of new self-sensing cement-based strain sensors allows the development of dense sensor networks for Structural Health Monitoring (SHM) of reinforced concrete structures. These sensors are fabricated by doping cement-matrix mterials with conductive fillers, such as Multi Walled Carbon Nanotubes (MWCNTs), and can be embedded into structural elements made of reinforced concrete prior to casting. The strain sensing principle is based on the multifunctional composites outputting a measurable change in their electrical properties when subjected to a deformation. Previous work by the authors was devoted to material fabrication, modeling and applications in SHM. In this paper, we investigate the …

Peri-Elastodynamic Simulations Of Guided Ultrasonic Lamb Waves In Smart Structure With Surface Mounted Pzt, Subir Patra, Hossain Ahmed, Sourav Banerjee

Faculty Publications

Peridynamic based elastodynamic computation tool named Peri-elastodynamics is proposed herein to simulate the three-dimensional (3D) Lamb wave modes in materials for the first time. Peri-elastodynamics is a nonlocal meshless approach which is a scale-independent generalized technique to visualize the acoustic and ultrasonic waves in plate-like structure, micro-electro-mechanical systems (MEMS) and nanodevices for their respective characterization. In this article, the characteristics of the fundamental Lamb wave modes are simulated in a sample plate-like structure. Lamb wave modes are generated using a surface mounted piezoelectric (PZT) transducer which is actuated from the top surface. The proposed generalized Peri-elastodynamics method is not only …

Multiscale Deformation And Failure Behavior Of Polymer Bonded Explosives Subjected To High Rate Loading, Suraj Muthiramalil Ravindran

Theses and Dissertations

Polymer bonded explosives (PBX) are heterogeneous granular composites with a high-volume fraction of solid. Typically, they contain 80-95% explosive crystals and 5- 20% soft polymer binder. These materials are subjected to different loading conditions during their service life. The main function of the soft binder is to reduce shock sensitivity to prevent an accidental explosion. However, there have been inadvertent detonations in these materials during transportation and handling. The reason for such unintentional explosion is not well understood. It is commonly accepted that the formation of local hightemperature regions, called ‘hot spots’, is the primary cause. Hotspot formation is associated …

Fundamentals Of Srcoo3 Based Oxygen-Deficient Perovskites As Cathodes For Solid Oxide Fuel Cells, Tianrang Yang

Theses and Dissertations

The local structure and oxygen stoichiometry in oxide systems have a profound impact on oxygen electrocatalysis encountered in metal-air batteries and solid oxide fuel cells (SOFCs). However, this knowledge is often obtained under conditions different from the real working conditions of the material, resulting in misinterpretation and misunderstanding. This PhD dissertation aims to obtain the structure and oxygen stoichiometry information of a class of perovskite oxides under their real working conditions in solid oxide fuel cells. Several perovskite oxides were selected for the study: Sr0.9Y0.1CoO3- (SYC10), Sr0.9Y0.3CoO3- (SYC30), SrCo0.9Nb0.1O3- (SCN10) and SrCo0.9Ta0.1O3- (SCT10). The local crystal structure and oxygen stoichiometry …

Monitoring The Progress Of Damage In A Sicf-Sicm Composite Nuclear Fuel Cladding Under Internal Pressure Using Acoustic Emission, Luis H. Alva

Theses and Dissertations

The relation between the progress of damage and the acoustic emission (AE) activity of a nuclear grade Sif-SiCm composite tubing under internal pressure was studied. The nuclear grade Sif-SiCm composite tubing is manufactured by the company General Atomics (GA) and made of nuclear grade HI Nicalon type S fiber preforms following a chemical vapor infiltration (CVI) technique. Sif-SiCm composites are good candidates to replace current nuclear fuel cladding materials because of the good chemical stability and strength at high temperatures. In this work, a Sif-SiCm composite tubing was tested under internal pressure at room temperature (RT) to study the damage …

Combustion Behavior Of Sub-Millimeter Sized Oxygenated And N-Alkane Fuel Droplets, Mohammad Fahd Ebna Alam

Theses and Dissertations

The primary scientific explorations of this thesis work are to better understand (a) microgravity fire-suppression of untested extinguisher, (b) combustion kinetic model refinement of renewable fuel butanol (C4H9OH) isomers, and (c) directly induced cool flame dynamics of higher n-alkane fuels from an isolated small droplet combustion perspective employing computational fluid dynamics with comprehensive chemical kinetics. The chronological development of the research direction shifts from a relatively small fuel like methanol (CH3OH) to heavier straight paraffinic fuel n-decane (n-C10H22). The first installment of the thesis is directed towards answering the feasibility of thennewly considered fire suppressant xenon (Xe) for microgravity space …

Enhance Flow Boiling In Microchannels By Regulating Two-Phase Transport Patterns, Wenming Li

Theses and Dissertations

Flow boiling in microchannels is one of the most promising cooling techniques for microelectronics. Using latent heat by vaporization can significantly improve heat dissipation of high power density electronic devices. Most of the failure of electronic devices is induced by the occurrence of critical heat flux (CHF), which defines the maximum operating conditions. However, the vigorous rapid generation of vapor through phase change leads to chaotic two-phase flows in microchannels, resulting in flowinstability in terms of severe flow, temperature and pressure drop fluctuations. Particularly, the very well-known bubble confinement exacerbates the two-phase flow instabilities and greatly deteriorates heat transfer performance …

Manufacturing Feature Recognition With 2d Convolutional Neural Networks, Yang Shi

Theses and Dissertations

Feature recognition is a critical sub-discipline of CAD/CAM that focuses on the design and implementation of algorithms for automated identification of manufacturing features. The development of feature recognition methods has been active for more than two decades for academic research. However, in this domain, there are still many drawbacks that hinder its practical applications, such as lack of robustness, inability to learn, limited domain of features, and computational complexity. The most critical one is the difficulty of recognizing interacting features, which arises from the fact that feature interactions change the boundaries that are indispensable for characterizing a feature. This research …

High Temperature Compression Creep Of U3si2, Emil Angelo Cahanap Mercado

Theses and Dissertations

As a result of the Fukushima Daiichi Nuclear Disaster in 2011, a push for increasing the safety of nuclear power plants was made through research grants funded through the United States Department of Energy via the Accident Tolerant Fuels (ATF) campaign. One of the focuses of the campaign is improving the accident tolerance of nuclear fuel during a loss of coolant accident.

A promising set of being researched from the ATF is Silicon Carbide (SiC) composite cladding and Uranium Silicide (U3Si2) fuel pellets. Under high temperatures, stresses, and times the creep deformation can play an important factor in pellet to …

System Optimization And Material Development Of Solid Oxide Cells For Energy Conversion And Storage, Libin Lei

Theses and Dissertations

Solid oxide cells (SOCs) can convert chemical energy to electricity in the fuel cell mode and store electricity to chemicals in the electrolysis mode. However, there are still critical barriers, such as energy efficiency and durability, for the development and commercialization of SOCs. The objective of this dissertation is to apply system optimization and materials design to address the critical barriers for solid oxide cells in energy conversion and energy storage applications. One major focus of the dissertation is related to improve energy efficiency, enhance the cell performance and achieve multifunctionality in solid oxide electrolysis cells (SOECs). In addition, development …

Analysis Of Pellet-Cladding Mechanical Interaction On U3si2 Fuel With A Multi-Layer Sic Cladding Using Bison, Ray A. Freeman

Theses and Dissertations

U3Si2 is currently being considered as a possible replacement for the current light water reactor fuel, UO2. U3Si2’s high melting temperature, high uranium density, and high thermal conductivity are favorable in accident conditions, such as a loss of coolant accident. Improved accident performance is further expected when paired with a SiC/SiC cladding, since it provides relatively high strength and a high oxidation resistance.

Modeling of U3Si2 and SiC/SiC in reactor is currently very important since much of their behavior is still unknown. By implementing models that describe the properties of U3Si2 and SiC/SiC into INL’s fuel performance code BISON, performance …

Physics-Based Approaches For Structural Health Monitoring And Nondestructive Evaluation With Ultrasonic Guided Waves, Md Yeasin Bhuiyan

Theses and Dissertations

The engineering infrastructures have a growing demand for damage monitoring systems to avoid any potential risk of failure. Proper damage monitoring solutions are of a great interest to this growing demand. The structural health monitoring (SHM) and nondestructive evaluation (NDE) offer appropriate online and offline damage monitoring solutions for a variety of mechanical and civil infrastructures that includes unmanned aerial vehicles (UAV), spaceships, commercial aircraft, ground transportation, wind turbines, nuclear spent fuel storage tanks, bridges, naval ships, and submarines. The fundamentals of the ultrasonic SHM and NDE consist of multi-disciplinary fields. The dissertation addresses SHM and NDE using ultrasonic guided …

Effect Of Weak Adhesion Interface On Mechanical And Dielectric Properties Of Composite Materials, Prashant Katiyar

Theses and Dissertations

Interfaces are often the most critical part of the heterogeneous materials and their structures. Such interfaces appear a multiple length scales and significantly affect bulk properties in different material systems. Fiber reinforced composite materials are one such example of heterogeneous materials with interfaces at constituent scale (fiber-matrix interface and interphase) to laminate scale (secondary adhesive joints). Manufacturing induced defects and subsequent in-service damage at these interfaces can severely affect the durability of fiber reinforced laminated composite materials and their joints. In addition to lamination process, defects can also form during secondary joining process (e.g., adhesive bonding and repair) which can …

Effect Of Material Orientation On The Impact Response Of Graded Cellular Materials, Abigail Wohlford

Theses and Dissertations

In this study, the effect of layer stacking on the energy absorption characteristics of density-graded cellular polymers subjected to high velocity impact is investigated experimentally. The focus in the present work is to characterize the constitutive response and deformation mechanisms of these Functionally Graded Foam Materials (FGFM) using full-field measurements. Uniform foam Quasi-static and dynamic testing of uniform foam specimens are completed for each nominal density used in the layered foam samples. The low strain-rate experiments are performed in order to determine the mechanical properties of foam specimens. The high-rate experiments for homogenous foam specimens were completed to further characterize …

Characterization Of Evaporation/Condensation During Pool Boiling And Flow Boiling, Mostafa Mobli

Theses and Dissertations

Present dissertation has investigated pool and flow boiling and their characteristics via numerical means. A code was developed to investigate and enhance heat transfer performance during different modes of phase change phenomena. Multiphase heat transfer has proven to be one of the most effective means of heat transfer in different industries, therefore, there have been numerous experimental and numerical studies on the subject of phase change phenomena in a wide range of conditions and setups; yet there are complex bubble dynamics and heat transfer characteristics that remain unresolved. To have a more detailed look at and a better understanding of …

Acousto-Ultrasonic Shm/Nde Methods Toward Field Application, Stephen Harris Howden

Theses and Dissertations

Acousto-ultrasonic nondestructive evaluation (NDE) and structural health monitoring (SHM) methods offers solutions in damage detection, material properties evaluation and more. These ultrasonic waves can propagate through solids and interact with structural features and discontinuities. In this thesis use of several acousto-ultrasonics NDE/SHM methods were explored to evaluate their sensing and detection capabilities toward damage detection field applications in nuclear and aerospace industries.

For nuclear applications, passive sensing using piezoelectric sensors and acoustic emission (AE) techniques were explored on the spent fuel dry storage casks. Dry storage casks are used in the nuclear industry to transport or store spent nuclear fuel …

The Mechanical Properties And Deformation Behavior Of Heat Treated Versus As-Received Inconel X-750, Christopher Marsh

Theses and Dissertations

X-750 is a nickel-chromium based super alloy of usefulness in a wide variety of applications such as gas turbines, rocket engines, nuclear reactors, pressure vessels, tooling, and aircraft structures. Its good mechanical properties are due to the strengthening from precipitation of γ′ particles upon prior ageing heat treatment. In this work, the effect of such heat treatment on the mechanical properties, tensile behavior, and fracture mechanisms of X-750 was studied at various temperatures by comparing it with a non-aged, solution annealed X-750. Tensile tests were conducted from room temperatures up to 900 °C at three separate strain rates (10-3, 10-4, …

Structural Health Monitoring Using Ultrasonic Guided Waves And Piezoelectric Wafer Active Sensors, Faisal Haider Mohammad

Theses and Dissertations

This dissertation is organized in three major parts covering ardent and challenging research topics in structural health monitoring (SHM). Part I focuses on the theoretical and numerical analysis of acoustic emission (AE) guided waves in both Cartesian coordinates (2D) and cylindrical coordinates (3D) system using energy approach, which, to the best of our knowledge, has not been yet reported elsewhere. AE guided waves appear due to sudden energy release during incremental crack propagation in a plate. The Helmholtz decomposition approach is applied to the inhomogeneous elastodynamic Navier-Lame equation for both the displacement field and body forces. For the displacement field, …