Engineering Commons^™

Enhanced Reversibility And Durability Of A Solid Oxide Fe–Air Redox Battery By Carbothermic Reaction Derived Energy Storage Materials, Xuan Zhao, Xue Li, Yunhui Gong, Kevin Huang

Faculty Publications

The recently developed solid oxide metal–air redox battery is a new technology capable of high-rate chemistry. Here we report that the performance, reversibility and stability of a solid oxide iron–air redox battery can be significantly improved by nanostructuring energy storage materials from a carbothermic reaction.

Cyclic Durability Of A Solid Oxide Fe-Air Redox Battery Operated At 650°C, Xuan Zhao, Yunhui Gong, Xue Li, Nansheng Xu, Kevin Huang

Faculty Publications

The recently developed rechargeable solid oxide metal-air redox battery has shown a great potential for applications in mid- to large-scale stationary energy storage. Cyclic durability is one of the most important requirements for stationary energy storage. In this study, we report the cyclic durability of a solid oxide Fe-air redox battery operated at 650°C. The battery was continuously cycled 100 times under a current density of 50 mA/cm² with rather flat performance, producing an average specific energy of 760 Wh/kg-Fe at a round-trip efficiency of 55.5%. The post-test examination indicated that the performance losses could arise from the fuel-electrode …

A High Energy Density All Solid-State Tungsten-Air Battery, Xuan Zhao, Xue Li, Yunhui Gong, Nansheng Xu, Kevin Gregory Romito, Kevin Huang

Faculty Publications

An all solid-state tungsten–air battery using solid oxide–ion electrolyte is demonstrated as a new chemistry for advanced energy storage. The unique design of separated energy storage from the electrodes allows for free volume expansion–contraction during electrical cycles and new metal–air chemistry to be explored conveniently.

A New Class Of Solid Oxide Metal-Air Redox Batteries For Advanced Stationary Energy Storage, Xuan Zhao

Theses and Dissertations

Cost-effective and large-scale energy storage technologies are a key enabler of grid modernization. Among energy storage technologies currently being researched, developed and deployed, rechargeable batteries are unique and important that can offer a myriad of advantages over the conventional large scale siting- and geography- constrained pumped-hydro and compressed-air energy storage systems. However, current rechargeable batteries still need many breakthroughs in material optimization and system design to become commercially viable for stationary energy storage.

This PhD research project investigates the energy storage characteristics of a new class of rechargeable solid oxide metal-air redox batteries (SOMARBs) that combines a regenerative solid oxide …