Engineering Commons^™

Formulation And Aerosol Jet Printing Of Nickel Nanoparticle Ink For High-Temperature Microelectronic Applications And Patterned Graphene Growth, Nicholas Mckibben, Michael Curtis, Olivia Maryon, Mone’T Sawyer, Maryna Lazouskaya, Josh Eixenberger, Zhangxian Deng, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Aerosol jet printing (AJP) is an advanced manufacturing technique for directly writing nanoparticle inks onto target substrates. It is an emerging reliable, efficient, and environmentally friendly fabrication route for thin film electronics and advanced semiconductor packaging. This fabrication technique is highly regarded for its rapid prototyping, the flexibility of design, and fine feature resolution. Nickel is an attractive high-temperature packaging material due to its electrical conductivity, magnetism, and corrosion resistance. In this work, we synthesized nickel nanoparticles and formulated an AJP ink, which was printed on various material surfaces. Thermal sintering experiments were performed on the samples to explore the …

Exploring Methods For Recycling Filament Waste In 3d Printing, Max Rios Carballo

Publications and Research

The goal of the current study is to investigate cutting-edge techniques for recycling filament waste from 3D printing procedures. Appropriate waste management techniques are required to reduce this trash's harmful environmental consequences. The goal of the project is to look at new methods for recycling filament waste in order to minimize disposal and encourage reuse. To acquire data from pertinent papers and research, a thorough literature review methodology was used. The findings show that this issue may be resolved utilizing a variety of recycling techniques, including shredding, melting, and re-extrusion. The type of filament waste and the intended goal will …

Oblique Packing And Tunable Excitonic Coupling In Dna-Templated Squaraine Rotaxane Dimer Aggregates, Matthew S. Barclay, Christopher K. Wilson, Simon K. Roy, Olga A. Mass, Azhad U. Chowdhury, Jonathan S. Huff, Daniel B. Turner, Paul H. Davis, Bernard Yurke, William B. Knowlton, Jeunghoon Lee, Ryan D. Pensack

Materials Science and Engineering Faculty Publications and Presentations

When molecules are aggregated such that their excited states form delocalized excitons, their spatial arrangement, or packing, can be coarsely controlled by templating and finely controlled by chemical substitution; however, challenges remain in controlling their packing on intermediate length scales. Here, we use an approach based on mechanically interlocked molecules to promote an elusive oblique packing arrangement in a series of three squaraine rotaxane dimers. We template the squaraine rotaxane dimers using DNA and observe two excitonically split bands of near-equal intensity in their absorption spectra – a distinct signature of oblique packing, validated by theoretical modeling of the experimental …

Influence Of Hydrophobicity On Excitonic Coupling In Dna-Templated Indolenine Squaraine Dye Aggregates, Olga A. Mass, Christopher K. Wilson, German Barcenas, Lan Li, Bernard Yurke, William B. Knowlton, Ryan D. Pensack, Jeunghoon Lee

Materials Science and Engineering Faculty Publications and Presentations

Control over the strength of excitonic coupling in molecular dye aggregates is a substantial factor for the development of technologies such as light harvesting, optoelectronics, and quantum computing. According to the molecular exciton model, the strength of excitonic coupling is inversely proportional to the distance between dyes. Covalent DNA templating was proved to be a versatile tool to control dye spacing on a subnanometer scale. To further expand our ability to control photophysical properties of excitons, here, we investigated the influence of dye hydrophobicity on the strength of excitonic coupling in squaraine aggregates covalently templated by DNA Holliday Junction (DNA …

Anisotropic Plasticity Modeling Of Thin Sheets And Its Application To Micro Channel Forming Of Steel Foils, Jie Sheng

Mechanical Engineering Research Theses and Dissertations

Thin sheet metals and ultrathin metal foils produced by industrial rolling processes are textured polycrystalline materials and their mechanical behaviors may depend strongly on the orientation of applied loading. Consideration of such plastic anisotropy in advanced modeling of these materials is of the paramount importance in designing optimal manufacturing processes for automotive and other applications using finite element methods. This research addresses several critical issues in anisotropic plasticity modeling and its applications in analyzing micro channel forming of ultrathin stainless-steel foils. An experimental study has first been carried out on the accuracy and sensitivity of measuring the plastic strain ratios …

First-Principles Studies Of Substituent Effects On Squaraine Dyes, German Barcenas, Austin Biaggne, Olga A. Mass, Christopher K. Wilson, Ryan D. Pensack, Jeunghoon Lee, William B. Knowlton, Bernard Yurke, Lan Li

Materials Science and Engineering Faculty Publications and Presentations

Dye molecules that absorb light in the visible region are key components in many applications, including organic photovoltaics, biological fluorescent labeling, super-resolution microscopy, and energy transport. One family of dyes, known as squaraines, has received considerable attention recently due to their favorable electronic and photophysical properties. In addition, these dyes have a strong propensity for aggregation, which results in emergent materials properties, such as exciton delocalization. This will be of benefit in charge separation and energy transport along with fundamental studies in quantum information. Given the high structural tunability of squaraine dyes, it is possible that exciton delocalization could be …

Rehology And Electrical Conductivity Of Particulate Composites In Additive Manufacturing, Bin Xia

Mechanical Engineering Research Theses and Dissertations

Extrusion-based multi-functional additive manufacturing (AM) has been a rapidly developing area in AM recently. Particulate composites are widely used in this area to provide different functionalities with different types of particulate additives. However, there is no systematic understanding of the behavior of particulate composites during extrusion (especially in small nozzles) or of their properties once deposited in the build. This work investigates the properties of the type of particulate composites usually used in additive manufacturing, composed of a polymer matrix material and particulate additives within the micrometer scale. The focus is on the material rheology in the nozzle/capillary (for the …

Ball-On-Ring Test Validation For Equibiaxial Flexural Strength Testing Of Engineered Ceramics, Adrianna E. Lupercio, Ehsan Moshkelgosha, Riley C. Winters, Cayden Doyle, Mahmood Mamivand, Andrew T. Nelson, Brian J. Jaques

Materials Science and Engineering Faculty Publications and Presentations

The validation of a ball-on-ring, equibiaxial flexural strength method to obtain the transverse rupture strength (TRS) of right cylindrical ceramic specimens was performed in this study. Validation of the test method was achieved using commercially available engineered high purity alumina disks and finite element (FE) model analysis. The validated fixture was then used to obtain the TRS and Weibull statistical analysis of MgO-partially stabilized zirconia (MSZ) and Y₂O₃-partially stabilized zirconia (YSZ) ceramic disks. TRS data for alumina, MSZ, and YSZ agreed with the TRS values reported in the literature. A statistically relevant number of samples (N …

Damage Evolution And High-Rate Response Of High-Strength Concrete Under Triaxial Loading, Brett Williams

Mechanical Engineering Research Theses and Dissertations

The research presented in this study focuses on understanding fundamental mechanisms that drive material response under dynamic loading conditions. The objectives of the research were to: (1) to understand damage initiation and propagation in the bulk geomaterial under a variety of loading conditions and (2) to systematically investigate the strain rate effects on the triaxial compressive response of cementitious materials through the development of an innovative, first of its kind large-diameter (50 mm) triaxial Kolsky bar system.

The triaxial compressive response of high-strength concrete is needed to understand pressure-dependent material behavior, which is important for modeling extreme loading events. However, …

Detection Of Nucleotides In Hydrated Ssdna Via 2-D H-Bn Nanopore With Ionic-Liquid/Salt-Water Interface, Jungsoo Lee

Multidisciplinary Studies Theses and Dissertations

Accomplishing slow translocation speed with high sensitivity has been the greatest mission for solid-state nanopore (SSN) to electrically detect nucleobases in single-stranded DNA (ssDNA). In this study, a method to detect nucleobases in ssDNA using a SSN is introduced by considerably slowing down the translocation speed and effectively increasing its sensitivity. The ultra-thin titanium dioxide (TiO₂) coated hexagonal boron nitride (h-BN) nanopore was fabricated, along with an ionic-liquid [bmim][PF₆]/2.0 M KCl aqueous (cis/trans) interfacial system, to increase both the spatial and the temporal resolutions. As the ssDNA molecules entered the nanopore, a …

Aerosol Jet Printed Capacitive Strain Gauge For Soft Structural Materials, Kiyo T. Fujimoto, Jennifer K. Watkins, Timothy Phero, Takoda Bingham, Kshama Lakshmi Ranganatha, Benjamin C. Johnson, Zhangxian Deng, Brian Jaques, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Soft structural textiles, or softgoods, are used within the space industry for inflatable habitats, parachutes and decelerator systems. Evaluating the safety and structural integrity of these systems occurs through structural health monitoring systems (SHM), which integrate non-invasive/non-destructive testing methods to detect, diagnose, and locate damage. Strain/load monitoring of these systems is limited while utilizing traditional strain gauges as these gauges are typically stiff, operate at low temperatures, and fail when subjected to high strain that is a result of high loading classifying them as unsuitable for SHM of soft structural textiles. For this work, a capacitance based strain gauge (CSG) …

High-Performance Flexible Bismuth Telluride Thin Film From Solution Processed Colloidal Nanoplates, Madhusudan Kongara, Tony Varghese, Karthik Chinnathambi, Jesse Schimpf, Josh Eixenberger, Paul H. Davis, Yaqiao Wu, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Thermoelectric generators are an environmentally friendly and reliable solid‐state energy conversion technology. Flexible and low‐cost thermoelectric generators are especially suited to power flexible electronics and sensors using body heat or other ambient heat sources. Bismuth telluride (Bi₂Te₃) based thermoelectric materials exhibit their best performance near room temperature making them an ideal candidate to power wearable electronics and sensors using body heat. In this report, Bi₂Te₃ thin films are deposited on a flexible polyimide substrate using low‐cost and scalable manufacturing methods. The synthesized Bi₂Te₃ nanocrystals have a thickness of 35 ± …

Homogenization Of Composite And Cellular Materials Incorporating Microstructure And Surface Energy Effects, Ahmad Gad

Mechanical Engineering Research Theses and Dissertations

In the last few decades, the popularity of composite and cellular materials has rapidly increased through their widespread applications in multiple engineering fields including aerospace, automotive, civil and biomedical. However, to a large extent, the success of their practical applications depends on our ability to predict their mechanical behavior by using high-fidelity mechanics models.

Micromechanical modeling of composite and cellular materials is a challenging task due to the heterogeneous nature of such materials and the interactions among various constituent phases at the microscopic level, which result in non-homogeneous deformation, strain and stress fields. Therefore, it is necessary to develop simple …

Investigation Of The Electrode Polarization Effect For Biosensor Applications, Anil Koklu

Mechanical Engineering Research Theses and Dissertations

My research focuses on electrokinetic transport. Particularly, in this dissertation, we focus on fabrication and testing of micro electrodes with nanostructured surfaces to minimize the electrode polarization (EP) effects for biosensor applications. In the first study, electrochemical deposition of gold nanoparticles on to planar gold electrodes was used to generate rough surfaces. Dendritic nanostructures that reduced EP up to two orders of magnitude was obtained by optimizing the deposition conditions. These structures also enhanced dielectrophoresis (DEP) response of our bio-chips, making them usable in physiological buffers. In further studies we discovered a universal scaling of EP in the frequency domain, …

Investigation Of Fundamental Principles Of Rigid Body Impact Mechanics, Khalid Alluhydan

Mechanical Engineering Research Theses and Dissertations

In impact mechanics, the collision between two or more bodies is a common, yet a very challenging problem. Producing analytical solutions that can predict the post-collision motion of the colliding bodies require consistent modeling of the dynamics of the colliding bodies. This dissertation presents a new method for solving the two and multibody impact problems that can be used to predict the post-collision motion of the colliding bodies. Also, we solve the rigid body collision problem of planar kinematic chains with multiple contacts with external surfaces.

In the first part of this dissertation, we study planar collisions of Balls and …

Design And Control Of Fiber Encapsulation Additive Manufacturing, Matt Saari

Mechanical Engineering Research Theses and Dissertations

This work presents the design, development, and analysis of the Fiber Encapsulation Additive Manufacturing (FEAM) system developed at the Laboratory for Additive Manufacturing Robotics \& Automation at the Lyle School of Engineering at Southern Methodist University. The innovation introduced by FEAM is the ability to insert a continuous fiber of different material into the flowing extrudate. Correctly positioning the fiber feed inside the extrudate while turning the fiber in arbitrary directions is a critical aspect of the technology. This will allow for the full exploitation of the capabilities of the FEAM technology to produce robotic components that actuate and sense. …

Analytical And Experimental Study Of Laser Cladding Of Ni/Wc Metal Matrix Powders Reinforced With Rare Earth Elements Using A High Power Direct Diode Laser, Mohammed Sayeed

Mechanical Engineering Research Theses and Dissertations

The corrosion and wear are major limiting factors for steel in the harsh environments and can be controlled by depositing protective passive coatings. Nickel based alloy cladding of steel offers a solution by enabling better corrosion and wear resistance, and high bonding strength. The laser surface cladding of steel was conducted using a high power direct diode laser. Layers of tungsten carbide in Ni (40%Ni-60%WC) combined with 1% and 2% Lanthanum Oxide (La₂O₃) and Cerium Oxide (CeO₂) were deposited on ASTM A36 steel substrate. The X-ray diffraction and scanning electron microscopy were employed to …

Thermal Transport In Layer-By-Layer Assembled Polycrystalline Graphene Films, David Estrada, Alondra Perez

Materials Science and Engineering Faculty Publications and Presentations

New technologies are emerging which allow us to manipulate and assemble 2-dimensional (2D) building blocks, such as graphene, into synthetic van der Waals (vdW) solids. Assembly of such vdW solids has enabled novel electronic devices and could lead to control over anisotropic thermal properties through tuning of inter-layer coupling and phonon scattering. Here we report the systematic control of heat flow in graphene-based vdW solids assembled in a layer-by-layer (LBL) fashion. In-plane thermal measurements (between 100 K and 400 K) reveal substrate and grain boundary scattering limit thermal transport in vdW solids composed of one to four transferred layers of …

Open-Source Automated Chemical Vapor Deposition System For The Production Of Two-Dimensional Nanomaterials, Lizandra Williams-Godwin, Dale Brown, Richard Livingston, Tyler Webb, Lynn Karriem, Elton Graugnard, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

The study of two- dimensional (2D) materials is a rapidly growing area within nanomaterials research. However, the high equipment costs, which include the processing systems necessary for creating these materials, can be a barrier to entry for some researchers interested in studying these novel materials. Such process systems include those used for chemical vapor deposition, a preferred method for making these materials. To address this challenge, this article presents the first open-source design for an automated chemical vapor deposition system that can be built for less than a third of the cost for a comparable commercial system. The materials and …

Soft-Microrobotics: The Manipulation Of Alginate Artificial Cells, Samuel Sheckman

Mechanical Engineering Research Theses and Dissertations

In this work, the approach to the manipulation of alginate artificial cell soft-microrobots, both individually and in swarms is shown. Fabrication of these artificial cells were completed through centrifugation, producing large volumes of artificial cells, encapsulated with superparamagnetic iron oxide nanoparticles; these artificial cells can be then externally stimulated by an applied magnetic field. The construction of a Permeant Magnet Stage (PMS) was produced to manipulate the artificial cells individually and in swarms. The stage functionalizes the permanent magnet in the 2D xy-plane. Once the PMS was completed, Parallel self-assembly (Object Particle Computation) using swarms of artificial cells in complex …

High-Performance And Flexible Thermoelectric Films By Screen Printing Solution-Processed Nanoplate Crystals, Tony Varghese, Courtney Hollar, Joseph Richardson, Nicholas Kempf, Chao Han, Pasindu Gamarachchi, David Estrada, Yanliang Zhang

Materials Science and Engineering Faculty Publications and Presentations

Screen printing allows for direct conversion of thermoelectric nanocrystals into flexible energy harvesters and coolers. However, obtaining flexible thermoelectric materials with high figure of merit ZT through printing is an exacting challenge due to the difficulties to synthesize high-performance thermoelectric inks and the poor density and electrical conductivity of the printed films. Here, we demonstrate high-performance flexible films and devices by screen printing bismuth telluride based nanocrystal inks synthesized using a microwave-stimulated wet-chemical method. Thermoelectric films of several tens of microns thickness were screen printed onto a flexible polyimide substrate followed by cold compaction and sintering. The n-type films demonstrate …

Metals Additive Manufacturing Powder Aging Characterization, Thomas Russell Lovejoy, Nicholas Karl Muetterties, David Takeo Otsu

Mechanical Engineering

The metallic additive manufacturing process known as selective laser melting requires highly spherical, normally distributed powder with diameters in the range of 10 to 50 microns. Previous observations have shown a degradation in powder quality over time, resulting in unwanted characteristics in the final printed parts. 21-6-9 stainless steel powder was used to fabricate test parts, with leftover powder recycled back into the machine. Powder samples and test specimens were characterized to observe changes across build cycles. Few changes were observed in the physical and mechanical properties of the specimens, however, there were indications of chemical changes across cycles. Potential …

Electrical Resistance Monitoring Of Damage And Crack Growth In Advanced Sic-Based Ceramic Composites, Gregory Morscher, Craig Smith, Emmanuel Maillet, Chris Baker, Rabih Monsour

Dr. Gregory N. Morscher

No abstract provided.

Correlating Electrical Resistance Change With Mechanical Damage In Woven Sic/Sic Composites: Experiment And Modeling, Thanyawalai Sujidkul, Craig Smith, Zhijun Ma, Gregory Morscher, Zhenhai Xia

Dr. Gregory N. Morscher

Silicon carbide (SiC) fiber-reinforced SiC matrix composites are inherently multifunctional materials. In addition to their primary function as a structural material, the electric properties of the SiC/SiC composites could be used for the sensing and monitoring of in situ damage nucleation and evolution. To detect damage and use that information to further predict the useful life of a particular component, it is necessary to establish the relationship between damage and electrical resistance change. Here, two typical SiC/SiC composites, melt infiltrated (MI), and chemical vapor infiltrated (CVI) woven SiC/SiC composites, were tested to establish the relationship between the electrical response and …

Design, Fabrication, And Properties Of 2-2 Connectivity Cement/Polymer Based Piezoelectric Composites With Varied Piezoelectric Phase Distribution, Xu Dongyu, Cheng Xin, Sourav Banerjee, Huang Shifeng

Sourav Banerjee

The laminated 2-2 connectivity cement/polymer based piezoelectric composites with variedpiezoelectric phase distribution were fabricated by employing Lead Zirconium Titanate ceramicas active phase, and mixture of cement powder, epoxy resin, and hardener as matrix phase with a mass proportion of 4:4:1. The dielectric, piezoelectric, and electromechanical coupling properties of the composites were studied. The composites with large total volume fraction ofpiezoelectric phase have large piezoelectric strain constant and relative permittivity, and thepiezoelectric and dielectric properties of the composites are independent of the dimensional variations of the piezoelectric ceramic layer. The composites with small total volume fraction of piezoelectric phase have large …

Banded Microstructure In 2024-T351 And 2524-T351 Aluminum Friction Stir Welds: Part Ii. Mechanical Characterization, Michael Sutton, Bangcheng Yang, Anthony Reynolds, Junhui Yan

Anthony P. Reynolds

No abstract provided.

Anisotropic Compositional Expansion And Chemical Potential For Amorphous Lithiated Silicon Under Stress Tensor, Valery I. Levitas, Hamed Attariani

Mechanical and Materials Engineering Faculty Publications

Si is a promising anode material for Li-ion batteries, since it absorbs large amounts of Li. However, insertion of Li leads to 334% of volumetric expansion, huge stresses, and fracture; it can be suppressed by utilizing nanoscale anode structures. Continuum approaches to stress relaxation in Li_xSi, based on plasticity theory, are unrealistic, because the yield strength of Li_xSi is much higher than the generated stresses. Here, we suggest that stress relaxation is due to anisotropic (tensorial) compositional straining that occurs during insertion-extraction at any deviatoric stresses. Developed theory describes known experimental and atomistic simulation …

Enhancing Precalculus Curricula With E-Learning: Implementation And Assessment, Janet Callahan, Seung Youn Chyung, Joanna Guild, William Clement, Joe Guarino, Doug Bullock, Cheryl Schrader

Materials Science and Engineering Faculty Publications and Presentations

During Fall semester of 2007, a semester-long, quasi-experimental study was conducted at Boise State University to investigate the effectiveness of a systematically sequenced and managed, self-paced e-learning activity on improving students’ academic performance and motivation. A total of 125 students enrolled in 3 different sections of a Precalculus class participated in the study. The e-learning activity was implemented in 2 of the 3 sections as a required homework assignment. Students enrolled in one of the 2 selected sections were all engineering majors. The 3^rd section was a control group that did not use the e-learning activity. A pre-test, measuring …