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Articles 1 - 9 of 9

Full-Text Articles in Engineering

Basic Principles And Applications Of Secm In Metal Corrosion, Fa-He Cao, Yan Xia, Wen-Juan Liu, Lin-Rong Chang, Jian-Qing Zhang Oct 2013

Basic Principles And Applications Of Secm In Metal Corrosion, Fa-He Cao, Yan Xia, Wen-Juan Liu, Lin-Rong Chang, Jian-Qing Zhang

Journal of Electrochemistry

Scanning electrochemical microscopy (SECM) is chemical microscopy with higher spatial resolution. After 24 years of development, SECM has been widely applied in mapping and kinetics study of heterogeneous electron transfer in localized processes at solid-liquid or liquid-liquid interfaces. The fundamentals and recent advances of SECM in corrosion applications are described, including SECM mapping and kinetics on localized corrosion of metal or coating. Research work of SECM in corrosion by our group is also introduced. Future applications of SECM in corrosion are highlighted.


Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang Oct 2013

Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang

Journal of Electrochemistry

As a highly-sensitive and non-destructive in situ technique, spectroscopic ellipsometry has been widely applied in corrosion investigation to acquire the dynamic information of the “electrode-medium” interface during corrosion. This paper lays out some representative demonstrations in several established optical models used to interpret data obtained with spectroscopic ellipsometry in corrosion investigation. In addition, the latest trends in development of this technique are analyzed.


Iron-Magnesium Alloy Bioabsorbable Blood Stent, Kaitlyn Jarry, L Stanciu Oct 2013

Iron-Magnesium Alloy Bioabsorbable Blood Stent, Kaitlyn Jarry, L Stanciu

The Summer Undergraduate Research Fellowship (SURF) Symposium

Bioabsorbable materials are fairly new and proper alloys for implantation in the body have not yet been established. There are a few polymers that have showed promise, but they do not provide the proper mechanical support that metal does. These materials would be used to create devices such as blood stents and orthopedic screws. Investigation into the properties of different alloys can help to establish a material that can be used for implanted devices that are only needed for a limited amount of time. In order to investigate these alloys many different experiments will to be run to test the …


Density Functional Theory (Dft) Study On The Hydrolysis Behavior Of Degradable Mg/Mg Alloys For Biomedical Applications, Marjan Nezafati Aug 2013

Density Functional Theory (Dft) Study On The Hydrolysis Behavior Of Degradable Mg/Mg Alloys For Biomedical Applications, Marjan Nezafati

Theses and Dissertations

Magnesium-based (Mg and/or Mg alloys) materials possess many advantageous physicochemical/biological characteristics such as good biocompatibility and similarity of the mechanical properties to the human bone tissue, which renders this material a promising candidate for the biomedical and implant applications. One of the most attractive features of Mg-based materials is the degradability in the physiological environment. With the burst of research on the biodegradable materials for the healthcare device applications, Mg and its alloys attracted a strong attention in the bioengineering field in recent years. However, the major limitation of applying Mg-based materials to biomedical applications is the fast degradation/corrosion rate …


Multifunctional Corrosion Inhibition Behavior Of Zn-Al Calcined Layered Double Hydroxides For Steel Rebar In Nacl Solution, Xiao-Juan Zhang, Jing-Jing Wang, Shi-Gang Dong, Chang-Jian Lin Jun 2013

Multifunctional Corrosion Inhibition Behavior Of Zn-Al Calcined Layered Double Hydroxides For Steel Rebar In Nacl Solution, Xiao-Juan Zhang, Jing-Jing Wang, Shi-Gang Dong, Chang-Jian Lin

Journal of Electrochemistry

The Zn-Al layered double hydroxides (Zn-Al LDHs) and calcined products (Zn-Al CLDHs) were synthesized successfully under a routine air atmosphere. The results showed that both Zn-Al LDHs and Zn-Al CLDHs had obvious flake structures. The corrosion inhibition of Zn-Al CLDHs for steel rebar in NaCl solution was studied by electrochemical techniques. It was found that the corrosion rate of steel rebar decreased significantly after the steel rebar was treated by Zn-Al CLDHs in NaCl solution for 3 h. It was indicated that Zn-Al CLDHs could absorb Cl- and release OH- during their reconstruction process, which provided dual protection …


Evaluation Of Corrosion Properties Of Proprietary Metal Alloy Stents For In-Vivo Use, Michael David Bremner Jun 2013

Evaluation Of Corrosion Properties Of Proprietary Metal Alloy Stents For In-Vivo Use, Michael David Bremner

Materials Engineering

To assess corrosion rates of metal alloy bio-absorbable stents an experimental set-up was designed to mimic the coronary artery environment. The artery was modeled using 4mm diameter Tecoflex tubing and the metal alloy stents were inserted into the tubing using a catheter. As is the case in cardiac surgery, the catheter with the stent and a microballoon were maneuvered to the desired position. The microballoon was then slowly inflated to expand the stent and compress it against the tubing walls. The catheter and microballoon were then withdrawn. A circulating pump system was set up to cycle fetal bovine serum (FBS) …


Evaluation Of Forging Strain For Maximum Grain Size In Open-Die Forged 6061 Aluminum, Eric Strehl Jun 2013

Evaluation Of Forging Strain For Maximum Grain Size In Open-Die Forged 6061 Aluminum, Eric Strehl

Materials Engineering

In an effort to maximize grain growth of open-die forged 6061 aluminum alloy parts, samples from three of Weber Metals’s suppliers (Hidal Co-Almex USA Inc., TST Inc., and Vista Metals Corp.; to be called Supplier H, Supplier T, Supplier V respectively) were cut into cylinders with diameters of 0.75˝ and heights of 2˝, and put through a simulated forging process and heat treatment. It is possible that additional alloying elements may be promoting or inhibiting grain growth in the final part. Maximizing grain growth for aluminum alloy parts results in improved resistance to intergranular corrosion. Samples from each vendor had …


Comparison Of Polyurethane And Polysiloxane Coating Systems In Marine Environments, Jake Jarman, Jessica Salvatin Jun 2013

Comparison Of Polyurethane And Polysiloxane Coating Systems In Marine Environments, Jake Jarman, Jessica Salvatin

Materials Engineering

This project investigates the performance benefits of polysiloxane and polyurethane coating systems for corrosion protection in marine environments. PPG Industries Amercoat 450H and International Paint Interthane 990HS were the polyurethane topcoats tested. PPG Industries Ameron PSX 700 (New Blend) and International Paint Interfine 878 were the polysiloxane topcoats tested. Each coating was sprayed onto carbon steel panels that were prepared through hand blasting with glass beads. Scribed and unscribed panels were tested in a salt fog chamber for 1,200 hours according to ASTM Standard B0117-11 and in a UV/Humidifier for 1,650 hours according to ASTM Standard D4587-11. Panels were tested …


Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh Jan 2013

Kelvin Probe Electrode For Contactless Potential Measurement On Concrete-Properties And Applications, Michael Thomas Walsh

USF Tampa Graduate Theses and Dissertations

The practical feasibility of using a Kelvin Probe as a novel reference electrode in the measurement of both potential and polarization pulse response of reinforcing steel in concrete is demonstrated. Potential values measured using a KP reflect greater stability and repeatability than can typically be attained with conventional reference electrodes. Duplicate reinforced concrete beam test specimens with well-differentiated centrally corroding rebar segments were analyzed using both the Kelvin Probe (KP) and a conventional Saturated Calomel Electrode (SCE). Potential profile maps were developed using potential values recorded under static conditions with both the SCE and the KP. Nominal polarization resistance was …