Engineering Commons^™

Localized Corrosion Behaviour Of Molybdenum Bearing And Stabilized Stainless Steels In Saline Media, Hany Mohamed Sabry Ahmed

Archived Theses and Dissertations

No abstract provided.

Preparation And Properties Of Tantalum Silicide Films On Silicon Substrates, Lei Jin

Theses

Tantalum silicide (TaSi₂) thin films were sputter deposited on p- type and n- type silicon substrates using VARIAN 3125 magnetron DC sputtering system with TaSi₂ target. The thicknesses of TaSi₂ thin films considered in this study are 200Å, 600Å and 1000Å, respectively. The TaSi₂/Si wafers were annealed at temperatures in the range of 400 to 900°T. The sheet resistances of TaSi₂ thin films with various thicknesses were measured by four-point probe before and after annealing. The sheet resistance decreases with increase in annealing temperature and decreases with the increase in thickness of TaSi …

Nanoporous Sio2/Vycor Membranes For Air Separation, Mihir Tungare

Theses

Porous Vycor tubes with 40Å initial pore diameter were modified using low pressure chemical vapor deposition (LPCVD) of silicon dioxide N0₂). Diethylsilane (DES) in conjunction with nitrous oxide (N₂O) was used as a precursor to synthesize these SiO₂ films. The aim of this study was to obtain a considerable selectivity between species of comparable size and hence N₂O was used. The use of N₂O was believed to make the process self-limiting. DES was allowed to flow through the tube and N₂O on the outside in the chamber at 550°C …

Synthesis And Characterization Of Low Pressure Chemically Vapor Deposited Boron Nitride And Titanium Nitride Films, Narahari Ramanuja

Dissertations

This study has investigated the interrelationships governing the growth kinetics, resulting compositions, and properties of boron nitride (B-C-N-H) and titanium nitride (Ti-N-Cl) films synthesized by low pressure chemical vapor deposition (LPCVD) using ammonia (NH₃)/triethylamine-borane and NH₃/titanium tetrachloride as reactants, respectively.Several analytical methods such as the FTIR, UVNisible spectroscopy, XPS, AES, RBS, SEM, and XRD were used to study the stoichiometry and structure of the deposited films.

The B-N-C-H films were synthesized over a temperature range of 300 to 8500C at various flow rate ratios of the reactants and total pressure range of 50 to 150 mTorr. …

Longitudinal Cracking Of Concrete Slab In Composite Beams, Talat Fawzi Abu-Amra

Archived Theses and Dissertations

No abstract provided.

Kinetics Of Laser Chemical Vapor Deposition Of Carbon And Refractory Metals, Feng Gao

Doctoral Dissertations

Three-dimensional laser chemical vapor deposition (3D-LCVD) has been used to grow rods of carbon, tungsten, titanium, and hafnium from a variety of hydrocarbons and metal halide-based precursors. A novel computerized 3D-LCVD system was designed and successfully used in the experiments. A focused Nd:Yag laser beam (λ = 1.06 μm) was utilized to locally heat up a substrate to deposition temperature. The rods, which grew along the axis of the laser beam, had a typical diameter of 30–80 μm and a length of about 1 mm. The precursors for carbon deposition were the alkynes: propyne, butyne, pentyne, hexyne, and octyne. Propyne …

Pulsed Optoacoustics In Solids, Zibiao Wei

Electrical & Computer Engineering Theses & Dissertations

Optoacoustic techniques are widely used to probe and characterize target materials including solids, liquids and gases. Included in such applications are diagnoses of thin films and semiconductor materials. The need to obtain greater spatial resolution requires the generation of shorter optoacoustic pulses. For such pulses, non-thermal effects may be quite important. On the other hand, even when an optoacoustic pulse is generated by an initially non-thermal technique, the thermal aspects become important in its evolution and propagation. The research undertaken in this Ph.D. dissertation included the generation and detection of optoacoustic signals through the thermal elastic mechanism. Several applications in …

Mechanics Of A Functionally-Graded Titanium Matrix Composite, G. Brandt Miller

Theses and Dissertations

Functionally-graded Titanium Matrix Composites, (F/G TMCs) combine the ideal properties of titanium matrix composites with the more practical machining qualities of monolithic (unreinforced) alloy. This material shows great promise in application to aerospace structural components - even in parts whose design requirements have defied the use of composite materials in the past. Successful implementation of such a material would lead to enhanced aircraft performance. However, the basic properties of a functionally-graded titanium matrix composite need to be investigated. The composite/alloy transition region, or joint area, may be less strong than its constituents and therefore determine the overall performance of the …

Chemical Mechanical Polishing Optimization For 4h-Sic, Craig L. Neslen

Theses and Dissertations

Scratch free surfaces are required for substrates used in epitaxial growth. Silicon carbide (SiC) is a substrate material that is used in the epitaxial growth of SiC, GaN, and InGaN electronic devices. Preliminary chemical mechanical polishing (CMP) studies of 1 3/8" 4H-SiC wafers were performed in an attempt to identify the polishing parameter values that result in a maximum material removal rate and thus reduce substrate polishing time. Previous studies reported increased material removal rates associated with increasing polishing temperature, slurry pH, pressure, and polishing pad speed. In the current study, the effects of temperature, slurry pH, polishing pressure, and …

Optical Investigation Of Molecular Beam Epitaxy AlXGa1-XN To Determine Material Quality, Judith L. Mcfall

Theses and Dissertations

The purpose of this research was to determine the quality of AIGaN samples with various mole fractions of aluminum doped with silicon. The samples utilized for this study were composed of an AIN buffer layer sandwiched between the sapphire substrate and AIGaN epilayer grown by molecular beam epitaxy (MBE). Cathodoluminescence (CL) and photoluminescence (PL) were employed to determine the mole fraction of aluminum in each sample. These techniques also gave insight into the material's nonuniformity, defects, and impurities. CL was run at 4 different beam energies (2,5,10, & 15 keV) with four different currents (1,10,50, & 90 µA) for the …

Factors Affecting Carrier Transport In Ultrafast Iii-V Compound Semiconductor Based Photodiodes, James Alexander Mcadoo

Dissertations, Theses, and Masters Projects

This dissertation describes a comparative study conducted on GaAs MSM photodetectors to assess the importance of surface effects on the optical and frequency response characteristics of MSM photodetectors. MSM photodetectors on III-V compound semiconductors are technologically important because of their applications to fiber optic communication systems. While surface effects have been previously ignored, they must be considered in assessing the ultimate performance limits of such devices, especially if nanoscale MSM photodetectors are to be used. A controlled study was carried out in which high quality devices were subjected to surface damage over a known range and the resultant effects of …

Plasma Source Ion Implantation Of High Voltage Electrodes, Thomas Joseph Venhaus

Dissertations, Theses, and Masters Projects

Field emission and breakdown characteristics of high voltage, large area electrodes determine the performance of many vacuum-based electron sources. A corroborative project with the Thomas Jefferson National Accelerator Facility involves studying the behavior of such electrodes after nitrogen ion implantation. A Plasma Source Ion Implantation (PSII) facility is designed and constructed at William and Mary, and used to treat stainless steel electrodes. PSII is a novel implantation technique developed at the University of Wisconsin-Madison. A workpiece is submerged in a quiescent plasma of the species to be implanted. A series of high, negative voltages (30--100 kV) is applied to the …

Surface Processing By Rfi Pecvd And Rfi Psii, Lingling Wu

Dissertations, Theses, and Masters Projects

An RFI plasma enhanced chemical vapor deposition (PECVD) system and a large-scale RF plasma source immersion ion implantation (PSII) system were designed and built to study two forms of 3-D surface processing, PECVD and PSII. Using the RFI PECVD system, Ti-6Al-4V substrates were coated with diamond-like carbon films with excellent tribological and optical properties. as an innovation, variable angle spectroscopic ellipsometry (VASE) was successfully applied for non-destructive, 3-D, large-area tribological coatings quality investigation.;Based on the experience with the RFI PECVD system, a large-scale RFICP source was designed and built for the PSIL Langmuir probe and optical emission spectroscopy studies indicated …

Effect Of Antioxidants On Ultra High Molecular Weight Polyethylene (Uhmwpe), Clifford Schrader

Masters Theses

This thesis presents a study on the effects of antioxidants on the oxidative induction time (OIT), thermal behavior, and hardness property of ultra high molecular weight polyethylene (UHMWPE). The antioxidants were dissolved into methanol alcohol before the solution was mixed with UHMWPE powder. The mixture was degassed under vacuum, and then compression-molded into disks 1.25 in. in diameter.

Different antioxidants were evaluated at concentrations up to 0.6 percent. A 0.6 percent concentration was used to screen the effectiveness of various antioxidants. Effect of antioxidant concentration was investigated in the range between 0 and 0.6 percent. OIT was evaluated on UHMWPE …

Pre-Inoculation Effect Of Sic In Production Of Thin Wall Ductile Iron Castings, Nikolay Y. Laukhin

Dissertations and Theses @ UNI

Pre-inoculation effect of SiC additions and its effect on castability, microstructure, and magnesium recovery in thin wall ductile iron plates have been studied. Experimental results were compared with alternative FeSi75 furnace pre-inoculation additions.

The first series of experiments aimed to set the baseline of iron quality, when using FeSi75 pre-inoculant

In the second series of experiment, different methods of introduction of Sic into liquid iron were studied. It was established that Sic added into the stream during the tapping into the flow-through chamber or added directly into the flow-through chamber produced lower Si recovery. The most effective method of introduction …

Theoretical And Experimental Study Of Generation Mechanisms For Laser Ultrasound In Woven Graphite /Epoxy Composites With Translaminar Stitching, Adam D. Friedman

Dissertations, Theses, and Masters Projects

The aerospace industry is beginning to use advanced composite materials for primary load bearing structures and their failure mechanisms must be better understood to predict their behavior in service. The Combined Loads Tests (COLTS) facility is being constructed at the NASA Langley Research Center to characterize these failure mechanisms. Laser based ultrasonic NDE can monitor the samples during dynamic loading without interfering with the structural tests. However, the constraints of implementing laser ultrasound in a structures laboratory reduces the efficiency of the technique. The system has to be "eye-safe" because many people will be present during the structural tests. Consequently, …

In-Situ Frequency-Dependent Electromagnetic Sensing For Monitoring Physical And Chemical Attributes During Chemical Processing, Jeffrey David Rogozinski

Dissertations, Theses, and Masters Projects

The objective of this research was to develop an in-situ sensing technique that monitors the molecular-level response of ions and dipoles to an applied electric field in order to characterize the changes in state of a polymer resin during chemical processing. This technique needs to be capable of monitoring the reaction progress not only in the laboratory setting but also in-situ in the processing tool or reaction environment. Frequency Dependent Electromagnetic Sensing (FDEMS) was selected for this task.;This dissertation investigates the applicability of FDEMS to monitoring two types of processing methods: reactive and batch reactor. The reactive processing system examined …