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Full-Text Articles in Engineering
Molten Salt Technologies For Advanced Nuclear Fuel Cycles And Molten Salt Reactors, Dimitris Killinger
Molten Salt Technologies For Advanced Nuclear Fuel Cycles And Molten Salt Reactors, Dimitris Killinger
Theses and Dissertations
This dissertation provides five topics—an assessment of different monitoring and analytical techniques often cited in the literature for molten salt systems and designs for nuclear engineering applications. First, we explored commonly used materials for quasi-reference electrodes in molten chloride salts. Second, the limitations of the electrochemical analysis known as cyclic voltammetry due to the concentration of uranium(III) present were being investigated. Third, we provided an experimental assessment on the development of a spectroelectrochemical cell for interrogating various spectroelectrochemical techniques, namely chronoabsorptometry and chronofluorometry, and their limitations due to the presence of uranium(III) ions. Fourth, a study on the corrosion resistance …
The Effect Of Rapid Solidification And Heat Treatment On Microstructure And Electrochemical Properties Of Advanced Biomaterial Co-Cr-Mo-C Alloy, Hamid Reza Erfanian Nazif Toosi
The Effect Of Rapid Solidification And Heat Treatment On Microstructure And Electrochemical Properties Of Advanced Biomaterial Co-Cr-Mo-C Alloy, Hamid Reza Erfanian Nazif Toosi
Theses and Dissertations
Co-Cr-Mo-C alloys have been used for implant materials for decades because of their strength, corrosion resistance, wear resistance, and biocompatibility. To develop durable low-friction joint replacement implants, it is important to understand the solidification structure and properties of these materials. While HCP phase is the thermodynamically stable phase in these alloys, they maintain their high-temperature γ-FCC matrix and coarse dendritic structure on cooling to room temperature when cast by conventional methods. In this research, a wedgeshaped copper chill mold was used to examine the effect of cooling rates from 10 K/s to 450 K/s on the microstructure, HCP fraction, and …
Corrosion Of Aluminum Current Collector In Cost Effective Rechargeable Lithium-Ion Batteries, Shengyi Li
Corrosion Of Aluminum Current Collector In Cost Effective Rechargeable Lithium-Ion Batteries, Shengyi Li
Theses and Dissertations
Rechargeable lithium ion batteries (LIB) have been widely used as commercial energy storage systems for portable equipment, electronic devices and high power applications (e.g. electronic vehicles). One issue with the commercialized LIB is that expensive, highly toxic and flammable organic solvents are used in the electrolyte and the fabrication process of electrodes. The toxic organic based solvents increase the production cost and lead to significant safety concerns in the event of a battery overcharge or short circuit. The recent development of “green manufacturing” technology allows manufacturers to replace the organic solvents used in the cathode coating process by aqueous based …
Microstructure, Wetting Angle And Corrosion Of Aluminum-Silicon Alloys, Shvetashva Suri
Microstructure, Wetting Angle And Corrosion Of Aluminum-Silicon Alloys, Shvetashva Suri
Theses and Dissertations
In this study the effect of composition, surface roughness and water droplet size on contact angle and corrosion properties of cast Aluminum-Silicon alloys containing Si from 5% to 50% have been examined. The water contact angle was measured on a given sample using a goniometer. In addition, the effect of surface roughness and droplet size on contact angle has been measured for alloys at a fixed composition. The microstructures can be found in this report with sizes of primary and eutectic Silicon as well as inter-particle spacing between Silicon. Contact angle measurements are accompanied with a photographic validation of the …
Density Functional Theory (Dft) Study On The Hydrolysis Behavior Of Degradable Mg/Mg Alloys For Biomedical Applications, Marjan Nezafati
Density Functional Theory (Dft) Study On The Hydrolysis Behavior Of Degradable Mg/Mg Alloys For Biomedical Applications, Marjan Nezafati
Theses and Dissertations
Magnesium-based (Mg and/or Mg alloys) materials possess many advantageous physicochemical/biological characteristics such as good biocompatibility and similarity of the mechanical properties to the human bone tissue, which renders this material a promising candidate for the biomedical and implant applications. One of the most attractive features of Mg-based materials is the degradability in the physiological environment. With the burst of research on the biodegradable materials for the healthcare device applications, Mg and its alloys attracted a strong attention in the bioengineering field in recent years. However, the major limitation of applying Mg-based materials to biomedical applications is the fast degradation/corrosion rate …