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Synthesis And Characterization Of Polymer-Silica Composite Hydrogel Particles And Influence Of Hydrogel Composition On Cement Paste Microstructure, Matthew J. Krafcik, B Bose, Kendra Erk
Synthesis And Characterization Of Polymer-Silica Composite Hydrogel Particles And Influence Of Hydrogel Composition On Cement Paste Microstructure, Matthew J. Krafcik, B Bose, Kendra Erk
School of Materials Engineering Faculty Publications
The objective of this research is to define the fundamental structure-property relationships of water-swollen polymer hydrogel particles that are employed as internal curing agents in cementitious mixtures, in addition to reporting a novel synthesis procedure for combining pozzolanic materials with hydrogel particles. Solution polymerization was performed to incorporate amorphous nanosilica particles within acrylic-based polymer hydrogel particles of varying chemical compositions (i.e., monomer ratio of acrylic acid (AA) to acrylamide (AM)). Experiments were designed to measure the absorption capacity and kinetics of hydrogel particles immersed in pure water and cementitious pore solution, as well as determine the impact of particles on …
A Rheometry Method To Assess The Evaporation-Induced Mechanical Strength Development Of Polymer Solutions Used For Membrane Applications, Eduard Caicedo Casso, Jessica L Sargent, Rachel M. Dorin, Ulrich B. Wiesner, William A. Phillip, Bryan M. Boudouris, Kendra Erk
A Rheometry Method To Assess The Evaporation-Induced Mechanical Strength Development Of Polymer Solutions Used For Membrane Applications, Eduard Caicedo Casso, Jessica L Sargent, Rachel M. Dorin, Ulrich B. Wiesner, William A. Phillip, Bryan M. Boudouris, Kendra Erk
School of Materials Engineering Faculty Publications
Rotational and oscillatory shear rheometry were used to quantify the flow behavior under minimal and significant solvent evaporation conditions for polymer solutions used to fabricate isoporous asymmetric membranes by the self-assembly and non-solvent induced phase separation (SNIPS) method. Three different A-B-C triblock terpolymer chemistries of similar molar mass were evaluated: polyisoprene-^-polystyrene-6-poly(4-vinylpyridine) (ISV); polyisoprene-6- polystyrene-6-poly(V,A-dimethylacrylamide) (ISD); and polyisoprene-Z>-polystyrene-h-poly(fer/- butyl methacrylate) (ISB). Solvent evaporation resulted in the formation of a viscoelastic film typical of asymmetric membranes. Solution viscosity and film viscoelasticity were strongly dependent on the chemical structure of the triblock terpolymer molecules. A hierarchical magnitude (ISV>ISB>ISD) was observed …
Controllable Internal Mixing In Coalescing Droplets Induced By The Solutal Marangoni Convection Of Surfactants With Distinct Headgroup Architectures, Jerome J. Nash, Patrick T. Spicer, Kendra Erk
Controllable Internal Mixing In Coalescing Droplets Induced By The Solutal Marangoni Convection Of Surfactants With Distinct Headgroup Architectures, Jerome J. Nash, Patrick T. Spicer, Kendra Erk
School of Materials Engineering Faculty Publications
Through several complementary experiments, an investigation of the bulk and interfacial flows that emerged during the coalescence of two water-in-oil droplets with asymmetric compositional properties was performed. By adding surfactant to one of the coalescing droplets and leaving the other surfactant-free, a strong interfacial tension gradient (i.e., solutal Marangoni) driving energy between the merging droplets generated pronounced internal mixing. The contributions of two distinct types of surfactant, anionic ammonium lauryl sulfate (ALS) and cationic cetyltrimethylammonium bromide (CTAB) on the rate of coalescence bridge expansion and on the generation of opposing flows during coalescence were investigated. All coalescence experiments supported the …
Synthesis And Characterization Of Polymer-Silica Composite Hydrogel Particles And Influence Of Hydrogel Composition On Cement Paste Microstructure, Matthew J. Krafcik, B Bose, Kendra Erk
Synthesis And Characterization Of Polymer-Silica Composite Hydrogel Particles And Influence Of Hydrogel Composition On Cement Paste Microstructure, Matthew J. Krafcik, B Bose, Kendra Erk
School of Materials Engineering Faculty Publications
The objective of this research is to define the fundamental structure-property relationships of water-swollen polymer hydrogel particles that are employed as internal curing agents in cementitious mixtures, in addition to reporting a novel synthesis procedure for combining pozzolanic materials with hydrogel particles. Solution polymerization was performed to incorporate amorphous nanosilica particles within acrylic-based polymer hydrogel particles of varying chemical compositions (i.e., monomer ratio of acrylic acid (AA) to acrylamide (AM)). Experiments were designed to measure the absorption capacity and kinetics of hydrogel particles immersed in pure water and cementitious pore solution, as well as determine the impact of particles on …