Engineering Commons^™

Production And Applications Of Formaldehyde-Free Phenolic Resins Using 5-Hydroxymethylfurfural Derived From Glucose In-Situ, Yongsheng Zhang

Electronic Thesis and Dissertation Repository

The phenol-formaldehyde (PF) resin manufacturing industry is facing a growing challenge with respect to concerns over human health, due to the use of carcinogenic formaldehyde and sustainability due to the use of petroleum-based phenol in PF resin manufacture. Glucose and its derivative, 5-hydroxymethylfurfural (5-HMF), have proven to be potential substitutes for formaldehyde in the synthesis of phenolic novolac resins.

This thesis investigated a number of glucose and 5-HMF resin systems including the curing of phenol-glucose novolac resin (PG) with a bis-phenol-A type epoxy. The curing process was modeled according to the Sestak-Berggren equation (S, B) using Málek methods. This was …

Development Of Novel Nanomaterials Based On Silicon And Graphene For Lithium Ion Battery Applications, Yuhai Hu

Electronic Thesis and Dissertation Repository

Electrochemical energy storage is one of the important strategies to address the strong demand for clean energy. Rechargeable lithium ion batteries (LIBs) are one of the typical electrochemical devices and have been used in a great number of areas. Now, the challenge for the LIB research is to make the batteries carry higher energy density so as to fulfill the demand of the emerging markets, particularly, electric vehicles and portable smart electronics. In this regard, the present commercial anode material can not meet this requirement. Much effort is being made toward either exploring new morphologies of carbon materials or searching …

Surface Modification Of Aluminum Alloys By Plasma Electrolytic Oxidation, Vahid Dehnavi

Electronic Thesis and Dissertation Repository

Plasma Electrolytic Oxidation (PEO) is a surface treatment for the production of ceramic oxide coatings with great properties, such as high wear and corrosion resistance, on metal substrates, particularly aluminum and magnesium alloys. Formation of PEO coatings involves complex processes and mechanisms that are difficult to study. Currently, the PEO process is in a transition phase from research to commercial application, with a primary focus on the corrosion and wear protection of light alloys, and has recently generated interest as a promising surface treatment for biomedical applications.

To justify the industrial application of PEO, a more systematic and in-depth study …

On The Interfacial Fracture Mechanics Of Long-Fibre Reinforced Polymer Composites, Ian N. Swentek

Electronic Thesis and Dissertation Repository

Fibre-reinforced polymer composites are being widely adopted as the de facto material for automotive lightweight design, but lack the material models capable of accurately predicting fracture. To address this research gap, three large-scale experimental studies are undertaken to characterize thermoset polymers during cure, understand the fibre-matrix interfacial bond strength, and predict the fracture of random long-fibre composites via the energy of fracture. In conjunction with the Fraunhofer Project Center in London, Ontario, sample sheet moulded composites were used to verify the key findings with several industrial composite samples. With refined interfacial strength measurement methods, and accurate predictions of the composite …

Surfactant Assisted Dispersion Of Single-Walled Carbon Nanotubes In Polyvinylpyrrolidone Solutions, Tennison Yu

Electronic Thesis and Dissertation Repository

Obtaining stable aqueous dispersions is one of the main challenges hindering a widespread and effective use of single-walled carbon nanotubes (SWNT) in many applications. Although it has been recognized that their versatility makes them an extremely attractive material, the unique molecular structure that gives SWNTs their unmatched electronic, mechanical, and thermal properties is also responsible for strong van der Waals interactions. This, combined with extremely high aspect ratios and flexibility, causes SWNTs to adhere strongly into tightly bundled ropes. In these bundles, SWNTs are not as useful as their linearized unbundled equivalents. Thus, in order to take advantage of their …

Mechanistic Failure Criterion For Unidirectional And Random Fibre Polymer Composites, Jamaloddin Jamali

Electronic Thesis and Dissertation Repository

Polymer composite design in energy absorbing components requires a failure criterion that can predict the energy involved in its fracture under different modes of loading. Present mixed mode criteria are mainly empirical or semi-empirical, and are only suitable for a small range of composite types.

The purpose of this study was to develop a mechanistic failure criterion that is applicable to a wide range of polymer composites. An energy based mechanistic failure criterion is proposed to characterize the toughness of unidirectional (UD) and randomly oriented short fibre composites (random fibre composites).

In UD and random composites, the criterion predicts the …

Humidity Effect On The Structure Of Electrospun Core-Shell Pcl-Peg Fibers For Tissue Regeneration Applications, Adam P. Golin

Electronic Thesis and Dissertation Repository

With the aim of creating a biodegradable scaffold for tympanic membrane (TM) tissue regeneration, core-shell nanofibers composed of a poly(caprolactone) shell and a poly(ethylene glycol) core were created using a coaxial electrospinning technique. In order to create fibers with an optimal core-shell morphology, the effect of relative humidity (RH) on the core-shell nanofibers was systematically studied, with a FITC-BSA complex encapsulated in the core to act as a model protein. The core-shell nanofibers were electrospun at relative humidity values of 20, 25, 30, and 40% RH within a glove box outfitted for humidity control. The core-shell morphology of the fibers …