Engineering Commons^™

Investigating Near-Field Radiative Heat Transfer With Titanium Carbide Mxenes And Slanted Columnar Thin Films, Sean Luke Murray

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This work investigates the mechanisms to manipulate and control the magnitudes of Near-Field Radiative Heat Transfer (NFRHT) using two-dimensional materials and nanostructured surfaces. NFRHT occurs when the geometrical features of the radiating objects or the separation distance between interacting bodies are comparable to or lower than the characteristic thermal radiation wavelength. NFRHT magnitudes surpass the blackbody limit by several orders of magnitude due to phenomena such as photon tunneling and new modes of energy transfer, like surface polaritons. Therefore, it is crucial to understand how material properties and surface nanostructures affect NFRHT.

The first part of this work examines the …

Studies Of Exotic Electronic, Optical, And Electrochemical Properties In Nanoparticle Assembly And Graphene, Jay Min Lim

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

It is well known that exotic properties and phenomena emerge as structural dimensions shrink to nanoscales. We self-assembled one-dimensional chains of gold nanoparticles in solution and quantified the growth process by monitoring the redshift of localized surface plasmon resonance (LSPR). Curiously, the redshift stopped while the chains continued to rearrange as manifested by gradual reduction in the LSPR peak. Using electromagnetic simulations, we quantitatively explained the phenomena as a rapid “addition-polymerization” followed by a sharp transition to “condensation-process.” Next, recognizing the significant electric field enhancement in the interparticle gap, a photoluminescent-active Eu³⁺ ion was used to probe Surface-Enhanced Photoluminescence …

Smart Automatic Modal Hammer Predictor-Corrector Approach For Accurate Excitation Of Dynamical Systems, Mohammad Nasr

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This research introduces an innovative solution that revolutionizes the study of linear and nonlinear dynamical systems—a smart automatic modal hammer. With its affordability and intelligent capabilities, this automatic modal hammer becomes an invaluable tool for research and industry, enabling repeatable strikes with precise force control. This system's significance becomes particularly evident when studying nonlinear systems, which heavily rely on the excitation level for their dynamics. By offering a cost-effective design this proposed system proves to be robust in accelerating research on nonlinear dynamics, providing researchers with an efficient and accessible means to delve deeper into these complex systems. The proposed …

Computational Studies Of Charge-Transfer Mechanisms In Electrochemical Materials, Mohammadreza Reza Nouri

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

Understanding charge transfer mechanisms of electrochemical reactions is critical for advancing a variety of electrochemical energy storage and conversion technologies such as water electrolysis, fuel cells, and batteries. (Photo)electrochemical water splitting, involving OER at the anode and HER at the cathode, presents an environmentally friendly way of storing energy from renewable sources in the form of pure hydrogen. While a lot of emphasis has been placed on developing highly active and stable OER/HER catalysts, our atomic-level understanding of the underlying charge transfer mechanisms falls behind.

In this work, we focus on both Faradaic and non-Faradaic charge transfer mechanisms to investigate …

Laser Surface Processing For Enhanced Adhesion Between Diamond Coatings And Metallic Substrates, Zhipeng Wu

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

Application of diamond coatings on metallic substrates endows them with superior properties including mechanical robustness and corrosion resistance, rendering them highly adaptable for diverse industrial and technological applications. However, significant disparities in coefficients of thermal expansion (CTEs) result in pronounced residual stress near interfaces, causing delamination of the diamond coatings. Moreover, weak chemical bonding poses a concern for certain metallic substrates. Laser surface processing techniques show promise in enhancing adhesion by altering stress distribution and improving mechanical bonding. Therefore, the research efforts described in this dissertation mainly focus on femtosecond (fs) laser texturing for enhanced adhesion of diamond coatings on …

Electrical And Morphological Investigation Of A Fe(Ii) Based Spin Crossover Complex And Its Composite, Rifat Mahbub

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

Spin crossover (SCO) complexes have unique properties of switching their spin state upon perturbations like temperature, pressure, light, etc. Along with the spin state, different properties vary like structural, electrical, magnetic, optical properties. This enables these materials to be potentially used in various applications like molecular electronics, memory devices, switching devices, sensors and many more. To incorporate spin crossover materials into devices with efficient performance, the electrical behavior needs to be understood. This dissertation aims to investigate the effect of crystal structure on the electrical properties of iron(II) triazole spin crossover complex and how it can be modified for better …

Advancements In Microscale Tensile Testing: A Novel Device For The High Throughput Analysis Of Two-Photon Polymerized Microfibers In Liquid, Grayson D. Minnick

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

Two-photon polymerization (TPP) enables the 3D fabrication of micro- and nanostructures from biocompatible materials with high resolutions, reaching into the realm of hundreds of nanometers. Such capabilities are crucial for advancing applications in fields like mechanobiology. As microscale technologies evolve, the precise characterization of material properties becomes increasingly essential. This is especially true for TPP-printed microstructures serving as scaffolds for 3D cell culture and intended for studying the mechanics of tissues. Despite the importance, traditional micro-scale tensile testing methods typically lack scalability and fail to replicate relevant environmental conditions. This dissertation introduces a new device that is specifically designed to …

Growth And Simulation Of Dielectric-Metal Nanoheterostructured Thin Films By Ballistic Deposition, Shawn Wimer

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

This thesis is divided into two related topics: the structural and chemical characterization of dielectric-metal nanoheterostructured thin films grown by glancing angle deposition (GLAD) and the results of the simulated growth of films and structures by GLAD with discrete-space and continuous-space Monte Carlo ballistic simulation.

Individual structures comprising films grown by GLAD were investigated by S/TEM and SEM imaging, electron diffraction, and chemical characterization and mapping by EDX. Different intermolecular interactions within and between different materials, including Si, Ag, Au, and ZrO₂, are linked to differences in the shapes of individual materials in heterostructures, the shape of heterostructures …

Laser 3d Printing Of Diamond-Based Composite Materials For Thermal Management Applications, Nada Kraiem

Dissertations and Doctoral Documents from University of Nebraska-Lincoln, 2023–

With the trend towards miniaturization of electrical equipment and the constant increase in power density in semiconductor devices, efficient heat management has become a major concern for researchers. Indeed, this technological evolution imposes increasingly strict constraints in terms of thermal dissipation, necessitating innovative solutions to ensure better durability and reliability of components. In this context, the use of composite materials offering high thermal conductivity (TC) and low coefficient of thermal expansion (CTE) compared to pure metals has become essential to address overheating issues in electronic components.

The utilization of advanced materials such as diamond (D), with exceptional TC and hardness …

Sliding Markov Decision Processes For Dynamic Task Planning On Uncrewed Aerial Vehicles, Trent Wiens

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Mission and flight planning problems for uncrewed aircraft systems (UASs) are typically large and complex in space and computational requirements. With enough time and computing resources, some of these problems may be solvable offline and then executed during flight. In dynamic or uncertain environments, however, the mission may require online adaptation and replanning. In this work, we will discuss methods of creating MDPs for online applications, and a method of using a sliding resolution and receding horizon approach to build and solve Markov Decision Processes (MDPs) in practical planing applications for UASs. In this strategy, called a Sliding Markov Decision …

Development Of A Multi-Use Modular Microfluidic Platform Using 3d Printing, Carson Emeigh

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Microfluidic lab-on-a-chip (LoC) technology has driven numerous innovations due to their ability to perform laboratory-scale experiments on a single chip using microchannels. Although LoC technology has been innovative, it still suffers from limitations related to its fabrication and design flexibility. Typical LoC fabrication, with photolithography, is time consuming, expensive, and inflexible. To overcome the limitations of LoC devices, modular microfluidic platforms have been developed where multiple microfluidic modules, each with a specific function or group of functions, can be combined on a single platform. Modular microfluidics have overcome some of the limitations of LoC devices, but currently, their fabrication is …

Design And Optimization Of A Novel Monolithic Spring For High-Frequency Press-Pack Sic Fet Modules, Bogac Canbaz

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Silicon Carbide (SiC) Field-Effect Transistor (FET) modules lead the way in power electronics, being superior in efficiency and robustness for high-frequency applications. The shift towards SiC from traditional silicon (Si)-based devices is driven by its superior thermal conductivity, higher electric field strength, and operational efficiency at elevated temperatures. These features are critical for the development of next-generation, grid-oriented power converters aimed at enhancing the reliability and sustainability of power systems. This research focuses on high-frequency press-pack (HFPP) SiC FET modules, addressing the primary challenge of miniaturizing SiC FET dies without compromising performance, through an innovative press-contact design essential for increased …

Dynamic Impact Testing And Numerical Analysis Of Non-Proprietary Astm F2656-20 M50 Anti-Ram Barrier Components, Weston Kelley

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

In a post-9/11 world, hostile actors are using vehicles as weapons to inflict civilian casualties. Pedestrians, vulnerable road users, military personnel, and police may be targeted using a vehicle as a weapon. The United States Department of Defense (DoD) also utilizes Entry Control Facilities (ECFs) which are carefully designed transportation corridors to manage how threat vehicles are able to access military facilities. In 2004, DoD started to upgrade all ECFs using both passive and active barriers. Many anti-ram vehicle barriers were evaluated according to the criteria established in ASTM F2656, but to date few options are available which are (1) …

Safety Evaluation Of Hawaii Dot Modified Type A-1 Flared Buried In Backslope Guardrail End Terminal, Sina Changizian

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The Hawaii Department of Transportation (HDOT) desired to evaluate the crashworthiness of a guardrail end terminal design in which the upstream guardrail anchorage was connected to a block partially buried in a cut slope, known as a “Buried in Backslope” or BIB design. The HDOT BIB system used an upper W-beam with 8-in. deep blockouts attached to W6x9 steel posts and a lower W-beam rubrail located 3 in. below the upper rail. The system used two horizontal flares: 7.4:1 near the upstream anchor block and a 13:1 flare through the ditch.

Critical impact points (CIPs) were identified and recommended for …

An Icfd Fluid Model Used In A Mash Tl-6 Vehicle Model, Md Zunayed Habib

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The objective of this thesis was to develop an ICFD finite element model of a partially filled deformable container suitable for impact scenarios. This model will be later incorporated into the existing TL-6 vehicle model, which is a tractor-tank trailer vehicle model. Previous finite element fluid models for the TL-6 vehicle used an elastic fluid model, which could not predict the fluid behavior correctly.

A study was conducted on the ICFD modeling and an improved ICFD model has been developed using the LS-DYNA, a finite element analysis software. Different properties and parameters of the fluid and the container were adopted …

Experimental Analysis Of Nonlinear Wave Propagation In Bistable Mechanical Metamaterials With A Defect, Samuel R. Harre

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Mechanical metamaterials built up of compliant units can support the propagation of linear and nonlinear waves. A popular architecture consists of a one-dimensional chain of bistable elements connected by linear springs. This type of chain can support nonlinear transition waves that switch each element from one stable state to the other as they propagate along the chain. One way to manipulate the propagation of such waves is via introduction of a local inhomogeneity, i.e., a defect in the otherwise periodic chain. Recent analytical and numerical work has shown that based on its initial velocity, a transition wave may be reflected, …

Characterization Of Interlayer Laser Shock Peening During Fused Filament Fabrication Of Polylactic Acid (Pla), Fabien Denise

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The field of additive manufacturing (AM) has gained a significant amount of popularity due to the increasing need for more sustainable manufacturing techniques and the adaptive development of complex product geometries. The problem is that AM parts routinely exhibit flaws or weaknesses that affect functionality or performance. Over the years, surface treatments have been developed to compensate certain flaws or weaknesses in manufactured products. Combining surface treatments with the modularity of additive manufacturing could lead to more adaptable and creative improvements of product functions in the future. The current work evaluates the feasibility of pursuing a new research axis in …

Applications Of Femtosecond Laser-Processed And Nanoneedle-Synthesized Surfaces To Enhance Pool Boiling Heat Transfer, Peter Efosa Ohenhen

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

In the present work, the integration of femtosecond laser surface processing (FLSP) with copper hydroxide on hybrid surfaces was examined. The goal was to determine the impact on pool boiling enhancement. The samples for the investigation were fabricated by first functionalizing with FLSP, and the process was then followed by citric acid cleaning (CAC) to eliminate the oxides generated on the copper surface during the FLSP process. After the citric acid cleaning, the samples were immersed in ethanol and subjected to an ultrasonic bath for 25 minutes. This step was performed to eliminate any residual citric acid and loose particles. …

Hydroxyapatite-Based Coatings On Silicon Wafers And Printed Zirconia, Antoine Chauvin

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Dental surgery needs a naturally attract implant design that can ensure both osseointegration and soft tissue integration. Hydroxyapatite (HAp), the main mineral constituent of dentine and tooth enamel, is commonly used as a coating component, notably for overlaying titanium– or ceramics–based implants. This thesis aims to investigate the behavior of a HAp-based coating, specifically designed to be compatible with a porous substrate. Coating layers are made by sol–gel dip coating by immersion of porous substrates made by additive manufacturing into solutions of HAp, having been mixed with polyethyleneimine (PEI), to improve the adhesion of HAp on the substrate. First, the …

Analysis Of Bombyx Mori Silk And Polyimide Nanofibers, Sabrina Leseul

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This thesis presents a study on the properties of Bombyx Mori silk nanofibers and polyimide (PI) nanofibers. Firstly, a Bombyx Mori silk solution has been created with degummed silkworm cocoons in order to separate the fibroin and the sericin, the two main proteins of the silk. The fibroin was then centrifuged to remove insoluble particles and stored and 4°C before mixing with hexafluoroisopropanol (HFIP). On the second part, a polyimide solution, made with shavings of polyimide and N,N-dimethylformamide (DMF). Both solutions are then electrospun. Electrospinning parameters are studied. In this way, a part of my thesis has been dedicated to …

Breakdown Of The Drift-Diffusion Model For Transverse Spin Transport In A Disordered Pt Film, Kirill D. Belashchenko, Giovanni G. Baez Flores, Wuzhang Fang, Alexey Kovalev, Mark Van Schilfgaarde, Paul M. Haney, Mark D. Stiles

Department of Physics and Astronomy: Faculty Publications

Spin-accumulation and spin-current profiles are calculated for a disordered Pt film subjected to an in-plane electric current within the nonequilibrium Green's function approach. In the bulklike region of the sample, this approach captures the intrinsic spin Hall effect found in other calculations. Near the surfaces, the results reveal qualitative differences with the results of the widely used spin-diffusion model, even when the boundary conditions are modified to try to account for them. One difference is that the effective spin-diffusion length for transverse spin transport is significantly different from its longitudinal counterpart and is instead similar to the mean-free path. This …

Majorana Bound States In A D-Wave Superconductor Planar Josephson Junction, Hamed Vakili, Moaz Ali, Mohamed Elekhtiar, Alexey Kovalev

Department of Physics and Astronomy: Faculty Publications

We study phase-controlled planar Josephson junctions comprising a two-dimensional electron gas with strong spin-orbit coupling and d-wave superconductors, which have an advantage of a high critical temperature. We show that a region between the two superconductors can be tuned into a topological state by the in-plane Zeeman field, and can host Majorana bound states. The phase diagram as a function of the Zeeman field, chemical potential, and the phase difference between superconductors exhibits the appearance of Majorana bound states for a wide range of parameters. We further investigate the behavior of the topological gap and its dependence on the …

Toward Low Carbon Footprint And Lightweight Masonry Alkali-Activated Material, Zina Ebrahim, Mohammad Mastali, Marc Maguire

Durham School of Architectural Engineering and Construction: Faculty Publications

The portland cement concrete industry and the masonry industry are undergoing changes in response to skilled labor shortages and concerns over climate and pollution. There may be interest from parts of the industry in lower carbon footprint and lightweight masonry products. Toward this aim, the use of hemp shiv--the woody core of the hemp plant--in alkali-activated concrete was investigated herein and shown to have a wide range of impacts on the hardened state characteristics of a material suitable for structural concrete masonry units (CMUs) in accordance with ASTM C90 requirements. Hemp shiv is well known for its use in hempcrete, …

Point Heat Source Correlation To Microstructural Evolution In Advanced Manufacturing, Mark Anderson

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Although there are different ways that advanced manufacturing can be performed, the use of single-point heat sources has become the standard to control a final product’s properties. It is imperative to understand how the heat source used in the different advanced manufacturing processes affect the microstructure of interest. The intimate relationship between the heat source and microstructure allows for controlling and tailoring a part’s properties. Utilizing different microstructural analysis, the cross-correlation of various point heat sources to developed microstructure was conducted in this dissertation.

Laser powder bed fusion allows for unique print-to-part protocols, but the dynamics of the process makes …

Design Of A Miniature Robotic Surgery Technology Demonstration Payload For Orbital Spaceflight, Rachael Wagner

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This thesis describes the design of a technology demonstration payload that will test robotic surgery while aboard a 2024 expedition of the International Space Station (ISS). The payload utilizes a new miniature surgical robot to complete simulated surgical tasks on orbit, both autonomously and while remotely controlled by an Earth-based user. The experiment investigates the effects of microgravity and latency on robotic surgery, with the following goals:

1. Demonstrate the use of a miniature robotic surgical system in microgravity through performing simulated surgical tasks.

2. Quantify the effects of microgravity on robotic surgical techniques including forces, torques, and kinematic accuracy. …

Blood Flow Regulates Atherosclerosis Progression And Regression, Morgan A. Schake

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Atherosclerosis is the most prevalent pathology of cardiovascular disease with no known cure. Despite the many systemic risk factors for atherosclerosis, plaques do not form randomly in the vasculature. Instead, they form around bifurcations and the inner curvature of highly curving arterial segments that contain so-called disturbed blood flow that is low in magnitude and multidirectional over the cardiac cycle. Conversely, straight, non-bifurcated arterial segments that contain moderate-to-high and unidirectional (i.e., normal) blood flow are protected from plaque development. Thus, blood flow is a key regulator of atherosclerosis that may be able to be leveraged to develop new therapeutics. Towards …

Assessment Of Bridge Pier Response To Fire, Vehicle Impact, And Air Blast, Chen Fang, Qusai Alomari, Daniel G. Linzell

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Highway bridges exposed to intentional or unintentional fire followed by combined vehicle impact and air blast are at risk of significant damage and, possibly, collapse. Limited studies examining the complex effects of these extreme demands on bridge support elements and parametrizing their response and damage are found in the open literature. Research that is presented is part of an ongoing numerical investigation examining round, multi-column, reinforced concrete (RC), bridge pier behavior subject to multi-hazard scenarios involving fire, vehicle impact, and air blast. Detailed nonlinear finite element analysis models of single columns and multi-column piers supported by a pile foundation system …

Parametric Modeling Of Biomimetic Sharkskin For Wire Edm For Drag Reduction And Hydrophobicity, Joel Maxwell

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

This research sets out to demonstrate the viability of parametric modeling for biomimetic sharkskin in the effort to reduce drag and create a self-cleaning surface. Multiple designs were created to be machined by Wire EDM on stainless steel and titanium and were comparatively tested. Limitations of current manufacturing processes to economically produce naturally occurring structures such as sharkskin, emphasize the need to be able to calculate the most accurate design for a given manufacturing process. By designing a simplified but parametrically consistent model compared to an accurately depicted 3D model of sharkskin, the textured samples produced can be further tested …

Prediction Of Meltpool Depth In Laser Powder Bed Fusion Using In-Process Sensor Data, Part-Level Thermal Simulations, And Machine Learning, Grant King

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The goal of this thesis is the prevention of flaw formation in laser powder bed fusion additive manufacturing process. As a step towards this goal, the objective of this work is to predict meltpool depth as a function of in-process sensor data, part-level thermal simulations, and machine learning. As motivated in NASA's Marshall Space Flight Center specification 3716, prediction of meltpool depth is important because: (1) it can serve as a surrogate to estimate process status without the need for expensive post-process characterization, and (2) the meltpool depth provides an avenue for rapid qualification of microstructure evolution. To achieve the …

Scaling Cellular Agriculture Production With Photolithography: A Study On Curing And Degradation, Alexis Garrett

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

To meet the requirements for full production in cellular agriculture, a multi-disciplinary approach is required. New questions and understandings between different concepts, such as texture and cooking, need to be identified and how they correlate with cellular behavior and taste. This work focuses on understanding and developing photolithographic systems for scalable cellular agriculture. There were two specific research directions: 1) a traditional photolithography printing system was improved upon for mass manufacturing purposes and 2) mechanical analysis and degradation of key potential photolithographic biomaterials were tested for a food product. A novel digital rotational ultraviolet manufacturing (DRUM) process was developed, and …