Engineering Commons^™

Enhancing The Durability And The Service Life Of Asphalt Pavements Through Innovative Light-Induced Self-Healing Materials, Marwa Hassan

Data

Corresponding data set for Tran-SET Project No. 17BLSU02. Abstract of the final report is stated below for reference:

"The objective of this study was to evaluate the efficiency of a new generation of Ultraviolet (UV) light-induced self-healing polymers in enhancing the durability and self-healing properties of asphalt mixtures. Self-healing polymers were successfully synthesized in the laboratory and were characterized using Fourier Transform Infrared Spectroscopy (FTIR). In addition, Thermogravimetric Analysis (TGA) results showed that the synthesized polymers achieved the required thermal stability to resist asphalt mixture production processes. Viscosity results showed that addition of 5% Recycled Asphalt Shingle (RAS) and/or 20% …

Development Of A Self-Healing And Rejuvenating Mechanisms For Asphalt Mixtures Containing Recycled Asphalt Shingle, Marwa Hassan

Data

Corresponding data set for Tran-SET Project No. 17BLSU06. Abstract of the final report is stated below for reference:

"The objective of this study was to test the hypothesis that hollow-fibers encapsulating a rejuvenator product could improve both self-healing, rejuvenation, and mechanical properties of asphalt mixtures. Hollow-fibers containing a rejuvenating product were synthesized via a wet spinning procedure with sodium-alginate polymer as the encapsulating material. An optimization of the production parameters for the synthesis of fibers was performed to develop fibers suitable for high-temperature and shear stress environment typical of asphalt mixture production. A self-healing experiment was conducted to evaluate the …

Integrated Health Monitoring And Reinforcement Of Transportation Structures With Optimized Low-Cost Multifunctional Braided Cables, Ibrahim Karaman, Darren Hartl

Data

Corresponding data set for Tran-SET Project No. 17STTAM04. Abstract of the final report is stated below for reference:

"Corresponding data set for The objective of this research study is to design, fabricate, and characterize multifunctional high strength and self-sensing braided cables and structures using novel Fe-based shape memory alloys (SMAs). The system exploits unique properties of recently developed low-cost super-elastic FeMnAlNi SMAs, which enables excellent super-elastic properties, high strength, and self-sensing in structural health monitoring (SHM) systems. This novel material technology can be coupled with modeling efforts that allow for accurate prediction of both the materials and structural response during …

Development Of A Self-Powered Structural Health Monitoring System For Transportation Infrastructure, Aydin Karsilaya, Samer Dessouky, Athanassios Papagiannakis

Data

Corresponding data set for Tran-SET Project No. 17PTAM03. Abstract of the final report is stated below for reference:

"Roadways and bridges play an important role in the economic and social health of society by connecting commerce and people. Economic growth and population expansion pose considerable burden on the aging infrastructure (i.e., pavements and bridges). There is a pressing need to develop structural health monitoring (SHM) technologies capable of collecting infrastructure utilization data. Doing so inexpensively with self-powered systems will revolutionize infrastructure monitoring technology, and will improve decision making enabling roadway and bridge preservation. In this study, a self-powered battery-less structural …

Use Of Ultra-High-Performance Fiber-Reinforced Concrete (Uhp-Frc) For Fast And Sustainable Repair Of Pavements, Shih-Ho Chao

Publications

This research presents a new methodology, which enables streets, roads, highways, bridges, and airfields to use an advanced fiber-reinforced concrete material, which can delay or prevent the deterioration of these transportation infrastructure when subjected to traffic and environmental loadings. The major problem of concrete is its considerable deterioration and limited service life due to its brittleness and limited durability. As a result, it requires frequent repair and eventual replacement, which consumes more natural resources. Ultra-high-performance fiber-reinforced concrete (UHP-FRC) introduces significant enhancement in the sustainability of concrete structures due to its dense microstructure and damage-tolerance characteristics. These characteristics can significantly reduce …

A Comprehensive Reliability-Based Framework For Corrosion Damage Monitoring And Repair Design Of Reinforced Concrete Structures, Homero Castaneda, Aydin Karsilaya, Ayman Okeil, Mahmoud Reda Taha

Publications

In this work, we developed a comprehensive framework for corrosion management of reinforced concrete (RC) structures. This framework includes critical steps of an effective approach to quantify the damage evolution as well as providing the timeframe for effective maintenance/repair strategies for corrosion assessment in RC structures. The framework included several activities including the use of indirect and direct inspection tools, theoretical development for damage prediction, experimental measurements and theoretical development of repair time based on reliability. The uniqueness of the framework is the integration of deterministic modeling of corrosion damage evolution by using mechanistic analysis with statistical modeling on corrosion …

Evaluation Of Comparative Damaging Effects Of Multiple Truck Axles For Flexible Pavements, Stefan Romanoschi, Athanassios Papagiannakis

Publications

This study aims at evaluating the effect of overlapping flexible pavement strain responses from truck axles that are not part of multiple axle configurations (i.e., tandem, triple and quad). For this purpose, a newly constructed pavement was instrumented with strain gauges installed at the bottom of the asphalt concrete base layer on US-287 south of Mansfield, TX. This pavement structure is typically used for medium- to high-volume roads in the South-Central region of the United States. The strain gauges were used to measure longitudinal and transverse strains under several passes of a test vehicle. This was a class 6 truck …

A Systematic Investigation Of Condensation Heat Transfer Using Asymmetric Micro-Scale Surfaces, Emily Brown

LSU Master's Theses

Asymmetric surfaces been shown to inducing unidirectional motion in the Leidenfrost regime; however, very minimal research has been conducted to investigate whether these surface can enhance condensation through the same means. The investigation of heat transfer of ratchets in condensation is a relatively untapped area of study, specifically ratchets with superhydrophobic properties. Anticipated difficulty lies in creating surfaces features or coatings that retain the ratchets and can adequately sustain optimal wetting state of Cassie-Baxter required to improve heat transfer performance during condensation. This study serves to investigate whether ratchets are a feasible surface feature to enhance condensation heat transfer. First, …

Novel Design And Synthesis Of Composite Nanomaterials For Lithium And Multivalent Ion Batteries, Wangwang Xu

LSU Doctoral Dissertations

Nowadays, the fast-increasing energy demand for efficient, sustainable and environmentally-friendly energy storage devices remains a significant and challenging issue. Lithium ion batteries (LIBs) have been widely used as commercial energy devices in portable electronics and also shown great promise in upcoming large-scale applications due to their advantages of environmental safety, efficiency in energy delivering and light weight. However, due to their limited capacity, energy densities and cycle ability, LIBs still need further improvement to expand their applications to a larger field, especially electric vehicle (EVs) and hybrid electric vehicles (HEVs), in which energy storage devices with large capacity and high …

Self-Healing Microcapsules As Concrete Aggregates For Corrosion Inhibition In Reinforced Concrete, Homero Castaneda, Marwa Hassan, Miladin Radovic, Jose Milla

Publications

Reinforced Concrete (RC) structures are vital to the US’s civil infrastructure for their strength and versatility. Unfortunately, RC elements deteriorate rapidly when exposed to corrosive environments. One possible solution is to extend the life of RC elements and systems using microencapsulated corrosion inhibitors to reduce the rebar corrosion rate. The capsules house an anodic corrosion inhibitor agent including calcium nitrate (CN) and triethanolamine (TEA). The integration of such microencapsulated materials will enhance the durability and extend the useful life by controlling the corrosion precursors and the corrosion process during damage evolution. Therefore, this work aims to develop and characterize the …

Hyperspectral Imaging For Characterizing Single Plasmonic Nanostructure And Single-Cell Analysis, Nishir Sanatkumar Mehta

LSU Master's Theses

Orientation of plasmonic nanostructures is an important feature in many nanoscale applications such as photovoltaics, catalyst, biosensors DNA interactions, protein detections, hotspot of surface-enhanced Raman spectroscopy (SERS), and fluorescence resonant energy transfer (FRET) experiments. Silver nanocubes with significant spectral signatures between 400-700 nm are observed in this experimental research. Whereas study of single cells will enable the analysis of cell-to-cell variations within a heterogeneous population. These variations are important for further analysis and understanding of disease propagation, drug development, stem cell differentiation, embryos development, and how cells respond to each other and their environment. Adipose-derived mesenchymal stem cells possess the …

Use Of Rice Hull Ash (Rha) As A Sustainable Source Of Construction Material, Zahid Hossain, Ashraf Elsayed

Publications

With the imminent shortage of natural resources, the need to find sustainable development is the highest in recent history. Therefore, this study examines the potential uses of Rice Hull Ash (RHA) as a sustainable cementitious material (SCM) in preparation of concrete. This study also assesses the use of RHA as an alternative of commonly used polymers in preparing high-grade asphalt binders. RHA is a potential sustainable solution because it is currently being treated as an agricultural waste material, yet its high silica content makes it a potential construction material. Three different sizes of RHA (600 µm, 150 µm, and 44 …

Use Of Nanoclays As Alternatives Of Polymers Toward Improving Performance Of Asphalt Binders, Zahid Hossain, Ashraf Elsayed

Publications

The main goal of this study is to assess the feasibility of the use of nanoclay as an alternative to commonly used polymers such as styrene-butadiene-styrene (SBS), which are used to modify the performance grade (PG) of asphalt binders. Three types of nanoclay and two types of neat binders were selected for laboratory investigation. Different amounts (1, 2, and 3%) of nanoclays were used. A blending protocol has been developed to mix the nanoclay with the asphalt binder. Rotational Viscosity (RV), Dynamic Shear Rheometer (DSR), Optical Contact Analyzer (OCA) and Atomic Force Microscope (AFM) were conducted to evaluate the properties …

Development Of A Self-Healing And Rejuvenating Mechanisms For Asphalt Mixtures Containing Recycled Asphalt Shingle, Marwa Hassan

Publications

The objective of this study was to test the hypothesis that hollow-fibers encapsulating a rejuvenator product could improve both self-healing, rejuvenation, and mechanical properties of asphalt mixtures. Hollow-fibers containing a rejuvenating product were synthesized via a wet spinning procedure with sodium-alginate polymer as the encapsulating material. An optimization of the production parameters for the synthesis of fibers was performed to develop fibers suitable for high-temperature and shear stress environment typical of asphalt mixture production. A self-healing experiment was conducted to evaluate the healing/rejuvenation capabilities of sodium-alginate fibers in asphalt mixtures with varying types of binders and recycled materials. Based on …

Impacts Of Moisture On Asphalt Properties, Zahid Hossain

Publications

Stripping related moisture damage has been recognized as one of the major pavement distresses since the early 1990s. The main objective of this study is to establish an effective test protocol to quantify moisture susceptibility of asphalt pavements. To this end, selective test methods (Texas Boiling test, Tensile Strength Ratio, Retained Stability, and Hamburg Wheel Test), and procedures based on surface chemistries and molecular-level mechanistic properties have been investigated in this study. Firstly, a comprehensive list of literature related to moisture damage in asphalts was reviewed. Based on the literature review, a detailed project plan and test matrix were developed. …

Evaluation Of The Performance And Cost-Effectiveness Of Engineered Cementitious Composites (Ecc) Produced From Region 6 Local Materials, Gabriel Andres Arce Amador, Tyson Rupnow, Marwa Hassan

Publications

The project objective is to develop cost-effective Engineered Cementitious Composites (ECC) with locally available ingredients in Region 6 to address the deficiencies observed in ordinary concrete materials. The study explored the utilization of two types of river sands (coarse and fine), two types of PVA fibers (long and short), four levels of cement replacement with Class F fly ash, and the implementation of recycled crumb rubber in the performance of ECC materials. A total of 24 mix designs were prepared and evaluated in compression, tension, and bending to assess its mechanical properties. Furthermore, the cracking characteristics of the materials produced …

Enhancing The Durability And The Service Life Of Asphalt Pavements Through Innovative Light-Induced Self-Healing Materials, Marwa Hassan

Publications

The objective of this study was to evaluate the efficiency of a new generation of Ultraviolet (UV) light-induced selfhealing polymers in enhancing the durability and self-healing properties of asphalt mixtures. Self-healing polymers were successfully synthesized in the laboratory and were characterized using Fourier Transform Infrared Spectroscopy (FTIR). In addition, Thermogravimetric Analysis (TGA) results showed that the synthesized polymers achieved the required thermal stability to resist asphalt mixture production processes. Viscosity results showed that addition of 5% Recycled Asphalt Shingle (RAS) and/or 20% Reclaimed Asphalt Pavement (RAP) caused an increase in the viscosity of the binder blends. However, a reduction in …

Development Of A Standard Test Method For Characterization Of Asphalt Materials And Aging-Related Degradation Using An Extensional Rheometer, Nazimuddin Wasiuddin

Publications

An extensional deformation test method using a Sentmanat Extensional Rheometer (SER) fixture inside a Dynamic Shear Rheometer (DSR) is developed in this study to investigate the degradation of the polymer due to aging and to investigate the effect of modifier type. A relationship between different percentages of modifier and ductility of the modified binder is also investigated. The sample geometrics used in this study are 1 mm x 0.72 mm and 3 mm x 0.72 mm. A total of one hundred and sixty-two samples were tested. Three modifiers Styrene-Butadiene-Styrene (SBS), Polyphosphoric Acid (PPA) and latex were used. One PG 76-22, …

Bridge Deck Overlays Using Ultra-High Performance Concrete, Craig Newtson, Brad Weldon

Publications

This study investigated the use of a locally produced ultra-high performance concrete (UHPC) as an alternative to typical overlay materials. Several bond strength tests including slant-shear, splitting tension, and direct tension tests were performed to assess the bond strength between UHPC and normal strength concrete (NSC) substrate with varying surface textures. Tests were also conducted to assess the early-age and longer-term shrinkage behavior and coefficient of thermal expansion of the UHPC as well as rapid chloride permeability testing. Good bond between UHPC and NSC substrate was observed even with inadequate surface texture. Combined shrinkage and thermal effects were investigated for …

Chemically Modified Cellulosic Materials As Multi-Functional Agents In Polymer Composites, Jinlong Zhang

LSU Doctoral Dissertations

Comparative flame retardancy of micro wood fiber plastic composites (WPCs) with fire retardants (1,2-bis(pentabromophenyl) ethane, metal hydroxides and nanoclay) was studied. The fire additives (1,2-bis(pentabromophenyl) ethane as well as magnesium hydroxide) obviously enhanced the fire retarding properties of WPCs. Especially, 1,2-bis(pentabromophenyl) ethane significantly reduced the total heat release as well as heat release rate. In addition, a synergistic effect of 1,2-bis(pentabromophenyl) and nanoclay was achieved for the enhanced fire retarding performance of WPCs.

A copolymer of cellulose nanocrystals (CNCs) and poly(N-vinylcaprolactam) (PVCL) (PVCL-g-CNCs) for use as thermally-responsive polymers with low critical solution temperatures (LCSTs) was synthesized via atom transfer radical …

Electrocatalytic Properties Of Ni-Fe Basedalloys Toward Oxygen Evolution Reaction, Xiaodan Cui

LSU Doctoral Dissertations

In this dissertation, laser-based manufacturing was applied to develop NiFe-based alloys, with focus on their electrochemical characteristics toward oxygen evolution reaction during water electrocatalysis. The targeted electrocatalysts were designed by combining catalysis principles of absorption energy, electronic effect and geometry effect. Firstly, a one-step laser-based manufacturing method was applied to prepare a thin layer of NiFe-based electrodes with varied Ni to Fe ratios to replace high-cost noble metals as the electrocatalyst for oxygen evolution reaction (OER). Since each Ni has 0.6 d-vacancy and each Fe atom has 2.2 d-vacancies. The alloying of Ni-Fe allows electrons flowing from Ni to Fe, …

Radiation Effects In Apatite And High Entropy Alloy Under Energetic Ions And Electrons, Jianren Zhou

LSU Doctoral Dissertations

Radiation effects in apatite and high entropy alloy under energetic ions and electrons are studied in this doctoral dissertation to develop advanced crystalline ceramic waste forms and nuclear structural materials. Apatite is proposed as a ceramic waste form for the immobilization of radionuclides, but its performance is strongly affected by the irradiation of the incorporated radionuclides. It is thus important to understand the radiation effects in apatite structure and the underlying physics. Effects of chemical composition, grain size, interfacial structure, as well as radiation conditions on the microstructural evolution, phase transformation and damage mechanisms of apatite under alpha-decay and beta-decay …

Microstructural Characterization Of Shear Transformation Zones And Modeling Indentation Size Effect In Amorphous Polymers, Leila Malekmotiei

LSU Doctoral Dissertations

The first aim of this work is developing a procedure for experimental and analytical characterization of nano-scale microstructures which mediate large scale deformation in amorphous polymers. Glassy polymers are extensively used as high impact resistant, low density, and clear materials in industries. Nevertheless, their response under severe loading conditions is yet to be appropriately unraveled. Due to the lack of long-range order in the microstructures of glassy solids, their plastic deformation is different from that in crystalline solids. Shear Transformation Zones (STZs) are believed to be the main plasticity carriers in amorphous solids and defined as the localized atomic or …

Voltage-Controlled Deposition Of Nanoparticles For Next Generation Electronic Materials, Subhodip Maulik

LSU Doctoral Dissertations

This work presents both a feasibility study and an investigation into the voltage-controlled spray deposition of different nanoparticles, namely, carbon nanotubes (CNTs), as well as molybdenum disulfide (MoS₂) and tungsten disulfide (WS₂) from the transition metal dichalcogenides (TMDCs) family of materials. The study considers five different types of substrates as per their potential application to next-generation device electronics. The substrates selected for this research were: 1) aluminum as a conducting substrate, 2) silicon as a semiconducting substrate, 3) glass, silicon dioxide (SiO₂), and syndiotactic poly methyl methacrylate (syndiotactic PMMA) as insulating substrates.

Since the …

Nanostructured Materials Derived From Metal-Organic Frameworks For Energy And Environmental Applications, Zhiqiang Xie

LSU Doctoral Dissertations

Nowadays, energy and environmental issues have become the top priority among a series of global issues. Fossil fuels as the dominant source are depleted fast and usually lead to some environmental problems. Heavy metal pollution has posed a severe threat to environment and public health. Metal-organic frameworks (MOFs), as a very promising category of porous materials, have attracted more and more interest in research communities due to their extremely high surface areas, diverse nanostructures and unique properties. To meet the ever-increasing energy demand and tackle the heavy metal pollution in water, MOFs can function as ideal templates to prepare various …

Waste Management By Waste: Removal Of Acid Dyes From Wastewaters Of Textile Coloration Using Fish Scales, S M Fijul Kabir

LSU Master's Theses

Removal of hazardous acid dyes by economical process using low-cost bio-sorbents from wool industry wastewaters is of a pressing need, since it causes skin and respiratory diseases and disrupts other environmental components. Fish scales (FS), a by-product of fish industry, a type of solid waste, are usually discarded carelessly resulting in pungent odor and environmental burden. In this research, the FS of black drum (Pogonias cromis) were used for the removal of acid dyes (acid red 1 (AR1), acid blue 45 (AB45) and acid yellow 127 (AY126)) from wool industry wastewaters by absorption process with a view to …