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Articles 1 - 30 of 72
Full-Text Articles in Engineering
Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan
Optic Properties On Aggase2 Polycristal Fabrication, A. Harsono Soepardjo, I Dewa Made Janusetiawan
Makara Journal of Technology
Optic Properties on AgGaSe2 Polycristal Fabrication. Polycristal AgGaSe2, is compound (I-III-VI2) a semiconductor as basic material for thin film for solar cell. Polycristal was succesfully grown using Bridgmann Method, heated on sequential temperature treatment until 850°C and cooled down slowly until room temperature. Results observed were in the form of ingot (bars) with more or less 3 cm length and 13 mm in diameter. By using X-Ray Fefraction, composition obtained of each element (weight %) was Ag = 29,3996 %, Ga = 36,8123 % and Se = 30,29 % while using X-Ray Difraction lattice parameter obtained/calculated a = 4,4112 Å, …
Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty
Modelling And Simulation Of Packed Bed Catalytic Converter For Oxidation Of Soot In Diesel Powered Vehicles Flue Gas, Mohammad Nasikin, Praswasti P.D.K. Wulan, Vita Andrianty
Makara Journal of Technology
Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered Vehicles Flue Gas. Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel soot that can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension of catalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along the catalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic condition based on a kinetic study that …
Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto
Fuel Injection System For One Cylinder Motor Cycle Engine, Bambang Sugiarto
Makara Journal of Technology
Fuel Injection System for One Cylinder Motor Cycle Engine. Fuel injection has been developed for many years. But its common application is limited on car’s engine. With many reason fuel injection systems in motorcycle one cylinder engine has not been widely used yet. Fuel Injection System allows the amount of fuel, injected to be controlled appropriate to engine parameters such as engine speed, amount of air inducted to cylinder, temperature, for each cycle, over the entire engine operating conditions. This fuel injection research is done to find out the Volumetric Efficiency of the intake manifold system, the amount of fuel …
The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo
The Effects Of Influent Debit On Hydrodynamic Characteristic Of Bojongsoang Facultative Pond: Without Wind Effects, Rositayanti Hadisoebroto, Suprihanto Notodarmojo
Makara Journal of Technology
The Effects of Influent Debit on Hydrodynamic Characteristic of Bojongsoang Facultative Pond: Without Wind Effects. The performance of facultative pond in Bojongsoang WWTP have reported to be unstable. One of the cause of the unstable performance is the hydrodynamic characteristics that not met the criterion. The improper hydrodynamic characteristics are included the existence of dead-zone, the short-circuiting, and the turbulence due to eddy current. The study was to analyze the effect of the influent debit variation on the hydrodynamic characteristics of the pond using mathematical model. The two-dimensional hydrodynamic model was built from two hydrodynamic equations which are continuity and …
Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo
Influence Of Connection Placement To The Behavior Of Precast Concrete Exterior Beam-Column Joint, Elly Tjahjono, Heru Purnomo
Makara Journal of Technology
Influence of Connection Placement to the Behavior of Precast Concrete Exterior Beam-Column Joint. This paper presents an experimental study on the influence of connection placement to the behaviour of exterior beamcolumn joint of precast concrete structure under semi cyclic loading. Four half-scale beam-column specimens were investigated. Three beam-columns were jointed through connection that are placed in beam-column joint region and the forth is connected at the plastic hinge potensial region of the beam. Crack patterns, strength, stiffness and ductility of the test specimens have been evaluated. The test result indicated that all beam-column specimens show good ductility behavior.
Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang
Electrochemical Behaviours Of Hemoglobin-Ddab-Modified Powder Microelectrode And The Application Of The Powder Microelectrode In Determination Of Nitric Oxide, Zhi-Mou Guo, Huan Liu, Jian Chen, Wen-Ting Zhang
Journal of Electrochemistry
The electrochemical behaviours of DDAB-Hb-PME were studied in this paper. The (apparent) surface concentration of Hb was enhanced greatly by using the powder microelectrode (technique). NO reacts with Hb and absorbs on the surface of the modified carbon powder. Therefore, the output of the electrode was enhanced greatly by employing PME with higher reaction surface (area). The sensitivity of DDAB-Hb-PME is 3.1 mA/μmol·L~(-1)·cm~(2), which is much larger than the values obtained with the traditional electrodes. The detection limit is 9 nmol·L~(-1) and the linear response range is 9～100 nmol·L~(-1).
Electrochemical Investigations On Pitting Susceptibility Of Iron-Based Alloy, Wei-Shan Li, Hong-Yu Chen, Zhong-Zhi Yuan, Hong Li, Qi-Ming Huang, Dong-Sheng Lv
Electrochemical Investigations On Pitting Susceptibility Of Iron-Based Alloy, Wei-Shan Li, Hong-Yu Chen, Zhong-Zhi Yuan, Hong Li, Qi-Ming Huang, Dong-Sheng Lv
Journal of Electrochemistry
The formation process of passive film on iron and electronic properties and pitting susceptibility of an iron-based alloy are investigated by using linear potential sweep, alternative current impedance and electrochemical nose technologies. The relationship between reciprocal square capacitance and potential following the Mott-Schottky behavior is limited at a narrow rang of low potentials. At higher potentials, linear relationship between reciprocal capacitance and potential is obtained, which is ascribed to the increasing thickness of the passive film with potential. The donor density of the passive film is influenced by the formation potential of the film, passivator and microstructure. The decrease in …
Preparation And Photo-Catalyst Properties Of The Α-Fe_2o_3-Tio_2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen
Preparation And Photo-Catalyst Properties Of The Α-Fe_2o_3-Tio_2 Films On Sodium Alginate Polymer, Li-Qin Chen, Huai-Zhen Zhong, Ri-Yao Chen, Xi Zheng, Zhen Chen
Journal of Electrochemistry
Three new nano thin films of α-Fe_2O_(3)、TiO_2 and α-Fe_2O_(3)-TiO_2 by doping their powder with sodium alginate polymer were prepared. Surface structure and catalytic activities of the films were characterized by FTIR、XRD、PL、TEM and I-V techniques. The results of UV-visible absorption showed that the methylene blue was mineralized in aqueous of α-Fe_2O_(3)/SA、TiO_2/SA and (α-(Fe_2O_(3)))-TiO_2 /SA upon radiation with ultra violet light. α-Fe_2O_(3) enhanced their photo-decolorized-activities by doping 15% TiO_2.
Effect Of Fe~(3+) Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang
Effect Of Fe~(3+) Dopen Of Titanium Dioxide Film On Absorption Spectra And Photo Catalysis, Mei-Qun Xiao, Jia-Nian Shen, Moucheng Li, Peng-Fei Wu, Dong Liu, Yu-Juan Zhang
Journal of Electrochemistry
Photo-catalytic titanium dioxide film in nano crystalline has been prepared by electrochemical oxidation process and adding different amount of ferric ion into the electrolyte during the anodic oxidation.The effects of Fe~(3+) dopen on absorption spectra and photo-catalytic of the titanium dioxide films have been studied. It shows that the Fe~(3+) dopen caused the red shife of the absorption edge for the incoming light and exhibited the improved photocatalytic reactivity.
Studies On The Electrochemical Preparation And Electrochemical Properties Of Conducting Polymers——Brief Introduction To The Research Work Of Electrochemistry Of Conducting Polymers In Cas Key Laboratory Of Organic Solids(I), Yong-Fange Academy Of Sciences Li
Studies On The Electrochemical Preparation And Electrochemical Properties Of Conducting Polymers——Brief Introduction To The Research Work Of Electrochemistry Of Conducting Polymers In Cas Key Laboratory Of Organic Solids(I), Yong-Fange Academy Of Sciences Li
Journal of Electrochemistry
Conducting polymers have drawn much attention since the discovery of conducting polyacetylene in 1977, due to the novelty and curiosity of their structure and properties as well as their promising applications in many aspects. Among the studies of conducting polymers, the electrochemical preparation and electrochemical properties of conducting polymers are of special importance, because the electropolymerization is a main method for preparing conducting polymer films and the electrochemical properties are the basis for their applications in the fields of electrode materials for batteries, electrocatalysis, electrochromic display, etc. We are one of the earliest research groups in the world to perform …
Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma
Electrocatalytic Performances Of Carbon Nanotube Air Electrode For Oxygen Reduction, Feng-Ming Zhao, Chun-An Ma
Journal of Electrochemistry
The air electrodes with different mass ratio of Pt/active carbon or carbon nanotube as catalyst layer material have been prepared. The electrocatalytic performances for oxygen reduction were evaluated by means of polarization curve and electrochemical impedance spectroscopy (EIS). The results disclosed that carbon nanotubes dealt with nitric acid in the catalyst layer had been improved obviously on the electrocatalytic activity. After the surface of carbon nanotube was oxygenated and aggraded with platinum, the catalyst had obviously effects on the electrocatalytic activity. The air electrode with the mass ratio of active carbon to Pt/carbon nanotube in 4∶1 showed better electrocatalytic activity, …
The Investigation Of Bafesi/C Alloy Composite As Anode Materials For Li-Ion Battery, Rui-Xiang Feng, Hua Dong, Xin-Ping Ai, Han-Xi Yang
The Investigation Of Bafesi/C Alloy Composite As Anode Materials For Li-Ion Battery, Rui-Xiang Feng, Hua Dong, Xin-Ping Ai, Han-Xi Yang
Journal of Electrochemistry
A novel BaFeSi/C composite was prepared by mechanical ball milling, and lithium insertion reactions on the composite electrode were investigated by cyclic voltammetry ,charge-discharge measurements, XRD and XPS spectroscopy. It is demonstrated that the capacity retention with indiscernible capacity decas during charge-discharge cycling. The improved cycling ability of the composite is suggested from a cooperative action by inactive FeSi_(2 )and BaSi_2 matrix and outer graphite shell, which both buffer the volumetric changes of the active Si phase and provide a good connection for electronic and ionic conduction during lithium insertion and extraction processes.
Lico_(X)Ni_(1-X)O_2 Cathode Materials Prepared By Electrolysis Of Co And Ni, Jin-Ping Wei, Xin Sun, Xiao-Yu Wang, Xi-Kui Bian, Jin-Ling Zhai, Yan-Jie Yan-Jie
Lico_(X)Ni_(1-X)O_2 Cathode Materials Prepared By Electrolysis Of Co And Ni, Jin-Ping Wei, Xin Sun, Xiao-Yu Wang, Xi-Kui Bian, Jin-Ling Zhai, Yan-Jie Yan-Jie
Journal of Electrochemistry
A new electrolytic method was developed to prepare LiCo_(x)Ni_(1-x)O_2 as a cathode material of lithium-ion battery. Contrary to the traditional method, electrolytic method is a potential method with simple process to industrialization and no pollution. Metal cobalt and nickel were electrolysed in parallel to prepare the precursor of Co_( x )Ni_(1- x )(OH)_2.Different compositional precursors could be conveniently prepared by changing electrolytic current. The LiCo_(0.3)Ni_(0.7)O_2 cathode prepared by this method was found favorable charge-discharge and cycle properties. For the LiCo_(0.3)Ni_(0.7)O_(2 )cathode material, the discharge capacities in the 1st and 50th cycles were 163 mAh/g and 140 mAh/g with charge retention …
Study On Mass Transport In Liquid Layer Adjacent To The Electrode Through Transmission Vop-Spectroellipsometry, Wei Zhu, Yangyu-Ru Yangyu-Ru, Zong-Qing Huang
Study On Mass Transport In Liquid Layer Adjacent To The Electrode Through Transmission Vop-Spectroellipsometry, Wei Zhu, Yangyu-Ru Yangyu-Ru, Zong-Qing Huang
Journal of Electrochemistry
In electrochemical system, the mass transport process in liquid layer adjacent to electrode is studied through theoretical analysis only.The diffusion process can be analyzed theoretically by Fick's law for homogeneous media. Up to now, none of satisfied experimental method has been reported for studying mass transport of a whole process in liquid media yet. This paper described the experimental approach to explore mass transport in electrochemical system by transmission Vop-spectroellipsometry briefly.
Improvement And Its Mechanism Of Storage Performance Of Ni-Mh Battery, Xiao-Feng Li
Improvement And Its Mechanism Of Storage Performance Of Ni-Mh Battery, Xiao-Feng Li
Journal of Electrochemistry
The storage performance of nickel-metal-hydride (Ni-MH) battery was studied by using galvanostatic charge-discharge and cyclic voltammetry. The experimental results indicated that CoOOH could not be completely restored after its being thoroughly reduced at lower potential, which might weaken electric conduction network in the positive electrode and result in fading of electrochemical properties of Ni-MH battery. Addition of nickel powder as a conductive agent into the positive electrode was beneficial to the capacity recovery after storage.
Preparation And Electrochemical Magnesium Insertion Behaviors Of Mgv_2o_6, Hua-Tang Yuan, Li-Fang Jiao, Jian-Sheng Cao, Xiu-Sheng Liu, Ming Zhao, Yong-Mei Wang
Preparation And Electrochemical Magnesium Insertion Behaviors Of Mgv_2o_6, Hua-Tang Yuan, Li-Fang Jiao, Jian-Sheng Cao, Xiu-Sheng Liu, Ming Zhao, Yong-Mei Wang
Journal of Electrochemistry
MgV_2O_6was synthesized by conventional solid-state reaction from MgO and V_2O_(5)as starting materials. X-Ray diffraction analysis showed that the prepared sample belongs to the monoclinic structure. Electrochemical magnesium insertion from aprotic electrolytes such as organomagnesium halides into this host was found possible and exhibited charge/discharge circulation.
Applications Of New Activated Carbon Meterials In The Electric Double-Layer Capacitor, Jian-Jun Zhang
Applications Of New Activated Carbon Meterials In The Electric Double-Layer Capacitor, Jian-Jun Zhang
Journal of Electrochemistry
A new type activated carbon whose precursor was coconut shell could be obtained using specific physics-chemistry activation, and the activated carbon was applied as the material of electrode in EDLC(electrical double-layer capacitor),which had a large specific capacitance,and could charge and discharged in some large currents. Carbon dioxide and acid were used to modify carbon,and the effects of post-treatment on surface area and pore volume were investigated. A moulding method which has influence on some properties of carbon electrode with PTFE additive was researched in the paper.
Preparation And Electrochemical Performance Of New Composite Seperators For Lithium-Ion Batteries, Hu Cheng, Hong-Yan Du, Yong Yang
Preparation And Electrochemical Performance Of New Composite Seperators For Lithium-Ion Batteries, Hu Cheng, Hong-Yan Du, Yong Yang
Journal of Electrochemistry
New composite seperators for lithium ion batteries were prepared by coating PEO mixed with nanosize SiO_(2)onto microporous polypropylene(PP) seperators. Highly conductive electrolytes were prepared by soaking them in an electrolyte solution. With these composite separators, the lithium ion cell consisting of Li anode and LiNi_(0.8)Co_(0.2)O_(2)cathode were assembled. The high initial discharge capacity and good capacity retention were obtained through the cell.
Preliminary Study Of Speek Membranes For Direct Methanol Fuel Cells Application, Su-Zhen Ren
Preliminary Study Of Speek Membranes For Direct Methanol Fuel Cells Application, Su-Zhen Ren
Journal of Electrochemistry
This paper describes the methanol permeability characterization of SPEEK membranes and their feasibility for DMFC application. The SPEEK membranes showed a significant lower methanol permeation than Nafion~115 determined from voltammetric methods. An increase in open circuit voltage was found in the performance of SPEEK membranes in DMFC. The power density of the cell using SPEEK membrane was considerably poorer than that of Nafion~115. If modified properly, the SPEEK membranes can be chosen for DMFC application based on this study.
The Electrochemical Behavior And Determination Of Gsh At The Powder Microelectrode, Jian Chen, Zhong-Yu He, Chuansin Cha, Huan Liu
The Electrochemical Behavior And Determination Of Gsh At The Powder Microelectrode, Jian Chen, Zhong-Yu He, Chuansin Cha, Huan Liu
Journal of Electrochemistry
In this paper, the electrochemical behavior of GSH at the surface of platinum(Pt) electrode, glass carbon(GC) electrode and acetylene black packed powder microelectrode (AB-PME) was studied. It was found that the electrochemical oxidations of GSH at both Pt and GC electrode were highly irreversible. No current peak or current plateau could be observed from the CV curves. The direct electro-oxidation of GSH at carbon surface was achieved by using the PME technique.In this case, the apparent reversibility of GSH oxidation was enhanced significatly .The overpotential of GSH oxidation was reduced to 0.5 V at the surface of AB-PME compared with …
Studies On The Electrochemical Behavior Of Copper Paratolysulfate And Its Complexes, Ji-Guo Song, Pei-Kang Shen
Studies On The Electrochemical Behavior Of Copper Paratolysulfate And Its Complexes, Ji-Guo Song, Pei-Kang Shen
Journal of Electrochemistry
Copper (II) paratolysulfate has been synthesized and characterized by thermo-gravimetric (TG) measurements and differential scanning calorimetric (DSC) analysis. This salt can easily lose all crystal water and the dehydrated salt does not deliquesce in the air. It is found for the first time that the complex of Cu(p-OTs)_(2)/ethanolamine(1∶1) can catalyze the oxidation of 1,1′-bi-2-naphthol in DMSO and DMF, while the process is difficult to perform in H_(2)O and CH_(3)OH. The electrochemical behaviors of both Cu(p-OTs)_(2) and its complexes with ethanolamine have been studied on platinum electrode in DMSO, DMF, (CH_(3)OH) and H_(2)O respectively. The complexes of various copper salts with …
Nucleation And Crystal Growth Of Pt Electrodeposition On Poly Crystal Au Microdisc Electrode, Zhi-Yong Tao, Pei-Fang Liu
Nucleation And Crystal Growth Of Pt Electrodeposition On Poly Crystal Au Microdisc Electrode, Zhi-Yong Tao, Pei-Fang Liu
Journal of Electrochemistry
Based on the Fleischmann's model of nucleation and crystal growth for electrodeposition combined with the Barradas-Bosco's adsorption-nucleation model for electrochemical phase formation, the chronoamperometry was well fitted for Pt deposition on polycrystalline Au micro disc electrodes (30 μm in diameter) in different H_(2)PtCl_(6) concentrations at different over-potentials. The initial stage of Pt deposition in dilute H_(2)PtCl_(6) could be interpreted by the model of H_(2)PtCl_(6 ) adsorption combined with instantaneous nucleation and two-dimensional cylindrical growth. The rate constant of the two-dimensional growth increased linearly with overpotential. Then the deposit grew layer by layer and the rate constant increased non-linearly with overpotential. …
Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma
Electrochemical Reduction Of Nitrobenzene On The Wc Electrode In Acidic Solution, Chun-An Ma
Journal of Electrochemistry
The tungsten carbide (WC) electrode was constructed by using polyterafluoroethylene as binder. The electrochemical behavior of nitrobenzene on the WC electrode in acidic solution was investigated by cyclic voltammetry, linear scan method and chronoamperometry. Experimental results showed that WC electrode had good activity for the electrochemical reduction of nitrobenzene, and the electrode process was controlled by diffusion and electrochemical stepssimultaneously. The apparent active energy of the electrode process is 23.7kJ mol~(-1), while the active energy of the electrochemicalstep is 10.91kJ mol~(-1).
Synthesis Of (S)-3-Phenylpropane-2-Tert-Butoxycarbonylamino- 1-Thiol And Its Electrochemical Behavior Self-Assembled On Gold, Sun Ru
Journal of Electrochemistry
The synthesis of (S)-3-Phenylpropane-2-tert-butoxycarbonylamino- 1-thiol(N-Boc-APT) from L-phenylalanine was reported. L-Phenylalanine was reduced to the corresponding amino alcohol, protection of the amino group using tert-butyl pyrocarbonate gave (S)-2-tert-butoxycarbonylamino-3-phenylpropane-1-ol, which was then O-mesylated and treated with potassium thioacetate in DMF to give 3-phenylpropane-2-tert- butoxycarbonylamino-1-etylmercapto. After the acetyl group was removed with ammonia in alcohol, the desired target molecular was obtained. The structure of intermediate and target molecular was conformed by IR and ~(1)HNMR. We made N-Boc-APT self-assemble-modificated gold electrode and investigated its electrochemical behavior. The CV results of methylene blue on nano-Au/N-Boc-APT SAM/Au electrode showed that nano-Au could speed this electron transfer …
Effects Of Barium On The Performance Of Secondary Alkaline Zinc Electrode, Yi Zheng, Jian-Ming Wang
Effects Of Barium On The Performance Of Secondary Alkaline Zinc Electrode, Yi Zheng, Jian-Ming Wang
Journal of Electrochemistry
The active material of secondary alkaline zinc electrode with barium additives was prepared by a chemical reaction method and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical performance of various pasted Zn electrodes was investigated by cyclic voltammetry, charge/discharge method and electrochemical impedance spectra (EIS) technology. The addition of barium can synthesize a compound barium zincate with the molecular structure of BaZn(OH)_(4)· xH_(2)O and improve the discharge performance. The EIS of the various Zn electrodes showed two time constants besides diffusion impedance, including a state variable representing the covering degree of discharge products on the electrode …
Solid State Synthesis And Electrocatalysis Of Pt/Moo_3 For The Oxidation Of Methanol, Wang Qing
Solid State Synthesis And Electrocatalysis Of Pt/Moo_3 For The Oxidation Of Methanol, Wang Qing
Journal of Electrochemistry
The electrocatalyst, Pt/MoO_(3) synthesized by solid state reaction, was used for the oxidation of methanol in direct methanol fuel cells. The X-Ray diffraction and cyclic voltammetry were employed to investigate the performance of the material. It was shown that the typical diffraction peaks for Pt appeared in XRD. And a good electrocatalysis for methanol oxidation was observed. The peak potential of the methanol oxidation appeared at ca. 0.63V(vs.SCE) and the peak current density for the oxidation was 78.1 mA cm~(-2) .
Synthesis And Electrochemical Behavior Of Layered-Structure Limn_(1-X)Cr_Xo_2, Jie Xiao, Hui Zhan, Yun-Hong Zhou
Synthesis And Electrochemical Behavior Of Layered-Structure Limn_(1-X)Cr_Xo_2, Jie Xiao, Hui Zhan, Yun-Hong Zhou
Journal of Electrochemistry
The Layered-structure LiMn_(1-x)Cr_xO_(2 )(x=0,0.15) solid solution has been prepared by the rheological phase method. From the XRD results, undoped LiMnO_(2) crystallized almost entirely in the orthorhombic phase while the structure of LiMn_(0.85)Cr_(0.15)O_(2) belongs to monoclinic phase. TEM investigation shows that the final powder product consists of ultrafine spherical particles which are distributed homogeneously, with the average diameter ranging from 60 to 300nm. The initial discharge capacity of LiMn_(0.85)Cr_(0.15)O_(2) is much higher than that of undoped LiMnO_(2). After 40 cycles, the capacity retention for m-LiMn_(0.85)Cr_(0.15)O_(2 )is 94% at the current rate of 50mA/g under room temperature. The results of electrochemistry tests …
Lithium Insertion Into Tio_2(B) Nanobelts Synthesized By The "Soft Chemical" Method, Cha-Geng Nie, Zheng-Liang Gong, Lan Sun, Juan Zuo, Yue-Kun Lai, Chang-Jian Lin
Lithium Insertion Into Tio_2(B) Nanobelts Synthesized By The "Soft Chemical" Method, Cha-Geng Nie, Zheng-Liang Gong, Lan Sun, Juan Zuo, Yue-Kun Lai, Chang-Jian Lin
Journal of Electrochemistry
TiO_(2)(B) Nanobelts were synthesized by using the "Soft chemical"method. The products were characterized by means of transmission electron microscope(TEM), X-ray diffraction(XRD), Raman spectrum and energy dispersive spectrum(EDS). Galvanostatic charging and discharging tests showed that lithium-ion intercalation/deintercalation occurred reversibly in the TiO_(2)(B) nanobelts electrode, and a high capacity (265 mAh·g~(-1)) can be obtained. The results suggested that TiO_(2)(B) Nanobelts might be a promising negative electrode material of second Lithium battery.
Fabrication Of Solid Oxide Fuel Cells And Analysis Of Their Structure And Performance, Nai-Tao Yang
Fabrication Of Solid Oxide Fuel Cells And Analysis Of Their Structure And Performance, Nai-Tao Yang
Journal of Electrochemistry
An intermediate temperature solid oxide fuel cell (IT-SOFC) was fabricated by co-copressing-sintering methods, and the electrolyte of Ce_(0.8)Gd_(0.2)O_(1.9) (CGO) and cathode materials of La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3-α) (LSCF) were prepared by sol-gel method. The effect of preparation methods on the microstructure of the prepared fuel cells was analyzed by SEM . It shows that the cells prepared by the co-pressing/co-sintering method possess a dense electrolyte layer and a compact interface between electrolyte and anode but a curved configuration, while those prepared by the colloidal technique have a flat configuration but the electrolyte layer is not dense enough. The maximum output power density of …
The Effect Of Ferrous Sulphate On The Electroless Depositionof Co-Fe-P Alloys, Sen-Lin Wang, Qing-Hua Li
The Effect Of Ferrous Sulphate On The Electroless Depositionof Co-Fe-P Alloys, Sen-Lin Wang, Qing-Hua Li
Journal of Electrochemistry
Electroless deposition of Co-P alloy and Co-Fe-P alloy from an alkaline bath, containing sodium hypophosphite as a reducer, boric acid as a buffer agent and sodium citrate as a complexing agent, was investigated respectively. The effects of process parameters, such as pH of solution and metallic salt mole ratio of CoSO_(4)/FeSO_(4), on the plating rate were examined. It was found that the presence of ferrous sulfate in the bath has an inhibitory effect on the alloy deposition. As a consequence, the plating rate of Co-Fe-P is lower than that of Co-P. The electrochemical polarization measurements have been carried out to …