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Materials Science and Engineering

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University of Massachusetts Amherst

2017

Morphology

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Full-Text Articles in Engineering

Synthesis, Characterization And Application Of Block Copolymer And Nanoparticle Composites, Yue Gai Jul 2017

Synthesis, Characterization And Application Of Block Copolymer And Nanoparticle Composites, Yue Gai

Doctoral Dissertations

The “bottom-up” fabrication of functional hybrid material can be achieved by using directed self-assembly of functional nanoparticles (NP) and block copolymers (BCP) as templates. The versatile nanostructures of BCP provide possibilities to precisely control NPs spatial distribution and the resulting hybrid materials exhibit enhanced electrical, mechanical and optical functionalities. Three main topics related to BCP/NP composites are discussed in this dissertation: I) the spatial distribution of large NP in linear BCP; II) the morphology control of BCP templates with new architectures; and III) the magneto-optical properties of hybrid material using magnetic NPs. For well-ordered BCP/NP composite, the ratio of NP …