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Articles 1 - 19 of 19
Full-Text Articles in Engineering
Spray Printing Of Organic Semiconducting Single Crystals, Grigorios-Panagiotis Rigas, Marcia M. Payne, John E. Anthony, Peter N. Horton, Fernando A. Castro, Maxim Shkunov
Spray Printing Of Organic Semiconducting Single Crystals, Grigorios-Panagiotis Rigas, Marcia M. Payne, John E. Anthony, Peter N. Horton, Fernando A. Castro, Maxim Shkunov
Chemistry Faculty Publications
Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the possibility of large-scale production of inexpensive electronics targeting applications ranging from field-effect transistors and light-emitting diodes to medical X-ray detectors. Here we demonstrate a low-cost, scalable spray-printing process to fabricate high-quality organic single crystals, based on various semiconducting small molecules on virtually any substrate by …
Thin Film Concrete Coatings, Bobby W. Meade, Danny Wells, Theodore Hopwood Ii, Sudhir Palle
Thin Film Concrete Coatings, Bobby W. Meade, Danny Wells, Theodore Hopwood Ii, Sudhir Palle
Kentucky Transportation Center Research Report
KTC researchers obtained eight types of concrete coatings to assess their performance and resistance to chloride penetration. Researchers evaluated eight of the systems in the field and seven in the laboratory. In the field, coatings were applied to a bridge pier that had suffered degradation and chloride contamination. This site will undergo long term monitoring in order to thoroughly evaluate the coating systems. Adhesion of all products in both field and laboratory application was sufficient to provide a durable coating, and ranged from approximately 500 psi to 1,600 psi. Researchers also tested color and gloss changes, which are early indicators …
Enhanced Metallic Properties Of Srruo3 Thin Films Via Kinetically Controlled Pulsed Laser Epitaxy, Justin K. Thompson, J. Nichols, S. Lee, S. Ryee, John H. Gruenewald, John G. Connell, Maryam Souri, J. M. Johnson, J. Hwang, M. J. Han, H. N. Lee, D. -W. Kim, Sung S. Ambrose Seo
Enhanced Metallic Properties Of Srruo3 Thin Films Via Kinetically Controlled Pulsed Laser Epitaxy, Justin K. Thompson, J. Nichols, S. Lee, S. Ryee, John H. Gruenewald, John G. Connell, Maryam Souri, J. M. Johnson, J. Hwang, M. J. Han, H. N. Lee, D. -W. Kim, Sung S. Ambrose Seo
Physics and Astronomy Faculty Publications
Metal electrodes are a universal element of all electronic devices. Conducting SrRuO3 (SRO) epitaxial thin films have been extensively used as electrodes in complex-oxide heterostructures due to good lattice mismatches with perovskite substrates. However, when compared to SRO single crystals, SRO thin films have shown reduced conductivity and Curie temperatures (TC), which can lead to higher Joule heating and energy loss in the devices. Here, we report that high-quality SRO thin films can be synthesized by controlling the plume dynamics and growth rate of pulsed laser epitaxy (PLE) with real-time optical spectroscopic monitoring. The SRO thin …
Preparation And Microstructure Of Machinable Al2O3/Mica Composite By Ball Milling And Hot-Press Sintering, Qingbo Tian, Deyu Kong, Tongguang Zhai
Preparation And Microstructure Of Machinable Al2O3/Mica Composite By Ball Milling And Hot-Press Sintering, Qingbo Tian, Deyu Kong, Tongguang Zhai
Chemical and Materials Engineering Faculty Publications
A machinable α-Al2O3/mica composite was prepared by hot-press sintering. In this experiment, a mica-contained glass ceramic in the MgO-Al2O3-SiO2-F glassy system was employed and the base glass powders were obtained by traditional melting-quenched method. Then, α-Al2O3 milling swarf was introduced by medium α-alumina milling ball to the glass powders. The test results indicate that the composites consist of mica crystal and mullite crystal, which are precipitated in the base glass. The α-Al2O3 shows an irregular polygon, which is inlayed in the base material. With …
Fast Diffusion Of Silver In Tio2 Nanotube Arrays, Wanggang Zhang, Yiming Liu, Diaoyu Zhou, Hui Wang, Wei Liang, Fuqian Yang
Fast Diffusion Of Silver In Tio2 Nanotube Arrays, Wanggang Zhang, Yiming Liu, Diaoyu Zhou, Hui Wang, Wei Liang, Fuqian Yang
Chemical and Materials Engineering Faculty Publications
Using magnetron sputtering and heat treatment, Ag@TiO2 nanotubes are prepared. The effects of heat-treatment temperature and heating time on the evolution of Ag nanofilms on the surface of TiO2 nanotubes and microstructure of Ag nanofilms are investigated by X-ray diffraction, field emission scanning electron microscopy, and transmission electron microscopy. Ag atoms migrate mainly on the outmost surface of the TiO2 nanotubes, and fast diffusion of Ag atoms is observed. The diffusivity for the diffusion of Ag atoms on the outmost surface of the TiO2 nanotubes at 400 °C is 6.87 × 10−18 m2/s, …
Self-Similar Random Process And Chaotic Behavior In Serrated Flow Of High Entropy Alloys, Shuying Chen, Liping Yu, Jingli Ren, Xie Xie, Xueping Li, Ying Xu, Guangfeng Zhao, Peizhen Li, Fuqian Yang, Yang Ren, Peter K. Liaw
Self-Similar Random Process And Chaotic Behavior In Serrated Flow Of High Entropy Alloys, Shuying Chen, Liping Yu, Jingli Ren, Xie Xie, Xueping Li, Ying Xu, Guangfeng Zhao, Peizhen Li, Fuqian Yang, Yang Ren, Peter K. Liaw
Chemical and Materials Engineering Faculty Publications
The statistical and dynamic analyses of the serrated-flow behavior in the nanoindentation of a high-entropy alloy, Al0.5CoCrCuFeNi, at various holding times and temperatures, are performed to reveal the hidden order associated with the seemingly-irregular intermittent flow. Two distinct types of dynamics are identified in the high-entropy alloy, which are based on the chaotic time-series, approximate entropy, fractal dimension, and Hurst exponent. The dynamic plastic behavior at both room temperature and 200 °C exhibits a positive Lyapunov exponent, suggesting that the underlying dynamics is chaotic. The fractal dimension of the indentation depth increases with the increase of temperature, and …
Green Synthesis Nanocomposite Membranes, Dibakar Bhattacharyya, Vasile Smuleac, Rajender S. Varma, Subhas K. Sikdar
Green Synthesis Nanocomposite Membranes, Dibakar Bhattacharyya, Vasile Smuleac, Rajender S. Varma, Subhas K. Sikdar
Chemical and Materials Engineering Faculty Patents
A nanocomposite membrane includes a macroporous polymer membrane having a plurality of pores. A plurality of metal nanoparticles are synthesized and immobilized within those plurality of pores. The nanoparticles are reduced and capped with a green reducing and capping agent such as green tea extract.
Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao
Simultaneous Metal-Insulator And Antiferromagnetic Transitions In Orthorhombic Perovskite Iridate Sr0.94Ir0.78O2.68 Single Crystals, Hao Zheng, Jsaminka Terzic, Feng Ye, X. G. Wan, D. Wang, Jinchen Wang, Xiaoping Wang, P. Schlottmann, Shujuan Yuan, Gang Cao
Center for Advanced Materials Faculty Publications
The orthorhombic perovskite SrIrO3 is a semimetal, an intriguing exception in iridates where the strong spin-orbit interaction coupled with electron correlations tends to impose an insulating state. We report results of our investigation of bulk single-crystal Sr0.94Ir0.78O2.68 or Ir-deficient, orthorhombic perovskite SrIrO3. It retains the same crystal structure as stoichiometric SrIrO3 but exhibits a sharp, simultaneous antiferromagnetic (AFM) and metal-insulator (MI) transition occurring in the basal-plane resistivity at 185 K. Above it, the basal-plane resistivity features an extended regime of almost linear temperature dependence up to 800 K but the strong …
Observation Of Metallic Surface States In The Strongly Correlated Kitaev-Heisenberg Candidate Na2Iro3, Nasser Alidoust, Chang Liu, Su-Yang Xu, Ilya Belopolski, Tongfei Qi, Minggang Zeng, Daniel S. Sanchez, Hao Zheng, Guang Bian, Madhab Neupane, Yu-Tzu Liu, Stephen D. Wilson, Hsin Lin, Arun Bansil, Gang Cao, M. Zahid Hasan
Observation Of Metallic Surface States In The Strongly Correlated Kitaev-Heisenberg Candidate Na2Iro3, Nasser Alidoust, Chang Liu, Su-Yang Xu, Ilya Belopolski, Tongfei Qi, Minggang Zeng, Daniel S. Sanchez, Hao Zheng, Guang Bian, Madhab Neupane, Yu-Tzu Liu, Stephen D. Wilson, Hsin Lin, Arun Bansil, Gang Cao, M. Zahid Hasan
Center for Advanced Materials Faculty Publications
We report high-resolution angle-resolved photoemission spectroscopy measurements on the honeycomb iridate Na2IrO3. Our measurements reveal the existence of a metallic surface band feature crossing the Fermi level with nearly linear dispersion and an estimated surface carrier density of 3.2 x 1013 cm-2, which has not been theoretically predicted or experimentally observed, and provides the first evidence for metallic behavior on the boundary of this material, whereas the bulk bands exhibit a robust insulating gap. We further show the lack of theoretically predicted Dirac cones at the M¯ points of the surface Brillouin …
Anisotropic Softening Of Magnetic Excitations In Lightly Electron-Doped Sr2Iro4, X. Liu, M. P. M. Dean, Z. Y. Meng, M. H. Upton, T. Qi, T. Gog, Y. Cao, J. Q. Lin, D. Meyers, H. Ding, Gang Cao, J. P. Hill
Anisotropic Softening Of Magnetic Excitations In Lightly Electron-Doped Sr2Iro4, X. Liu, M. P. M. Dean, Z. Y. Meng, M. H. Upton, T. Qi, T. Gog, Y. Cao, J. Q. Lin, D. Meyers, H. Ding, Gang Cao, J. P. Hill
Center for Advanced Materials Faculty Publications
The magnetic excitations in electron-doped (Sr1−xLax)2IrO4 with x = 0.03 were measured using resonant inelastic x-ray scattering at the Ir L3 edge. Although much broadened, well defined dispersive magnetic excitations were observed. Comparing with the magnetic dispersion from the undoped compound, the evolution of the magnetic excitations upon doping is highly anisotropic. Along the antinodal direction, the dispersion is almost intact. On the other hand, the magnetic excitations along the nodal direction show significant softening. These results establish the presence of strong magnetic correlations in electron-doped (Sr1−xLax …
Microstructural Properties And Four-Point Bend Fatigue Behavior Of Ti-6.5al-2zr-1mo-1v Welded Joints By Electron Beam Welding, Peng Liu, Tongguang Zhai, Yuanbin Zhang
Microstructural Properties And Four-Point Bend Fatigue Behavior Of Ti-6.5al-2zr-1mo-1v Welded Joints By Electron Beam Welding, Peng Liu, Tongguang Zhai, Yuanbin Zhang
Chemical and Materials Engineering Faculty Publications
With the help of a four-point-bend of fatigue rig, high-cycle fatigue tests were carried out on an Ti–6.5Al–2Zr-1Mo-1V titanium alloy at room temperature, 20 Hz and R = 0.1 in ambient air. The test results indicated that the fatigue strength of base metal, 888 MPa, is about 120% of yield strength. The fatigue strength of joints is 814 MPa. It is about 110% of yield strength of base metal. When the loading stress is higher, the fatigue failure region is located in middle weld zone of weld face, which the cracks are propagated along coarse β phase’s grain boundary. When …
Size Effect On The Magnetic Phase In Sr4Ru3O10, Yan Liu, Jiyong Yang, Weike Wang, Haifeng Du, Wei Ning, Langsheng Ling, Wei Tong, Zhe Qu, Zhaorong Yang, Minling Tian, Gang Cao, Yuheng Zhang
Size Effect On The Magnetic Phase In Sr4Ru3O10, Yan Liu, Jiyong Yang, Weike Wang, Haifeng Du, Wei Ning, Langsheng Ling, Wei Tong, Zhe Qu, Zhaorong Yang, Minling Tian, Gang Cao, Yuheng Zhang
Center for Advanced Materials Faculty Publications
High quality Sr4Ru3O10 nanoflakes are obtained by the scotch tape-based micro-mechanical exfoliation method. The metamagnetic transition temperature Tmflake is found to decrease in line with the decrease of thickness, while the ferromagnetic (FM) phase, the ordinary, and anomalous Hall effects (OHE and AHE) are independent on the thickness of the flake. Analysis of the data demonstrates that the AHE reflects the FM nature of Sr4Ru3O10, and the decrease of thickness favors the Ru moments aligned in the ab-plane, which induces a decrease of the metamagnetic transition …
Notes On Contributions To The Science Of Rare Earth Element Enrichment In Coal And Coal Combustion Byproducts, James C. Hower, Evan J. Granite, David B. Mayfield, Ari S. Lewis, Robert B. Finkelman
Notes On Contributions To The Science Of Rare Earth Element Enrichment In Coal And Coal Combustion Byproducts, James C. Hower, Evan J. Granite, David B. Mayfield, Ari S. Lewis, Robert B. Finkelman
Center for Applied Energy Research Faculty and Staff Publications
Coal and coal combustion byproducts can have significant concentrations of lanthanides (rare earth elements). Rare earths are vital in the production of modern electronics and optics, among other uses. Enrichment in coals may have been a function of a number of processes, with contributions from volcanic ash falls being among the most significant mechanisms. In this paper, we discuss some of the important coal-based deposits in China and the US and critique classification systems used to evaluate the relative value of the rare earth concentrations and the distribution of the elements within the coals and coal combustion byproducts.
X-Ray Absorption Spectroscopy Study Of The Effect Of Rh Doping In Sr2Iro4, C. H. Sohn, Deok-Yong Cho, C. -T. Kuo, L. J. Sandilands, Tongfei Qi, Gang Cao, T. W. Noh
X-Ray Absorption Spectroscopy Study Of The Effect Of Rh Doping In Sr2Iro4, C. H. Sohn, Deok-Yong Cho, C. -T. Kuo, L. J. Sandilands, Tongfei Qi, Gang Cao, T. W. Noh
Center for Advanced Materials Faculty Publications
We investigate the effect of Rh doping in Sr2IrO4 using X-ray absorption spectroscopy (XAS). We observed appearance of new electron-addition states with increasing Rh concentration (x in Sr2Ir1−xRhxO4) in accordance with the concept of hole doping. The intensity of the hole-induced state is however weak, suggesting weakness of charge transfer (CT) effect and Mott insulating ground states. Also, Ir Jeff = 1/2 upper Hubbard band shifts to lower energy as x increases up to x = 0.23. Combined with optical spectroscopy, these results suggest a hybridisation-related mechanism, in …
Large-Area Graphene-Based Nanofiltration Membranes By Shear Alignment Of Discotic Nematic Liquid Crystals Of Graphene Oxide, Abozar Akbari, Phillip Sheath, Samuel T. Martin, Dhanraj B. Shinde, Mahdokht Shaibani, Parama Chakraborty Banerjee, Rachel Tkacz, Dibakar Bhattacharyya, Mainak Majumder
Large-Area Graphene-Based Nanofiltration Membranes By Shear Alignment Of Discotic Nematic Liquid Crystals Of Graphene Oxide, Abozar Akbari, Phillip Sheath, Samuel T. Martin, Dhanraj B. Shinde, Mahdokht Shaibani, Parama Chakraborty Banerjee, Rachel Tkacz, Dibakar Bhattacharyya, Mainak Majumder
Chemical and Materials Engineering Faculty Publications
Graphene-based membranes demonstrating ultrafast water transport, precise molecular sieving of gas and solvated molecules shows great promise as novel separation platforms; however, scale-up of these membranes to large-areas remains an unresolved problem. Here we demonstrate that the discotic nematic phase of graphene oxide (GO) can be shear aligned to form highly ordered, continuous, thin films of multi-layered GO on a support membrane by an industrially adaptable method to produce large-area membranes (13 × 14 cm2) in < 5 s. Pressure driven transport data demonstrate high retention (> 90%) for charged and uncharged organic probe molecules with a hydrated radius above 5 Å as well as modest (30–40%) retention of …
Biopolymeric Mucin And Synthetic Polymer Analogs: Their Structure, Function And Role In Biomedical Applications, Sundar Prasanth Authimoolam, Thomas D. Dziubla
Biopolymeric Mucin And Synthetic Polymer Analogs: Their Structure, Function And Role In Biomedical Applications, Sundar Prasanth Authimoolam, Thomas D. Dziubla
Chemical and Materials Engineering Faculty Publications
Mucin networks are viscoelastic fibrillar aggregates formed through the complex self-association of biopolymeric glycoprotein chains. The networks form a lubricious, hydrated protective shield along epithelial regions within the human body. The critical role played by mucin networks in impacting the transport properties of biofunctional molecules (e.g., biogenic molecules, probes, nanoparticles), and its effect on bioavailability are well described in the literature. An alternate perspective is provided in this paper, presenting mucin’s complex network structure, and its interdependent functional characteristics in human physiology. We highlight the recent advances that were achieved through the use of mucin in diverse areas of bioengineering …
Graphene Oxide Quantum Dots Covalently Functionalized Pvdf Membrane With Significantly-Enhanced Bactericidal And Antibiofouling Performances, Zhiping Zeng, Dingshan Yu, Ziming He, Jing Liu, Fang-Xing Xiao, Yan Zhang, Rong Wang, Dibakar Bhattacharyya, Timothy Thatt Yang Tan
Graphene Oxide Quantum Dots Covalently Functionalized Pvdf Membrane With Significantly-Enhanced Bactericidal And Antibiofouling Performances, Zhiping Zeng, Dingshan Yu, Ziming He, Jing Liu, Fang-Xing Xiao, Yan Zhang, Rong Wang, Dibakar Bhattacharyya, Timothy Thatt Yang Tan
Chemical and Materials Engineering Faculty Publications
Covalent bonding of graphene oxide quantum dots (GOQDs) onto amino modified polyvinylidene fluoride (PVDF) membrane has generated a new type of nano-carbon functionalized membrane with significantly enhanced antibacterial and antibiofouling properties. A continuous filtration test using E. coli containing feedwater shows that the relative flux drop over GOQDs modified PVDF is 23%, which is significantly lower than those over pristine PVDF (86%) and GO-sheet modified PVDF (62%) after 10 h of filtration. The presence of GOQD coating layer effectively inactivates E. coli and S. aureus cells, and prevents the biofilm formation on the membrane surface, producing excellent antimicrobial activity and …
Strain Effects On The Work Function Of An Organic Semiconductor, Yanfei Wu, Annabel R. Chew, Geoffrey A. Rojas, Gjergji Sini, Greg Haugstad, Alex Belianinov, Sergei V. Kalinin, Hong Li, Chad Risko, Jean-Luc Brédas, Alberto Salleo, C. Daniel Frisbie
Strain Effects On The Work Function Of An Organic Semiconductor, Yanfei Wu, Annabel R. Chew, Geoffrey A. Rojas, Gjergji Sini, Greg Haugstad, Alex Belianinov, Sergei V. Kalinin, Hong Li, Chad Risko, Jean-Luc Brédas, Alberto Salleo, C. Daniel Frisbie
Chemistry Faculty Publications
Establishing fundamental relationships between strain and work function (WF) in organic semiconductors is important not only for understanding electrical properties of organic thin films, which are subject to both intrinsic and extrinsic strains, but also for developing flexible electronic devices. Here we investigate tensile and compressive strain effects on the WF of rubrene single crystals. Mechanical strain induced by thermal expansion mismatch between the substrate and rubrene is quantified by X-ray diffraction. The corresponding WF change is measured by scanning Kelvin probe microscopy. The WF of rubrene increases (decreases) significantly with in-plane tensile (compressive) strain, which agrees qualitatively with density …
Development Of Pvdf Membrane Nanocomposites Via Various Functionalization Approaches For Environmental Applications, Douglas M. Davenport, Minghui Gui, Lindell E. Ormsbee, Dibakar Bhattacharyya
Development Of Pvdf Membrane Nanocomposites Via Various Functionalization Approaches For Environmental Applications, Douglas M. Davenport, Minghui Gui, Lindell E. Ormsbee, Dibakar Bhattacharyya
Chemical and Materials Engineering Faculty Publications
Membranes are finding wide applications in various fields spanning biological, water, and energy areas. Synthesis of membranes to provide tunable flux, metal sorption, and catalysis has been done through pore functionalization of microfiltration (MF) type membranes with responsive behavior. This methodology provides an opportunity to improve synthetic membrane performance via polymer fabrication and surface modification. By optimizing the polymer coagulation conditions in phase inversion fabrication, spongy polyvinylidene fluoride (PVDF) membranes with high porosity and large internal pore volume were created in lab and full scale. This robust membrane shows a promising mechanical strength as well as high capacity for loading …