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Engineering Commons

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Materials Science and Engineering

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Missouri University of Science and Technology

2010

Aluminum alloys<br />Cerium<br />Corrosion and anti-corrosives -- Research<br />Phosphate coating<br />Rare earths

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Full-Text Articles in Engineering

Phosphate Post-Treatment Of Cerium-Based Conversion Coatings On Al 2024-T3, Daimon K. Heller Jan 2010

Phosphate Post-Treatment Of Cerium-Based Conversion Coatings On Al 2024-T3, Daimon K. Heller

Doctoral Dissertations

"Phosphate post-treatment of cerium-based conversion coatings (CeCCs) on high strength aluminum alloys can significantly improve corrosion resistance. As-deposited CeCCs exhibit corrosion pits and salt tails across the specimen surface after 3 days of exposure, but post-treated CeCCs have withstood 14 days of salt spray exposure without visibly corroding. The morphology, phase, and electrochemical properties of spray deposited CeCCs were affected by post-treatment parameters such as immersion time, solution temperature, and phosphate source. The best performing coatings were post-treated in aqueous orthophosphate solutions for at least 5 min at temperatures of at least 85⁰C. These conditions converted cerium hydroxy/peroxy species in …