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Engineering Commons

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Materials Science and Engineering

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Missouri University of Science and Technology

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2008

Deuterium Solid-State NMR

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Full-Text Articles in Engineering

Dynamics Of Pipa-D₇ On Silica Surface, Piyawan Krisanangkura, Frank D. Blum Jan 2008

Dynamics Of Pipa-D₇ On Silica Surface, Piyawan Krisanangkura, Frank D. Blum

Chemistry Faculty Research & Creative Works

Molecular motion of polymer chains is an important determinant in understanding the physical properties of polymeric materials. Glass transition temperature (Tg) is a physical property of polymers, which is of primary interest. The study of the dynamics of polymer segments assists in understanding the dependence of Tg on polymer structure.1 For decades, studies have addressed the molecular motion in various polymers. Some of them have probed the dynamics of polymer backbones.2,3 the properties of a polymer at an interface may change because of the type of polymer, the substrate, or other variables. The side chain of a polymer can also …