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Full-Text Articles in Engineering

Understanding The Impact Of Microplastic Contamination On Soil Quality And Eco-Toxicological Risks In Horticulture: A Comprehensive Review, N. P. Gayathri, Geena Prasad, Vaishna Prabhakaran, Vishnu Priya Jun 2024

Understanding The Impact Of Microplastic Contamination On Soil Quality And Eco-Toxicological Risks In Horticulture: A Comprehensive Review, N. P. Gayathri, Geena Prasad, Vaishna Prabhakaran, Vishnu Priya

Research outputs 2022 to 2026

The horticulture sector, essential for global food production, confronts significant challenges with prevalent pollutants, mainly microplastics. The presence of microplastics in the food chain has induced physiological stress and a multifactorial food safety concern. The complexity of the problem, arising from intricate interactions among microplastics, organisms, and ecosystems, poses a substantial challenge to food safety, necessitating an immediate strategic perspective due to the associated risks to human health and eco-toxicology. Significant knowledge gaps persist regarding their impact on terrestrial ecosystems, especially in horticulture. This study addresses the urgent need to comprehend the implications of microplastics on soil health, eco-toxicological risks, …


Advective And Diffusive Gas Phase Transport In Vadose Zones: Importance For Defining Vapour Risks And Natural Source Zone Depletion Of Petroleum Hydrocarbons, Kaveh Sookhak Lari, Greg B. Davis, John L. Rayner, Trevor P. Bastow May 2024

Advective And Diffusive Gas Phase Transport In Vadose Zones: Importance For Defining Vapour Risks And Natural Source Zone Depletion Of Petroleum Hydrocarbons, Kaveh Sookhak Lari, Greg B. Davis, John L. Rayner, Trevor P. Bastow

Research outputs 2022 to 2026

Quantifying the interlinked behaviour of the soil microbiome, fluid flow, multi-component transport and partitioning, and biodegradation is key to characterising vapour risks and natural source zone depletion (NSZD) of light non-aqueous phase liquid (LNAPL) petroleum hydrocarbons. Critical to vapour transport and NSZD is transport of gases through the vadose zone (oxygen from the atmosphere, volatile organic compounds (VOCs), methane and carbon dioxide from the zone of LNAPL biodegradation). Volatilisation of VOCs from LNAPL, aerobic biodegradation, methanogenesis and heat production all generate gas pressure changes that may lead to enhanced gas fluxes apart from diffusion. Despite the importance of the gaseous …


Revitalizing Turtle Creek Park, Michael Hardyway, Ethan Harm, Abbey Jacoby, Casey Stephenson May 2024

Revitalizing Turtle Creek Park, Michael Hardyway, Ethan Harm, Abbey Jacoby, Casey Stephenson

Final Reports in ENST 411: Environmental Community Projects

We current ENST 411 students, Abbey Jacoby, Michael Hardyway, Ethan Harm, and Casey Stephenson have chosen to work with Jim Knight, East Buffalo Township, the Merrill Linn Land and Waterways Conservancy, and many others in an attempt to revitalize Turtle Creek Park for a plethora of reasons. Three of us are majoring in biology, and two are majoring in environmental science, which makes much of the information and techniques relevant in Turtle Creek applicable to our courses of study. This project included heavy hands on work which allowed us students to leave a memorable and impactful influence on the Lewisburg …


Microplastics Fouling Mitigation In Forward Osmosis Membranes By The Molecular Assembly Of Sulfobetaine Zwitterion, Javad Farahbakhsh, Mitra Golgoli, Mehdi Khiadani, Amir Razmjou, Masoumeh Zargar Apr 2024

Microplastics Fouling Mitigation In Forward Osmosis Membranes By The Molecular Assembly Of Sulfobetaine Zwitterion, Javad Farahbakhsh, Mitra Golgoli, Mehdi Khiadani, Amir Razmjou, Masoumeh Zargar

Research outputs 2022 to 2026

Forward osmosis (FO) membranes have potential for the efficient water and wastewater treatment applications. However, their development has faced significant challenges due to their fouling propensity. In this study, FO membranes modified with sulfobetaine zwitterions (i.e., [2-(Methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide) were fabricated and used for the first time to address microplastic (MP) fouling issue. Water flux, reverse salt flux (RSF), fouling, and flux recovery were evaluated for the membranes loaded with different quantities of the zwitterions ranging from 0.25 % to 2 %. The developed membranes were tested over 49 h with feed solutions containing polyethylene MPs and bovine serum albumin …


Will Saf Turbocharge The Corn Ethanol Market?, Richard Perrin, Lilyan Fulginiti, Felipe Miranda De Souza Almeida Mar 2024

Will Saf Turbocharge The Corn Ethanol Market?, Richard Perrin, Lilyan Fulginiti, Felipe Miranda De Souza Almeida

Cornhusker Economics

The long-run outlook for the corn ethanol industry is questionable, due to a transition to electric and hybrid vehicles. One source of hope for the long run is the potential demand for producing Sustainable Aviation Fuel (SAF). SAF is a key component in the United States Aviation Climate Action Plan, a path to net-zero greenhouse gas (GHG) emissions in the aviation industry by 2050. Demand for ethanol for SAF offers hope to the ethanol industry, but it depends a great deal on policy decisions that are being made now. Here we sketch out this story.

Based on the information available …


Field Research Report: Results From The Enreec Vri Field For The 2021, 2022, And 2023 Crop Seasons, Derek M. Heeren, Ali T. Mohammed, Eric Wilkening, Christopher M. U. Neale, Alan L. Boldt, Ankit Chandra, Precious Nneka Amori, Ivo Z. Goncalves, Yeyin Shi, Guillermo R. Balboa Mar 2024

Field Research Report: Results From The Enreec Vri Field For The 2021, 2022, And 2023 Crop Seasons, Derek M. Heeren, Ali T. Mohammed, Eric Wilkening, Christopher M. U. Neale, Alan L. Boldt, Ankit Chandra, Precious Nneka Amori, Ivo Z. Goncalves, Yeyin Shi, Guillermo R. Balboa

Department of Biological Systems Engineering: Conference Presentations and White Papers

Long-term irrigation management research has been conducted from 2014 to 2023 for corn and soybean at the Eastern Nebraska Research, Extension, and Education Center (ENREEC) Variable Rate Irrigation (VRI) Field located in subhumid east-central Nebraska (in the Lower Platte North Natural Resources District). The objective of this report was to present the overall results from the VRI Field for 2021 to 2023. Across the three growing seasons, there were the following irrigation treatments: Best Management Practice (BMP), 50% BMP, 125% BMP, rainfed, Spatial ET Modeling Interface (SETMI), SDD1, SDD2, machine-learning-based Cyber-Physical System (CPS), a student team recommended rate, and industry …


Stage And Discharge Prediction From Documentary Time-Lapse Imagery, Kenneth W. Chapman, Troy E. Gilmore, Mehrube Mehrubeoglu, Christian D. Chapman, Aaron R. Mittelstet, John E. Stranzl Jr. Jan 2024

Stage And Discharge Prediction From Documentary Time-Lapse Imagery, Kenneth W. Chapman, Troy E. Gilmore, Mehrube Mehrubeoglu, Christian D. Chapman, Aaron R. Mittelstet, John E. Stranzl Jr.

Biological Systems Engineering: Papers and Publications

Imagery from fixed, ground-based cameras is rich in qualitative and quantitative information that can improve stream discharge monitoring. For instance, time-lapse imagery may be valuable for filling data gaps when sensors fail and/or during lapses in funding for monitoring programs. In this study, we used a large image archive (> 40,000 images from 2012 to 2019) from a fixed, ground-based camera that is part of a documentary watershed imaging project (https://plattebasintimelapse.com/). Scalar image features were extracted from daylight images taken at one-hour intervals. The image features were fused with United States Geological Survey stage and discharge data as …


Life Cycle Greenhouse Gas Emissions In Maize No-Till Agroecosystems In Southern Brazil Based On A Long-Term Experiment, Guilherme Rosa Da Silva, Adam J. Liska, Cimelio Bayer Jan 2024

Life Cycle Greenhouse Gas Emissions In Maize No-Till Agroecosystems In Southern Brazil Based On A Long-Term Experiment, Guilherme Rosa Da Silva, Adam J. Liska, Cimelio Bayer

Biological Systems Engineering: Papers and Publications

Brazilian agriculture is constantly questioned concerning its environmental impacts, particularly greenhouse gas (GHG) emissions. This research study used data from a 34-year field experiment to estimate the life cycle GHG emissions intensity of maize production for grain in farming systems under no-tillage (NT) and conventional tillage (CT) combined with Gramineae (oat) and legume (vetch) cover crops in southern Brazil. We applied the Feedstock Carbon Intensity Calculator for modeling the “field-to-farm gate” emissions with measured annual soil N2O and CH4 emissions data. For net CO2 emissions, increases in soil organic C (SOC) were applied as a proxy, …


In Situ Water Sensing Systems: Research On Advancements In Environmental Monitoring, Abigail Seibel Dec 2023

In Situ Water Sensing Systems: Research On Advancements In Environmental Monitoring, Abigail Seibel

Honors Theses

In this work, two sensing systems were researched in order to improve in situ environmental monitoring. The first is a pH and Total Alkalinity sensor used to determine these characteristics of sea water. I explored the facets of this sensor over a 7-week internship with Dr. Ellen Briggs in her lab in summer of 2023. The second is a more holistic sensing system that reads temperature, turbidity, and pressure used for studying environmental characteristics of Alaskan bever ponds. Both systems were developed in close collaboration with scientists who are collecting data to better understand the impacts of climate change. Better …


Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee Dec 2023

Enhancing Urban Water Quality Through Biological-Chemical Treatment: Aquatic Macroinvertebrate Community And Temporal Chlorophyll-A Response, Matthew Chaffee

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

With a growing human population, urbanization is impeding a plethora of natural waterways. Of these, urban ponds play a vital role in nutrient sequestration, flood prevention, and habitat sanctuaries. However, nutrient loading can reduce habitat effectiveness and promote harmful algae blooms. To reduce internal nutrient loads, a biological-chemical treatment strategy consisting of floating treatment wetlands (FTWs) and lanthanum were applied to two urban retention ponds, Densmore and Wilderness Ridge Ponds. To measure effectiveness, chlorophyll-a samples were collected and correlated with Sentinel-2. A novel band algorithm termed 3BR1 produced a strong correlation (R2 = 0.72) to physical chlorophyll-a …


Pollutant Forecasting Using Neural Network-Based Temporal Models, Richard Pike Dec 2023

Pollutant Forecasting Using Neural Network-Based Temporal Models, Richard Pike

Masters Theses & Specialist Projects

The Jing-Jin-Ji region of China is a highly industrialized and populated area of the country. Its periodic high pollution and smog includes particles smaller than 2.5 μm, known as PM2.5, linked to many respiratory and cardiovascular illnesses. PM2.5 concentration around Jing-Jin-Ji has exceeded China’s urban air quality safety threshold for over 20% of all days in 2017 through 2020.

The quantity of ground weather stations that measure the concentrations of these pollutants, and their valuable data, is unfortunately small. By employing many machine learning strategies, many researchers have focused on interpolating finer spatial grids of PM2.5, or hindcasting PM2.5. However, …


Vertical Free-Swinging Photovoltaic Racking Energy Modeling: A Novel Approach To Agrivoltaics, Koami Soulemane Hayibo, Joshua M. Pearce Dec 2023

Vertical Free-Swinging Photovoltaic Racking Energy Modeling: A Novel Approach To Agrivoltaics, Koami Soulemane Hayibo, Joshua M. Pearce

Electrical and Computer Engineering Publications

To enable lower-cost building materials, a free-swinging bifacial vertical solar photovoltaic (PV) rack has been proposed, which complies with Canadian building codes and is the lowest capital-cost agrivoltaics rack. The wind force applied to the free-swinging PV, however, causes it to have varying tilt angles depending on the wind speed and direction. No energy performance model accurately describes such a system. To provide a simulation model for the free-swinging PV, where wind speed and direction govern the array tilt angle, this study builds upon the open-source System Advisor Model (SAM) using Python. After the SAM python model is validated, a …


Co2 Storage Capacity And Injectivity Of Stacked Carbonates Of The Pennsylvanian And Permian In Western Nebraska, Lateef Lawal Dec 2023

Co2 Storage Capacity And Injectivity Of Stacked Carbonates Of The Pennsylvanian And Permian In Western Nebraska, Lateef Lawal

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Geological carbon storage (GCS) is a critical aspect of carbon capture and storage (CCS) in which captured CO2 from power plants and industrial processes is injected and stored securely underground. Potential subsurface rock formations include saline aquifers, depleted oil and gas reservoirs, unmineable coal seams and volcanic rocks. GCS technology has been proven in the United States and many other parts of the world as a net-zero carbon emission strategy to mitigate the current climate crisis of our planet. Unlike other states such as Wyoming, GCS projects are still in the early phases in Nebraska. The goal of this …


Wastewater Treatment Plants: The Missing Link In Global One-Health Surveillance And Management Of Antibiotic Resistance, Abdolmajid Gholizadeh, Mehdi Khiadani, Maryam Foroughi, Hadi Alizade Siuki, Hadi Mehrfar Dec 2023

Wastewater Treatment Plants: The Missing Link In Global One-Health Surveillance And Management Of Antibiotic Resistance, Abdolmajid Gholizadeh, Mehdi Khiadani, Maryam Foroughi, Hadi Alizade Siuki, Hadi Mehrfar

Research outputs 2022 to 2026

Introduction: As a global public health crisis, antibiotic resistance (AR) should be monitored and managed under the One-Health concept according to the World Health Organization (WHO), considering the interconnection between humans, animals, and the environment. But this approach often remains focused on human health and rarely on the environment and its compartments, especially wastewater as the main AR receptor. Wastewater treatment plants (WWTPs) not only are not designed for reliving AR but also provide appropriate conditions for enhancing AR through different mechanisms. Methods: By reviewing the research-based statistics on the inclusion of WWTPs in the One-Health/AR program crisis, this paper …


Modeling Overdraft-Driven Nitrate Transport In Shallow Wells For Mitigation And Scenario Planning, Jonathan Cronk Nov 2023

Modeling Overdraft-Driven Nitrate Transport In Shallow Wells For Mitigation And Scenario Planning, Jonathan Cronk

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

In Nebraska, average nitrate concentrations in groundwater have doubled since 1974, making water quality management more important than ever. As droughts, heat waves, and floods become more common climate events, understanding their impacts will be necessary to make informed management decisions. Emerging literature describes that drought correlates to an increase in the concentration of nitrate-N at domestic and irrigation wells, however the relative contributions of the mechanisms thought to be responsible is currently unknown.

This research assessed the impact of recharge and pumping rate changes as two mechanisms affecting nitrate-N concentration during drought, assessed the relationship between well depth and …


Examining The Corn Seedling Emergence–Temperature Relationship For Recent Hybrids: Insights From Experimental Studies, Sahila Beegum, Charles Hunt Walne, Krishna N. Reddy, Vangimalla Reddy, Kambham Raja Reddy Oct 2023

Examining The Corn Seedling Emergence–Temperature Relationship For Recent Hybrids: Insights From Experimental Studies, Sahila Beegum, Charles Hunt Walne, Krishna N. Reddy, Vangimalla Reddy, Kambham Raja Reddy

Nebraska Water Center: Faculty Publications

Corn seedling emergence is a critical factor affecting crop yields. Accurately predicting emergence is crucial for precise crop growth and development simulation in process-based crop models. While various experimental studies have investigated the relationship between corn seedling emergence and temperature, there remains a scarcity of studies focused on newer corn hybrids. In the present study, statistical models (linear and quadratic functional relationships) are developed based on the seedling emergence of ten current corn hybrids, considering soil and air temperatures as influencing factors. The data used for model development are obtained from controlled soil plant atmospheric research chamber experiments focused on …


Analysis Of Wastewater Samples To Explore Community Substance Use In The United States: Pilot Correlative And Machine Learning Study, Marie A. Severson, Sathaporn Onanong, Alexandra Dolezal, Shannon L. Bartelt-Hunt, Daniel D. Snow, Lisa M. Mcfadden Oct 2023

Analysis Of Wastewater Samples To Explore Community Substance Use In The United States: Pilot Correlative And Machine Learning Study, Marie A. Severson, Sathaporn Onanong, Alexandra Dolezal, Shannon L. Bartelt-Hunt, Daniel D. Snow, Lisa M. Mcfadden

Nebraska Water Center: Faculty Publications

Background: Substance use disorder and associated deaths have increased in the United States, but methods for detecting and monitoring substance use using rapid and unbiased techniques are lacking. Wastewater-based surveillance is a cost-effective method for monitoring community drug use. However, the examination of the results often focuses on descriptive analysis.

Objective: The objective of this study was to explore community substance use in the United States by analyzing wastewater samples. Geographic differences and commonalities of substance use were explored.

Methods: Wastewater was sampled across the United States (n=12). Selected drugs with misuse potential, prescriptions, and over-the-counter drugs …


Characterization Of Environmental Levels Of Pesticide Residues In Household Air And Dust Samples Near A Bioenergy Plant Using Treated Seed As Feedstock, Jabeen Taiba, Eleanor G. Rogan, Daniel D. Snow, Chandran Achutan, Muhammad Zahid Oct 2023

Characterization Of Environmental Levels Of Pesticide Residues In Household Air And Dust Samples Near A Bioenergy Plant Using Treated Seed As Feedstock, Jabeen Taiba, Eleanor G. Rogan, Daniel D. Snow, Chandran Achutan, Muhammad Zahid

Nebraska Water Center: Faculty Publications

Exposure to neonicotinoid insecticides is associated with adverse human health outcomes. There is environmental contamination in Saunders County, Nebraska, due to the accumulation of fungicides and insecticides from a now-closed ethanol plant using seed corn as stock. A pilot study quantified environmental contamination in nearby houses from residual pesticides by measuring dust and air (indoor/outdoor) concentrations of neonicotinoids and fungicides at the study site (households within two miles of the plant) and control towns (20–30 miles away). Air (SASS® 2300 Wetted-Wall Air Sampler) and surface dust (GHOST wipes with 4 × 4-inch template) samples were collected from eleven study …


Does Drought Stress Eliminate The Benefit Of Elevated Co2,/Sub> On Soybean Yield? Using An Improved Model To Link Crop And Soil Water Relations, Wenguang Sun, David Fleisher, Dennis Timlin, Chittaranjan Ray, Zhuangji Wang, Sahila Beegum, Vangimalla Reddy Oct 2023

Does Drought Stress Eliminate The Benefit Of Elevated Co2,/Sub> On Soybean Yield? Using An Improved Model To Link Crop And Soil Water Relations, Wenguang Sun, David Fleisher, Dennis Timlin, Chittaranjan Ray, Zhuangji Wang, Sahila Beegum, Vangimalla Reddy

Daugherty Water for Food Global Institute: Faculty Publications

Crop simulation models are indispensable tools that facilitate studies to assess climate impacts and adaptation responses, but have not been adequately tested in terms of accurately predicting crop growth and water stress responses to high carbon dioxide concentrations [CO2]. The soybean model, GLYCIM, previously modified with a coupled leaf-level gas exchange – energy balance model, was integrated with a two-dimensional convectivediffusive root growth module which linked soil and leaf water potentials with the regulation of stomatal conductance. We evaluated the accuracy of this modified GLYCIM using experimental data from a Free-Air CO2 Enrichment (FACE) site, SoyFACE, and …


Leaching Performance Of Nanotechnology-Induced High-Arsenic-Bearing Tooeleite-Like Mineral Nanowaste, Arindam Malakar, Sanjit Das, Samirul Islam, Rajneesh Singh, Sugata Ray Oct 2023

Leaching Performance Of Nanotechnology-Induced High-Arsenic-Bearing Tooeleite-Like Mineral Nanowaste, Arindam Malakar, Sanjit Das, Samirul Islam, Rajneesh Singh, Sugata Ray

Nebraska Water Center: Faculty Publications

For arsenic decontamination from groundwater, arsenic crystallization is becoming adopted due to its sustainability and economic benefits. However, arsenic crystallization technology is a two-step process, which makes it complex and generates hazardous waste. Successful efforts toward making it a single-step process are presented here. The addition of nanorods and ball-milled zinc sulfide nanoparticles to arsenic-contaminated water result in highly monodispersed and higharsenic- containing mineralized nanowaste with a crystalline structure similar to the mineral Tooeleite ((Fe3+6(As3+O3)4SO4(OH)4•4H2O)). This study reports the results of a short-term stability test …


Dual Activation Of Peroxymonosulfate Using Mnfe2O4/G‑C3N4 And Visible Light For The Efficient Degradation Of Steroid Hormones: Performance, Mechanisms, And Environmental Impacts, Kitipong Poomipuen, Chainarong Sakulthaew, Chanat Chokejaroenrat, Athaphon Angkaew, Kanidrawee Techauay, Thapanee Poompoung, Kanokwan Teingtham, Piyaporn Phansak, Piyangkun Lueangjaroenkit, Daniel D. Snow Sep 2023

Dual Activation Of Peroxymonosulfate Using Mnfe2O4/G‑C3N4 And Visible Light For The Efficient Degradation Of Steroid Hormones: Performance, Mechanisms, And Environmental Impacts, Kitipong Poomipuen, Chainarong Sakulthaew, Chanat Chokejaroenrat, Athaphon Angkaew, Kanidrawee Techauay, Thapanee Poompoung, Kanokwan Teingtham, Piyaporn Phansak, Piyangkun Lueangjaroenkit, Daniel D. Snow

Daugherty Water for Food Global Institute: Faculty Publications

Single activation of peroxymonosulfate (PMS) in a homogeneous system is sometimes insufficient for producing reactive oxygen species (ROS) for water treatment applications. In this work, manganese spinel ferrite and graphitic carbon nitride (MnFe2O4/g-C3N4; MnF) were successfully used as an activator for PMS under visible light irradiation to remove the four-mostdetected- hormone-contaminated water under different environmental conditions. The incorporation of g-C3N4 in the nanocomposites led to material enhancements, including increased crystallinity, reduced particle agglomeration, amplified magnetism, improved recyclability, and increased active surface area, thereby facilitating the PMS activation and electron …


Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego Sep 2023

Hydrothermal Carbonization Of Biomass Wastes: Sustainability And Geochemistry, Michael A. Kruge, Teresa A. Centeno, Alvaro Amado-Fierro, José Manuel González-Lafuente, Ruben Forjan-Castro, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Introduction. To reduce the stream of solid waste going to landfills, innovative means for beneficial use are essential. The diversity and volume of organic wastes pose singular problems and opportunities for recovery and circularity. Common processes for organics include conversion to biofuels and carbonization to biochar, typically done by torrefaction (dry pyrolysis). Research on biochar explores its potential as pollutant adsorbent, agricultural or polluted soil amendment, biofuel (directly or as feedstock), and for carbon sequestration (Ighalo et al., 2022; Cavali et al., 2023). Recently, other processes at lower temperatures such as hydrothermal carbonization (HTC) offer new possibilities (Seshadri et al., …


Water-Energy-Food Linkages In Community Smallholder Irrigation Schemes: Center Pivot Irrigation In Rwanda, Ankit Chandra, Derek M. Heeren, Lameck O. Odhiambo, N. Brozovic Sep 2023

Water-Energy-Food Linkages In Community Smallholder Irrigation Schemes: Center Pivot Irrigation In Rwanda, Ankit Chandra, Derek M. Heeren, Lameck O. Odhiambo, N. Brozovic

Daugherty Water for Food Global Institute: Faculty Publications

Water, energy, and food are linked in intricate ways in irrigated agriculture and understanding the interplay of these components is crucial for sustainable and profitable crop production, particularly in smallholder setting such as in sub-Saharan Africa. This study evaluates water-energy-food linkages, engineering and economic performance, irrigation decision making, and challenges faced around water management in a community-based mechanized irrigation scheme in Rwanda. The research is the first to analyze such as scheme, which uses technology typically used by large farmers in a smallholder setting. The study investigates the variation in water requirements and the relationship and impacts of this variability …


Reaction Steps In Heterogeneous Photocatalytic Oxidation Of Toluene In Gas Phase—A Review, Yerzhigit Tulebekov, Zhandos Orazov, Bagdat Satybaldiyev, Daniel D. Snow, Raphaël Schneider, Bolat Uralbekov Sep 2023

Reaction Steps In Heterogeneous Photocatalytic Oxidation Of Toluene In Gas Phase—A Review, Yerzhigit Tulebekov, Zhandos Orazov, Bagdat Satybaldiyev, Daniel D. Snow, Raphaël Schneider, Bolat Uralbekov

Nebraska Water Center: Faculty Publications

A review of the current literature shows there is no clear consensus regarding the reaction mechanisms of air-borne aromatic compounds such as toluene by photocatalytic oxidation. Potential oxidation reactions over TiO2 or TiO2-based catalysts under ultraviolet and visible (UV/VIS) illumination are most commonly considered for removal of these pollutants. Along the pathways from a model pollutant, toluene, to final mineralization products (CO2 and H2O), the formation of several intermediates via specific reactions include parallel oxidation reactions and formation of less-reactive intermediates on the TiO2 surface. The latter may occupy active adsorption sites and …


Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley Aug 2023

Design Of Stormwater Bmps For Surface And Groundwater Protection Based On Site-Scale Soil Properties: Phase I, Kelly Kibler, Lisa Chambers, Melanie Beazley

Florida DOT

Much of Earth’s nutrient cycling takes place in soils. Characteristics of soils control physical, chemical, and biological processes that determine rates of nutrient fluxes, storage, or transformation. As remediation of excess nutrients in stormwater runoff is one function of stormwater Best Management Practices (BMPs), the soil profile constitutes one of the most important factors of BMP design. Variation observed in BMP effectiveness (e.g., why one BMP design works effectively in one place and not another) can often be explained by variations in the soil profile, either through direct means or by a soil’s influence on hydraulics of stormwater flow through …


Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil Aug 2023

Hydrological Dynamics Of Surface-Groundwater Interactions Between Major Springs Of Mammoth Cave And The Green River, Kentucky, Usa, Matthew Cecil

Masters Theses & Specialist Projects

Mammoth Cave is an iconic example of the cave and karst systems that underlie over 50% of the United States and provide around 13% of the world’s population with water resources. These environmental features are vulnerable to drought, pollution, and human impacts. The complex hydrological regime of the Mammoth Cave system has been studied in the past, but there are improvements and updates that can be made to the past research. The dynamics of the surface-groundwater system, particularly reversals of the Green River and how it backfloods into the cave, are some examples. Echo River and River Styx Springs provide …


Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort Jul 2023

Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort

Nebraska Water Center: Faculty Publications

The amount of antibiotics and personal care products entering local sewage systems and ultimately natural waters is increasing and raising concerns about long-term human health effects. We developed an adsorptive photocatalyst, Cu0.5Mn0.5Fe2O4 nanoparticles, utilizing co-precipitation and calcination with melamine, and quantified its efficacy in removing paraben and oxytetracycline (OTC). During melamine calcination, Cu0.5Mn0.5Fe2O4 recrystallized, improving material crystallinity and purity for the adsorptive–photocatalytic reaction. Kinetic experiments showed that all four parabens and OTC were removed within 120 and 45 min. We found that contaminant adsorption and reaction …


Incorporation Of Carbon Dioxide Production And Transport Module Into A Soil-Plant-Atmosphere Continuum Model, Sahila Beegum, Wenguang Sun, Dennis Timlin, Zhuangji Wang, David Fleisher, Vangimalla R. Reddy, Chittaranjan Ray Jun 2023

Incorporation Of Carbon Dioxide Production And Transport Module Into A Soil-Plant-Atmosphere Continuum Model, Sahila Beegum, Wenguang Sun, Dennis Timlin, Zhuangji Wang, David Fleisher, Vangimalla R. Reddy, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

Carbon dioxide release from agricultural soils is influenced by multiple factors, including soil (soil properties, soil-microbial respiration, water content, temperature, soil diffusivity), plant (carbon assimilation, rhizosphere respiration), atmosphere (climate, atmospheric carbon dioxide), etc. Accurate estimation of the carbon dioxide (CO2) fluxes in the soil and soil respiration (CO2 flux between soil and atmosphere) requires a process-based modeling approach that accounts for the influence of all these factors. In this study, a module for CO2 production via root and microbial respiration and diffusion-based carbon dioxide transport is developed and integrated with MAIZSIM (a process-based maize crop growth …


The Association Between Drought Exposure And Respiratory-Related Mortality In The United States From 2000 To 2018, Yeongjin Gwon, Yuanyuan Ji, Jesse E. Bell, Azar M. Abadi, Jesse D. Berman, Austin Rau, Ronald D. Leeper, Jared Rennie Jun 2023

The Association Between Drought Exposure And Respiratory-Related Mortality In The United States From 2000 To 2018, Yeongjin Gwon, Yuanyuan Ji, Jesse E. Bell, Azar M. Abadi, Jesse D. Berman, Austin Rau, Ronald D. Leeper, Jared Rennie

Daugherty Water for Food Global Institute: Faculty Publications

Climate change has brought increasing attention to the assessment of health risks associated with climate and extreme events. Drought is a complex climate phenomenon that has been increasing in frequency and severity both locally and globally due to climate change. However, the health risks of drought are often overlooked, especially in places such as the United States, as the pathways to health impacts are complex and indirect. This study aims to conduct a comprehensive assessment of the effects of monthly drought exposure on respiratory mortality for NOAA climate regions in the United States from 2000 to 2018. A two-stage model …


Improving The Cotton Simulation Model, Gossym, For Soil, Photosynthesis, And Transpiration Processes, Sahila Beegum, Dennis Timlin, Kambham Raja Reddy, Vangimalla Reddy, Wenguang Sun, Zhuangji Wang, David Fleisher, Chittaranjan Ray May 2023

Improving The Cotton Simulation Model, Gossym, For Soil, Photosynthesis, And Transpiration Processes, Sahila Beegum, Dennis Timlin, Kambham Raja Reddy, Vangimalla Reddy, Wenguang Sun, Zhuangji Wang, David Fleisher, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

GOSSYM, a mechanistic, process-level cotton crop simulation model, has a two-dimensional (2D) gridded soil model called Rhizos that simulates the below-ground processes daily. Water movement is based on gradients of water content and not hydraulic heads. In GOSSYM, photosynthesis is calculated using a daily empirical light response function that requires calibration for response to elevated carbon dioxide ( CO2). This report discusses improvements made to the GOSSYM model for soil, photosynthesis, and transpiration processes. GOSSYM’s predictions of below-ground processes using Rhizos are improved by replacing it with 2DSOIL, a mechanistic 2D finite element soil process model. The photosynthesis …