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Rational Design Of Cathode Materials For High Performance Lithium-Sulfur Batteries, Xi Chen

Theses and Dissertations

Sulfur, one of most promising cathode candidates for next-generation lithium ion batteries, shows a limited cycling performance due to its shuttling effect, low conductivity, self-discharge and volume expansion during lithiation and delithiation process. According to the operation principles, failure mechanism, and recent progress on lithium-sulfur batteries, here we developed several scalable and rational synthesis methods for high performance cathode materials. We dissolved commercial sulfur to anhydrous ethylenediamine (EDA) to form an EDA-S precursor, and then we reduced the sulfur particles size at conductive carbon black substrate. The 70% theoretical capacity of sulfur cathode battery was obtained. We also melted commercial …