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Articles 1 - 7 of 7
Full-Text Articles in Engineering
Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi
Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi
Biosystems and Agricultural Engineering Faculty Publications
Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, we investigated the depolymerization of alkaline lignin in aqueous 1-ethyl-3-methylimidazolium acetate [C2C1Im][OAc] under oxidizing conditions. Seven different transition metal catalysts were screened in presence of H2O2 as oxidizing agent in a batch reactor. CoCl2 and …
Reducing Equifinality Using Isotopes In A Process-Based Stream Nitrogen Model Highlights The Flux Of Algal Nitrogen From Agricultural Streams, William I. Ford, James F. Fox, Erik Pollock
Reducing Equifinality Using Isotopes In A Process-Based Stream Nitrogen Model Highlights The Flux Of Algal Nitrogen From Agricultural Streams, William I. Ford, James F. Fox, Erik Pollock
Biosystems and Agricultural Engineering Faculty Publications
The fate of bioavailable nitrogen species transported through agricultural landscapes remains highly uncertain given complexities of measuring fluxes impacting the fluvial N cycle. We present and test a new numerical model named Technology for Removable Annual Nitrogen in Streams For Ecosystem Restoration (TRANSFER), which aims to reduce model uncertainty due to erroneous parameterization, i.e., equifinality, in stream nitrogen cycle assessment and quantify the significance of transient and permanent removal pathways. TRANSFER couples nitrogen elemental and stable isotope mass‐balance equations with existing hydrologic, hydraulic, sediment transport, algal biomass, and sediment organic …
Development Of A Methodology To Determine Antibiotic Concentrations In Water Samples Using High-Pressure Liquid Chromatography, Tahnee Qualls, Carmen T. Agouridis, Manish Kulshrestha
Development Of A Methodology To Determine Antibiotic Concentrations In Water Samples Using High-Pressure Liquid Chromatography, Tahnee Qualls, Carmen T. Agouridis, Manish Kulshrestha
Biosystems and Agricultural Engineering Faculty Publications
Antibiotic concentrations are typically measured using solid-phase extraction along with liquid chromatography, but this process is not practical due to a large number of man hours involved. The use of a lyophilizer with high-pressure liquid chromatography (HPLC) is an accurate and cost-effective method of analyzing antibiotics in water samples. An initial antibiotic analysis methodology was developed with the goal of concentrating antibiotics in water samples for greater detection; however, it was observed that the methodology required additional refinement to improve accuracy, particularly when manure was present in the water samples. Based on prior tetracycline antibiotic research, we hypothesized that sample …
Contemporary And Future Characteristics Of Precipitation Indices In The Kentucky River Basin, Somsubhra Chattopadhyay, Dwayne R. Edwards, Yao Yu
Contemporary And Future Characteristics Of Precipitation Indices In The Kentucky River Basin, Somsubhra Chattopadhyay, Dwayne R. Edwards, Yao Yu
Biosystems and Agricultural Engineering Faculty Publications
Climatic variability can lead to large-scale alterations in the hydrologic cycle, some of which can be characterized in terms of indices involving precipitation depth, duration and frequency. This study evaluated the spatiotemporal behavior of precipitation indices over the Kentucky River watershed for both the baseline period of 1986–2015 and late-century time frame of 2070–2099. Historical precipitation data were collected from 16 weather stations in the watershed, while future rainfall time-series were obtained from an ensemble of 10 Coupled Model Intercomparison Project Phase 5 (CMIP5) global circulation models under two future emission pathways: Representative Concentration Pathways (RCP) 4.5 and 8.5. Annual …
Automated Calibration Of Electrochemical Oxygen Sensors For Use In Compost Bedded Pack Barns, John T. Evans, Michael P. Sama, Joseph L. Taraba, George B. Day
Automated Calibration Of Electrochemical Oxygen Sensors For Use In Compost Bedded Pack Barns, John T. Evans, Michael P. Sama, Joseph L. Taraba, George B. Day
Biosystems and Agricultural Engineering Faculty Publications
The objective of this study was to develop an automated calibration process for a galvanic cell type oxygen sensor. The manufacturer recommended a two-point calibration at room temperature; however, testing revealed that the response was not linear when both the temperature and oxygen concentrations varied. Thus, additional points were needed to generate a representative calibration equation and to reduce the sensor prediction interval. The calibration process needed to be capable of automatically recording sensor response (voltage) at an array of temperatures and oxygen concentrations. Calibration gases were used to precisely control the oxygen concentration inside a small manifold, and an …
Ammonia And Carbon Dioxide Emissions Of Three Laying-Hen Housing Systems As Affected By Manure Accumulation Time, Timothy A. Shepherd, Hongwei Xin, John P. Stinn, Morgan D. Hayes, Yang Zhao, Hong Li
Ammonia And Carbon Dioxide Emissions Of Three Laying-Hen Housing Systems As Affected By Manure Accumulation Time, Timothy A. Shepherd, Hongwei Xin, John P. Stinn, Morgan D. Hayes, Yang Zhao, Hong Li
Biosystems and Agricultural Engineering Faculty Publications
Laying-hen housing design and management are the most significant factors affecting the generation and release of gaseous ammonia to the atmosphere. Transitioning the hen housing type from traditional high-rise (where manure is stored within the house for about one year) to modern manure-belt style (where manure is removed every 1 to 4 d and placed into long-term storage) has significantly improved in-barn air quality and reduced farm-level ammonia emissions. As a direct result of the advantages, 100% of new construction for U.S. egg production incorporates manure-belt systems that regularly remove manure from the houses. However, manure-belt system designs (e.g., active …
Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck
Evaluation Of Flocculation, Sedimentation, And Filtration For Dewatering Of Scenedesmus Algae, Nicholas A. Rhea, Jack Groppo, Czarena Crofcheck
Biosystems and Agricultural Engineering Faculty Publications
Algae can be used as a feedstock for agricultural fertilizers, livestock and poultry feeds, anaerobic digestion, and biofuel production. For each end product, the requirements for moisture content (or solids content) vary, such that a desirable water removal strategy needs to be adaptable to varying levels of water removal. Flocculation, sedimentation, and filtration were evaluated as possible strategies for thickening and dewatering of algae. The goal of this study was to validate that algae cells treated by such means could be processed by vacuum belt filters and to determine the conditions under which the solids content could be increased to …