Engineering Commons^™

Biodegradation Kinetics For 1,2-Dichloroethane And Ethylene Dibromide In Anaerobic Enrichment Cultures Grown On Each Compound, Rong Yu

All Theses

1,2-Dichloroethane (DCA) and ethylene dibromide (EDB) are among the top 15 chlorinated aliphatic compounds on the Agency for Toxic Substances and Disease Registry's Priority List of Hazardous Substances. Co-contamination of groundwater with EDB and 1,2-DCA resulted mainly from environmental releases of leaded gasoline; these compounds were added as lead scavengers. A microcosm study by Henderson et al. with soil and groundwater from a site contaminated with leaded gasoline demonstrated anaerobic biodegradation of EDB at a higher rate, and to a greater extent, than 1,2-DCA. Both compounds were transformed mainly by dihaloelimination to ethene. The objectives of this study were to …

Catalytic Hydrodehalogenation And Hydrogenation Of Halogenated Aromatic Organic Contaminants For Application To Soil Remediation, Claire J. Osborn

USF Tampa Graduate Theses and Dissertations

The objective of this research was to aid in the development of a new method for removing and destroying soil contaminants. In particular, 1,2,4,5-tetrachlorobenzene (TeCB) was selected for this research. Hydrodehalogenation (HDH) was paired with hydrogenation for remedially destroying TeCB without generating a secondary waste stream in a single batch reactor. Palladium- and rhodium-catalyzed HDH and hydrogenation were applied in a batch reactor at room temperature and moderate hydrogen pressure. Cyclohexane was formed as an end product with benzene as an intermediate reactant.

An analytical method was developed to measure TeCB, benzene, and cyclohexane in a solution of water and …