Engineering Commons^™

Using Metal-Organic Frameworks (Mof) To Reduce The Carbon Footprint Of Concrete, Mona Ibrahim El-Hallak

Theses

The production of concrete by the construction industry has a massive impact on the environment. The process of manufacturing its main component, cement, releases a considerable amount of anthropogenic carbon dioxide. This thesis is concerned with the production of sustainable and eco-friendly concrete that integrates metal-organic frameworks (MOF) to capture and offset the CO₂ emissions emitted during the production of cement. The main objective is to synthesize a MOF capable of capturing CO₂ in concrete through accelerated carbonation curing and to assess its impact on concrete performance. Different parameters were examined, including the MOF content, initial curing duration, …

Numerical Modelling Of Externally-Bonded Fiber Reinforced Polymer Shear-Strengthened Reinforced Concrete Beams Subjected To Fatigue Loading, Nagwa Ibrahim Fares

Theses

An extensive number of existing structures persistently exposed to fatigue loading such as bridges, offshore structures, pavements, and highways, are in urgent need of repairing and strengthening. This may be attributed to the continuous increase in the load requirements, change of the structure’s function, and meeting current load standards. Among the potential methods of rehabilitation and strengthening of existing reinforced concrete structures, the externally bonding fiber reinforced polymers (FRP) composites are gaining massive popularity and becoming a viable and cost-effective method. Shear failure of reinforced concrete (RC) beams is known to be brittle, which occurs without prior sufficient warnings; therefore, …

Environmental Assessment Of The Impact Of Land-Based Discharges On Marine Water And Sediment Quality In Dubai, Uae, Ayman Fathy Halawa

Theses

The current seawater and Creek – Canal waterway in the Emirate of Dubai, UAE, is under tremendous pressure because of continuous urban water discharges from land-based sources. Therefore, the impact of urban water discharges on marine water and sediment quality in the Emirate requires a thorough assessment. The main objective of this study is to assess the impacts of effluent discharges on the quality of water and sediment in the open sea and Dubai Creek. The land-based sources include the power and desalination plants, industrial sector, sewage treatment plant, and stormwater runoff. To achieve the stated objective, relevant data on …

Enhanced Removal Of Perfluorooctanoic Acid (Pfoa) Via Microwave-Fenton-Reactive Membrane Filtration, Fangzhou Liu

Theses

Perfluorooctanoic Acid (PFOA), one of the common per- and poly fluorinated alkylated substances (PFASs), is increasingly detected in the environment due to the diverse industrial applications and high resistance to degradation processes. This study evaluated degradation of PFOA in microwave-assistant catalytic membrane filtration, a process that integrates microwave catalytic reactions into a ceramic membrane filtration. First, water permeation of the pristine and catalyst-coated membranes were examined under the influence of microwave irradiation to analyse the impacts of the coating layer and water temperature increase on permeate flux, which were well interpreted by three models. Then, the PFOA removal was first …

Control Of Energy Storage Utilisation For A Building Integrated Microgrid Using Multi-Objective Metaheuristic Optimisation Methods, Quang An Phan

Theses

The aim of this thesis was to develop and analyse optimisation strategies for commercial buildings with integrated microgrids, in order to find optimal trade-offs between maximising profitability and facilitating renewable energy from the national power grid. The continued proliferation of microgrids, as well as the increase in electricity produced by renewable energy sources on the Irish national grid has necessitated the requirement for these strategies. Models to simulate the performance of a photovoltaic system, wind turbine and battery bank were developed and validated. The most suitable optimisation algorithm to generate an optimal charge/discharge rate schedule for a battery bank was …

Controlled Release Chemical Oxidation: Sodium Persulfate Encapsulated In Pvac Polymer, Mosarrat Samiha Kabir

Theses

In this study, sodium persulfate was encapsulated in polyvinyl acetate (PVAc) polymer to investigate the potential of activated persulfate to remediate total coliform and E. coli bacteria from contaminated water through a control release system. Controlled release structures were produced with the polymer and persulfate melted to form pellets at two different baking times. CRP structures containing 60 weight % sodium persulfates blended with 40 weight % polyvinyl acetate (PS- PVAc) were baked for 4 minutes and 10 minutes at 120ºC. The kinetics release of sodium persulfate was studied in a water system and in sand columns. Experimental results showed …

Effectiveness Of Water Quality Benefits Provided By Stormwater Management Facilities/Infiltration Basin, Vinicius Rodrigues De Mattos Barreto

Theses

Stormwater Best Management Practices (BMP) and devices are systems frequently built under assumed design performances, but rarely verified after construction. Their effectiveness in protecting the environment against pollutants carried by stormwater runoff has been extensively questioned and investigated. This research presents a case study of an infiltration basin in Medford, NJ to verify if the 80% expected Total Suspended Solids (TSS) removal as stated in the New Jersey Stormwater BMP Manual is actually achieved. A sampling pit was installed on the site and infiltrated water samples were collected during three rain events and TSS measurements were compared with the inflow. …

Biogas From Slaughterhouse Waste In Ireland: Assessment Of Potential Energy Recovery Pathways, Aidan Ware

Theses

This study was undertaken to investigate the potential energy recovery from the anaerobic digestion (AD) of slaughterhouse wastes in Ireland. The research was approached in two ways; laboratory scale evaluation of methane production of the industrial waste streams from cattle, pig and chicken slaughtering facilities and a life cycle assessment (LCA) and energy balance to assess the potential utilisation pathways. This thesis includes; the evaluation of the potential biogas production from individual and combined slaughterhouse waste streams in Ireland on an equal footing through standardised laboratory testing, the effects of mandatory pre-treatments on the AD of slaughterhouse waste streams and …

Fates Of Spilt Oil And Factors Affecting The Bio-Degradation Of Oil: A Review, Amogh-Ranganath Chakravarthy

Theses

The usage of crude oil and its products is increasing; in turn, the number of spills is also going up. The inland spills are the more recurrent spills in the U.S today. This review article deals with the weathering of oils, which commences just after oil spills into the environment with various processes such as evaporation, dissolution, photo-oxidation, dispersion, emulsification and bio-degradation along with other possible fates. Biodegradation is one of the most significant processes of weathering which depends on oil physical and chemical characteristics, environmental characteristics, pH, salinity and oil concentration. There is a range of oil concentration for …

A Decision Making Tool For Sustainable Design In Construction, Enda Collins

Theses

This report defines sustainability and sustainable development before any research is carried out. This is necessary so that the research carried out further in the report makes sense and there is a reason for including such items in this report. The need for this project and what the project aims to achieve is also highlighted in the introduction of this report.

Sustainability is made up of three equal parts; social, economic and environmental. This report goes through each item and gives examples of each type of development. Having discussed sustainability in a broad sense the report then focuses on Legislation …

A Common Methodology To Assess The Sustainability Of Different Stages Of The Water Cycle In An Urban Environment In An Irish Context, Áine Mcgrath

Theses

The project proposes to devise a common methodology to assess the sustainability of different stages of the water cycle in an urban environment in an Irish context. With the reduction in infrastructure investment by the governing bodies, the concept of sustainable development is becoming more important.

The project involves using the principals and procedures of a system analysis along with sustainable key performance indicators to assess the sustainability of water cycle system, which includes water treatment, the water distribution system, wastewater treatment and flood risk management.

A sustainability assessment of the combined stages of an urban water cycle will provide …

Investigation Of Wastewater Treatment Plant Sustainability Potential In Terms Of Resource Recovery Essentials, Aoife Moloney

Theses

This thesis aims to explore the sustainability potential which exists in Wastewater Treatment Plants (WWTP's); particularly focusing on nutrient, energy, and water recovery and reuse. The core of the research will focus on the establishment of a sustainable Resource Recovery Treatment Plant (RRTP) plan for Limerick Main Drainage (LMD) WWTP, and potentially utilising this as a case study plant which could act as a foundation example within the sector.

There is a genuine need to investigate more sustainable options in wastewater treatment (WWT); increasing energy and sludge management costs are a real issue for non-sustainable WWTP's given that thousands of …

Investigation Into The Measure, Correlate And Predict Methodologies Used In Wind Farm Design Software, Brendan O'Sullivan

Theses

This paper is focused on the Measure Correlate and Predict (MCP) methodologies used to estimate long term wind resource at a prospective site. The first common step in all MCP methodologies is a successful wind measurement campaign at the prospective site. This campaign involves the erection of a wind measurement mast (ideally to the hub height of the proposed turbine) and careful selection of booms, mountings and anemometers. The wind measurement campaign is a vital part of the process as the correlation and prediction analysis is only as accurate as the measured wind data. Correlation is a measure of the …

Classification Of Irish Beaches To Determine Their Potential For Erosion, Aidan O'Connell

Theses

The objective of this literature review is to gather the relevant information regarding beach characteristics and beach erosion in order to undertake the project development stage of the thesis project. The background information that was reviewed was the different zones that are located on a beach; the functions of a beach and what most beaches are commonly used for; how beaches were formed; the legislation that is related to the beach or any work that is required to be carried out on a beach and some background information on the erosion of beaches.

The most relevant beach characteristics that impact …

Challenges Of Permitting Ballast Water Discharges From Commercial Vessels In U.S. Waters, Paul Rodriguez

Theses

On February 5, 2009, the US Environmental Protection Agency (US EPA) issued the Vessel General Permit (VGP), under the Clean Water Act (CWA), for discharges incidental to the normal operation of vessels, including ballast water discharges. This set forth permit requirements for most commercial vessel discharges within 3 nautical miles of U.S. shore. Since it will expire in December 2013, the US EPA recently issued a draft 2013 VGP. One of the significant changes is the proposal of numerical ballast water discharge standards requiring most commercial vessels to install ballast water treatment systems onboard.

The objective of this thesis is …

An Assessment Of Phosphorus Recovery From Dairy Wastewater, Éanna Kelleher

Theses

Phosphorus is an important nutrient for plant and animal life. It is one of the three essential nutrients required for plant growth; Nitrogen, Phosphorus and Potassium. It plays a vital role in the quality and structure of plants. In animals it is essential for the transfer of energy around the body and for the development of the skeleton. Phosphorus is mined from deposits of phosphate rock and is mainly used to produce fertiliser which is applied to agricultural land to improve plant growth. However, phosphorus is a finite resource and, similar to oil, is expected to peak during this century. …

Numerical Modelling Of The River Bandon, Stephen Finn

Theses

Numerical modelling involves the use of data from the physical environment and mathematical equations to achieve predictive solutions to many engineering problems including for river engineering. The field data is surveyed, sampled, recorded and tested before it is entered into the numerical modelling program for analysis. The numerical modelling program contains various mathematical equations that solve the data that has been entered. Numerical modelling is an important tool for predicting the consequences of future events. It can be used for predicting the damage of a 1 in 100 year flood event in a river system. Numerical modelling is used by …

Scenario Generation And Climate Change Modelling Of Nitrous Oxide Emissions From Grasslands In Ireland, Mark Cochrane

Theses

Described as a two-year study in relation to nitrous oxide emissions from agricultural grassland in the Republic of Ireland under a set or climate and environmental policy scenarios. Nitrous oxide is a greenhouse gas, with a global warning potential approximately three hundred times that or carbon dioxide. lt is required under the Kyoto Protocol that national inventories or all greenhouse gas emissions are established. The Intergovernmental Panel on Climate Change (IPCC) Tier approach is designed to establish current inventories of greenhouse gas emissions; however a scenario approach is also employed in order to estimate emissions in future years. Scenario sets …

Geotechnical, Environmental And Regulatory Aspects Of Brownfield Development, Martin Casey

Theses

Brownfield sites are a common feature of the urban landscape, have significant development potential and when remediated are the catalysts for urban regeneration. However, site specific information regarding geotechnical and environmental aspects of the site, including regulatory issues are needed in terms of bringing the land back into beneficial use. This research project discusses current Irish practice and regulation in respect of brownfield development. A comparison is made between Ireland, the United Kingdom, and the European Union in this regard. A review of all available literature indicates a number of shortcomings in respect of the geotechnical, environmental and regulatory aspects …

The Optimum Energy Crop In Ireland For Biofuel, Eoin Deasy

Theses

The motivation for this research stems from the potential of biofuels to assist Ireland in meeting obligations outlined in the 'Renewable Energy Source Directive' (2009/28/EC) and to reduce dependency on fossil fuels. The purpose of this work is to establish the merits of biofuel production Ireland ,with a keen focus on the technical, economic and environmental aspects of each. The three biofuel options investigated are biodiesel, bioethanol and biomethane. Eight crop varieties were investigated, these include; wheat, oats, barley, OSR, maize silage, sugar beet, grass silage and potatoes. The approach taken within this thesis was to perform a life cycle …

Feasibility Of Utilising Construction And Demolition Waste And Dredge Material As Landflll Liner, John David Riordan

Theses

Construction and demolition (C&D) waste and dredge material are significant bulk waste streams in the Republic of Ireland. This thesis examines the feasibility of combining these waste streams to produce a viable novel geotechnical clay liner for landfill.

This thesis includes a literature review and a detailed study of C&D waste, dredge material and landfill liners in Ireland. The research for this thesis includes a geotechnical laboratory test programme. Samples of C&D waste and dredge material were collected and tested to establish relevant characteristics. In addition, a senes of tests were commissioned on test samples to establish their chemical and …

The Potential For Ch4-Enriched Biogas As A Transport Fuel In Ireland, Niamh Power

Theses

Ireland needs a biofuel industry- to aid compliance with the Kyoto Protocol, the Biofuels Directive and to secure its energ>' supply. The overall aim of this work is to assess the potential of CH4-enriched biogas as a transport fuel in Ireland. Biogas is produced during the anaerobic digestion of biomass. This work investigates biogas production from two different feedstocks; biodegradable municipal waste and agricultural crops. To assess the potential for biogas as a transport fuel the alternatives to biogas are investigated and compared. Thus digestion and composting of biodegradable municipal waste, and biogas and ethanol production from agricultural crops …

Development And Application Of A Computer Simulation Tool For Ecological Risk Assessments, Haiyi Lu

Theses

In an effort to improve tools in ecological risk assessment (ERA), an ERA software tool was developed and applied. Based on a preliminary evaluation of existing ecorisk models, the relative deficiencies were identified and included the need for a user-friendly interface, an interactive database management system (DBMS), and a comprehensive evaluation of exposure pathways. In this research, Visual Basic (VB) 6.0 and Microsoft SQL server were selected for developing the Windows-based interface and local DBMS, respectively. For the exposure estimate, Yuma and Aberdeen Proving Grounds were identified as baseline ecosystems. Terrestrial and aquatic plant and animal receptor selection was based …

Optimization Of Nitrogen Removal In Sequencing Batch Reactor, Suppakit Poonyachat

Theses

Operating parameters for sequencing batch reactor have the influenceon each substrate concentration. Concentration profile changes as operationparameters are changed. The study was conducted to model the variationin effluent concentration from sequencing batch reactor. MLVSS and cycletime are the parameters that were varied. Concentration in Fill, React,and Settle Period were calculated by using kinetic equations.

The results can show that these parameters have effects on the concentrationprofile. The increase of MLVSS can lower the concentration of BOD andammonium concentration in React period. Increasing MLVSS can show thatmore substrate utilization and nitrification process occur more rapidly.Concentration of nitrate at the end of …

Intelligent Process For Uasb Reactors, Sita Mohan

Theses

The Upflow Anaerobic Sludge Blanket (UASB) reactor is widely used for the anaerobic treatment of concentrated municipal / industrial wastewaters and sludges. Ability to handle high organic loading rates and cost effectiveness are often the most cited merits of the UASB process. Numerous mathematical models have been developed to describe the process and mechanistic phenomena in these systems. However, evidence in the literature of these models having been applied, either as control or diagnostic tools is limited. The use of intelligent process control mechanisms can greatly ease problems associated with operating these reactor systems.

The objective of this study is …

Measurement Of Microcarrier Weighted Floc Using The Environmental Electron Microscope, Viriya Vithayaveroj

Theses

Utilizing the concept of coagulation in conjunction with the sediment enhancement by microcarrier, the microcarrier process has been demonstrated in a laboratory investigation as an effective and economic operation in removing colloidal particles in an aquatic system. The microcarrier, an inert aluminum silicate particulate (Ottawa Sand) of 53 to 75 micrometers in diameter was used in this study. The interaction between the flocs and the microcarriers plays an important role in the mixing process. The principal objective of this study is to examine the structural interaction between the flocs and the microcarrier.

The study was designed into two stages, the …

Modeling Of A Permeable Reactive Barrier, Guatam C. Ijoor

Theses

The focus of the presentstudy was centered on the modeling analysis to support the Permeable Reactive Barrier (PRB) design. The flow model formulated to simulate the Permeable Reactive Barrier System integrated the available geologic, hydro geologic and geo-chemical data from numerous recent installations to simulate a subsurface ground water scenario.

Different generic cases that a PRB system would fall into were identified based on its utility and aquifer conditions and then employed to produce different model adaptations. The different simulation codes and interfaces were evaluated, and the most expedient of them was used to simulate the Model.

The simulations were …

Characterization Of Steel Corrosion In An Aggressive Environment, Sung Min Maeng

Theses

As part of the Sustainable Green Manufacturing Program, the corrosion resistance of sputtered tantalum is being studied in order to evaluate it as a replacement coating for electroplated chrome. To accomplish this, studies were conducted to evaluate corrosion properties of the gun barrel steel by employing corrosion rate and bulk measurements including x-ray diffraction (XRD), scanning electron microscopy (SEM)/energy dispersive x-ray spectroscopy (EDX), and x-ray fluorescence (XRF), as well as synchrotron-based x-ray absorption spectroscopy (XAS).

Corrosion behavior of steel immersed in an aggressive environment of 37.8 % hydrochloric acid at room temperature was investigated as a function of time from …

Production Of Submicron Aerosols By Powder Depressurization, Amit Haryani

Theses

Disaggregation of dry powders in shear flow has limitations in producing submicron particles. This study explores a new method for the production of submicron particles by the depressurization of powder aerosols. The depressurization mechanism is based on the rapid depressurization of the aggregated powder through a specially designed nozzle. As the pressure suddenly decreases from very high values inside the aggregates (800 psi) to ambient at the surface of such aggregates, disaggregation takes place due to the force exerted by the gas escaping through their pore structure.

he effect of various process parameters, namely: nozzle diameter, pressure and pretreatment with …

Analysis And Modeling Of Ultrasound To Decontaminate Heavy Metals In Dredged Sediments, Ruvini Perera

Theses

Sediments contaminated with heavy metals due to past disposal practices threatens the environment and requires remediation. This research is an attempt to develop a technology to decontaminate heavy metals in the dredged sediments with an integrated set of processes using ultrasound. Acoustic cavitation caused by ultrasound energy can be used to remove chromium from the sediments. Two coupled processes were used to treat both coarse (Process#1) and fine (Process#2) fractions of the sediments. Full factorial experimental designs were carried out to evaluate the treatment technique and to statistically model and optimize the processes. The model for Process#1 had four contributing …