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The Effects Of Isoprene And Nox On Secondary Organic Aerosols Formed Through Reversible And Irreversible Uptake To Aerosol Water, Marwa M. El-Sayed, Diana L. Ortiz-Montalvo, Christopher J. Hennigan
The Effects Of Isoprene And Nox On Secondary Organic Aerosols Formed Through Reversible And Irreversible Uptake To Aerosol Water, Marwa M. El-Sayed, Diana L. Ortiz-Montalvo, Christopher J. Hennigan
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Isoprene oxidation produces water-soluble organic gases capable of partitioning to aerosol liquid water. The formation of secondary organic aerosols through such aqueous pathways (aqSOA) can take place either reversibly or irreversibly; however, the split between these fractions in the atmosphere is highly uncertain. The aim of this study was to characterize the reversibility of aqSOA formed from isoprene at a location in the eastern United States under substantial influence from both anthropogenic and biogenic emissions. The reversible and irreversible uptake of water-soluble organic gases to aerosol water was characterized in Baltimore, Maryland, USA, using measurements of particulate water-soluble organic carbon …