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Describing Plutonium Contamination Issues In Hanford Soils: Development Of A Thermodynamic Surface Complexation Model, Sarah Herr
All Theses
The development of remediation strategies for long-term site management requires knowledge of an actinide's geochemical behavior. Understanding this behavior can lead to the formation of a subsurface transport model. For example, plutonium mobility in the subsurface environment is significantly influenced by oxidation-reduction and complexation reactions. This work considered the surface-mediated reduction of plutonium, as well as the hydrolysis and carbonate complexation of the actinide.
Evaluating the significance of these reactions required several variable pH batch sorption studies. Experiments incorporated plutonium and neptunium sorption to sediments from the Hanford Nuclear Reservation in Washington State. Two different sediments were examined: coarse-grained and …
Determination Of Sorption Coefficients For Neptunium, Plutonium, Iodine, And Technetium In Engineered And Natural Systems Under Oxidizing And Reducing Conditions, Michael Lilley
All Theses
Plutonium, neptunium, technetium, and iodine present appreciable risks at nuclear waste disposal sites around the world due to their potential mobility. Sorption of each of these radionuclides is profoundly influenced by oxidation/ reduction reactions. Therefore, the mobility of each radionuclide may be greatly influenced by redox conditions of the natural or engineered system. The primary focus of this study was to determine distribution coefficients (Kd) for each radionuclide for engineered concrete and saltstone systems with varying amounts of reducing slag (a cement additive to create a reducing environment), and for iodide/iodate in natural sediments. Saltstones are a mixture …