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Environmental Engineering

University of Kentucky

Theses/Dissertations

Stable isotopes

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Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff Jan 2021

Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff

Theses and Dissertations--Biosystems and Agricultural Engineering

In the Midwestern U.S. seasonal hypoxia experienced in the Gulf of Mexico and harmful algal blooms in inland freshwater ponds, lakes, and rivers are partly fueled by dissolved orthophosphate loadings from disturbed landscapes. Efforts to reduce dissolved reactive phosphate (DRP) loadings have had varying levels of success and have led to insufficient water quality improvements. Inefficiencies in conservation strategies can stem from poor understanding of phosphate source and flow pathway dynamics. This study focused on monitoring sources and flow pathways of dissolved reactive P in a karst agroecosystem with phosphatic limestone. We collected event water samples at the Camden Creek …


Numerical Modeling And Isotope Tracers To Investigate Karst Biogeochemistry And Transport Processes, Admin Husic Jan 2018

Numerical Modeling And Isotope Tracers To Investigate Karst Biogeochemistry And Transport Processes, Admin Husic

Theses and Dissertations--Civil Engineering

This dissertation investigated the physical and biogeochemical processes affecting the source, fate, and transport of sediment, carbon, and nitrogen within a highly-coupled fluviokarst system. Elemental and isotopic datasets were collected at surface and subsurface locations for both dissolved and particulate contaminant phases, new methodology regarding data collection was presented to the karst research community, an in-cave sediment transport model coupling physical transport with elemental and isotopic mass balances of carbon and nitrogen was formulated, pathway and process control on nitrate leaching from agricultural karst watersheds was assessed, and nitrate mobilization and fractionation were modeled using high frequency storm sampling and …