Engineering Commons^™

Characterizing Reactive Iron Mineral Coatings And Their Roles In Natural Attenuation At A Site With Historical Contamination, Han Hua

Dissertations

Reactive iron mineral coatings in redox transition zones play an important role in contaminant attenuation. These mineral coatings include poorly crystalline to crystalline iron sulfides, carbonates, and oxyhydroxides, and are a signature of the biogeochemical processes occurring. To better understand these processes, reactive iron mineral coatings are characterized in an 18-m Anaerobic Core collected from a contaminated industrial site. This study targets redox transition zones uncovered in the core. A suite of complementary analyses is applied to distinguish the surface coating mineralogy using X-ray Diffraction, X-ray fluorescence, and field-emission scanning electron microscopy (FESEM) with energy dispersive X-ray analyzer (EDX). In …

The Stability Of Nanobubbles And Its Application In Contaminated Sediment Treatment, Shaini Dilsha Aluthgun Hewage

Dissertations

This dissertation consists of two sections. First, nanobubbles' stability and behavior are studied using experimental and theoretical approaches. Second, nanobubbles application combined with ultrasound to remediate contaminated sediments is discussed.

The stability study consists of four sections. (i). Laboratory investigation to determine bubble size distributions and zeta potentials for different gases, pH levels, temperatures, and salt conditions. (ii). A theoretical study based on the diffused double layer theory to explain nanobubbles' behavior in different NaCl concentrations. (iii). Nanobubbles' stability in electrolyte solutions under different ion valencies using deionized water, NaCl, Na₂SO₄, Na₃PO₄, …

An Experimental Investigation Of Alternative Wave Attenuation Mechanisms For A Modular Breakwater, Richard Perry

Electronic Theses and Dissertations

Global warming and sea level rise threaten to render traditional coastal protection structures as less effective. Floating breakwaters offer the advantages of adapting to rising sea level, allowing important material transport to occur, and being able to deploy and adapt to varying environmental conditions (seabed, depth, etc.). Traditional floating breakwaters typically consist of reflective concrete structures that are limited semi-sheltered locations. This research aimed to construct floating breakwaters out of lightweight materials with a smaller footprint while utilizing alternative attenuation mechanisms. Three breakwaters consisting of a box, beach, and pipe designs were constructed at 1:40 scale and tested in a …

Investigating The Role Of Iron In The Photogranulation Phenomenon, Abeera Ayaz Ansari

Doctoral Dissertations

Oxygenic photogranules (OPGs) are dense spherical microbial aggregates that are used for self-aerating wastewater treatment. Filamentous cyanobacteria are key granulating species, providing structural backbone and integrity in OPGs. Currently, the mechanisms for selecting filamentous cyanobacteria and their ability to form spherical OPGs are not well understood. Literature shows that iron (Fe) availability plays a significant role in the cyanobacterial growth and colony formation. Moreover, Fe availability is known to be dependent upon light, which is an essential growth substrate for the phototrophs. This research has investigated the role of Fe in the photogranulation phenomenon and the impact of light intensity …

Biodegradability Of Cellulose And Its Impact On Oxygen Transfer Efficiency And Biological Nutrients Removal, Ahmed Shawki Ahmed

Electronic Thesis and Dissertation Repository

Cellulose from toilet paper is a significant fraction of particulate organics, which is recoverable. For the first time, comprehensive mapping and tracking the fate of cellulose across various unit processes at full-scale in two water resource recovery facilities located in North America and Europe was undertaken. The influent cellulose content accounted for approximately one-third of the total suspended solids (TSS). More than 80% of the raw wastewater cellulose was captured in primary treatment. The high cellulose content of the primary sludge accounting for 17%-35% of the TSS facilitates cellulose recovery. Cellulose biodegradation efficiency varied between 70%-90% of the primary effluent, …

Laboratory Testing And Mechanistic Analysis Of Treated Subgrade Soils, Hari Kumar Reddy Yarrapureddi

Civil Engineering Theses

Calcium-based stabilizing agents such as cement and lime have been extensively used to improve the engineering properties of base and subgrade layers of pavement systems. Recently, polymers and chemical stabilizers have become popular due to cost efficiency, ease of application, and fast curing times. In this study, California Bearing Ratio (CBR) values of polymer and chemical treated soils were compared with the CBR values of soils treated with conventional stabilizers. Parametric sensitivity analyses was carried out on key parameters including the type of subgrade soil, stabilizing agent, stabilizing agent treatment levels, and moisture conditioning. Additionally, numerical analyses was performed to …

Expanding The Concept Of Comprehensive Area Ratio Parameter To The South-Central States Towards Simplifying The Structural Evaluation Of Flexible Pavements At The Network Level, Nitish R. Bastola

Civil Engineering Theses

The surface deflection bowl data collected through Non-Destructive Testing (NDT) has been widely utilized by various Department of Transportation (DOTs) in the South-Central States and other places. The primary purpose of using deflection-based NDTs in network-level assessment is to identify a weak pavement section that requires further analysis at the project level. The falling weight deflectometer (FWD) test is one of the common NDT based tests utilized by highway agencies in assessing the performance of the flexible pavement. However, a robust method to evaluate pavement sections utilizing FWD data from all the sensors are seldom developed. There is always a …

Policy Changes Impact In Deforestation Of The Brazilian Amazon, Iara Silva Jaques

Master's Projects and Capstones

Since discovered and inhabited, the Brazilian Amazon has been explored and impacted negatively by human activities. The conversion of forest to pastureland and farmland, as well as mining activities, road opening, wood and ore extraction and fire are historically the main causes of environmental damages and forest loss in the region. This project overviewed the latest changes in environmental policy and practices towards environmental protection conducted by the Brazilian president Jair Bolsonaro, since he took office in 2019, and analyzed the progress of deforestation in the recent years under the new federal administration. Geographic Information System analysis were used to …

Uncertainties In The Assessment Of Individual And Compound Flooding From River Discharge And Coastal Water Levels Under Climate Change, Shuyi Wang

Electronic Thesis and Dissertation Repository

It is widely recognized that climate change can impact the risks of flooding in many regions around the world especially the low-lying coastal areas. The concurrent occurrence of multiple flood drivers such as high river flows and coastal water levels can aggravate such impacts causing catastrophic damages. In this study, the individual and compounding effects of riverine and coastal flooding are investigated over Stephenville Crossing, a town located in the coastal-estuarine region of Newfoundland and Labrador (NL), Canada. The impacts of climate change on flood characteristics and the corresponding uncertainties associated with model inputs and structure, and emission scenarios are …

Numerical And Experimental Investigation Of Aeration Self Mixing By Using Pulsating And Continuous Air Flow, Ahmed Ali Alkhafaji

Theses and Dissertations

Wastewater treatment is considered one of the most common forms of pollution control in the united states. Considered as an integral part of the wastewater treatment, the aeration process is the most energy-consuming process among all the processes that take place in any wastewater treatment plant. According to the United States Environmental Protection Agency (EPA), a wastewater treatment plant is expected to remove at least 85% of the suspended solids and dissolved organic compounds from the wastewater before discharging it to a river or a lake. The normal operation of the aeration process is by compressing air continuously to basin …

Moisture Monitoring Of A Clt Structure In A Southern Climate, Elizabeth Poblete

Graduate Theses and Dissertations

Understanding of moisture behavior in cross laminated timber (CLT) is critical to the widespread use of CLT in construction in the United States. Currently, very little data exists on the long-term impact of moisture on CLT. The objective of this research is to collect data regarding the long-term moisture variation in the CLT panel at the University of Arkansas Adohi Hall residence hall. The climate of Northwest Arkansas is different from previously monitored buildings, as they were in the Pacific Northwest. Comparatively, Northwest Arkansas has a warmer climate with higher average annual precipitation. Waterproofing efforts are usually employed to prevent …

Sustainability In Construction: Using Lean Management Principles To Reduce Waste, Matthew Waite

Theses and Dissertations

The construction industry is facing many challenges. There are growing consumer demands for sustainable building. The construction industry generates a significant portion of the waste going into landfills. The construction industry has failed to keep pace with productivity in the manufacturing industry. Through adoption of Lean management principles, the construction industry can become more sustainable while increasing productivity. The literature was evaluated for three concepts: Lean management principles interaction with sustainability, the current state of sustainability in the construction industry, and the current state of Lean management principles in the construction industry. Lean management philosophies interactions with sustainability has been …

Assessing Grassed Waterway Implementation Using Acpf And Swat Models, Kirsten Schaefer

MSU Graduate Theses

Agriculture is the most significant contributor of nonpoint source pollutants in US waterways, with sediment being the most prevalent cause of impairments. Sediment loss mitigation occurs through Best Management Practices (BMPs), such as grassed waterways. Federal and state agencies incentivize the implementation of BMPs through cost-share programs for farmers. The investment of public funds has increased pressure to demonstrate the effectiveness and value of individual projects, necessitating the development of strategies for prioritizing projects based on the sensitivity of sites to sediment erosion and optimal locations for implementation. This study has three primary objectives: (i) document existing locations of grassed …

Detailed Modeling Of The Flash Hydrolysis Of Algae For Biofuel-Production In Comsol Multiphysics, Noah Joseph Legrand

Mechanical & Aerospace Engineering Theses & Dissertations

Algae-derived biofuels are being commercialized as an important renewable energy source. Like any new technology, conversion improvements are desired, including reductions in process complexity and better utilization of the entire microalgae feedstock. The Old Dominion Biomass Laboratory has focused on flash hydrolysis for algae biofuel production. That process involves rapidly heating algae and water mixed as a slurry to a subcritical state. Results from small-scale bench tests are promising, but process scale up is a challenge. Currently there exists a pilot laboratory scale system utilizing induction heating in order to reach controlled reaction temperatures with a reaction duration of 10 …

Chemical Interfacial Reactions Affecting The Speciation And Solubility Of Uranium In Organic-Rich Environments, Carmen A. Velasco

Civil Engineering ETDs

The aim of this dissertation was to investigate the interfacial reactions between uranium (U) and natural organic matter NOM) affecting the solubility, adsorption, and precipitation of U in organic-rich environments. The chemical interactions between U and NOM are not well understood, which justified the following research objectives: 1) Identify the effect of pH on U speciation and the organic functional chemistry in mineralized deposits from the Jackpile Mine.; 2) Identify the precipitation of U(VI) and NOM as a function of pH (2, 4 and 7); 3) Identify changes in DOM chemistry due to the reaction of NOM and U at …

Modeling Distributed Source Control Infrastructure At Neighborhood Scale For Mitigating Flood Risk In Amite River Watershed, Ahmad Amin Shefai

LSU Master's Theses

Flooding has always been a major threat to mankind. This is particularly true in urban areas due to urbanization-induced increasing impervious areas and subsequent increasing urban surface runoff, causing an increasing flooding risk to urban areas in spite of the fact that extensive flood control infrastructure has been constructed. The overall goal of this thesis is to present a distributed source control infrastructure-based approach for mitigating the flood risk. The new flood mitigation approach is demonstrated through the model implementation of a series of distributed source control infrastructure systems in the city of Denham Springs at a neighborhood scale. The …

A Framework For Assessing The Reliability, Availability, Maintainability, And Safety (Rams) Of Decentralized Sanitation, Adefunké Adeosun

USF Tampa Graduate Theses and Dissertations

In established industry sectors, Reliability, Availability, Maintainability, and Safety (RAMS) risk assessments are normally used to compare the risks associated with different technologies on process units. Sanitation solutions are split into traditional wastewater treatment which is centralized treatment and can be classified as an established industry, and decentralized treatment such as pit latrines and septic tank systems which are on much smaller scales. Also they can be classified as non-conventional methods such as reinvented advanced decentralized non-sewered sanitation solution techniques exist mainly in two forms as “Single-User Reinvented Toilet (SURT)” systems or “Multiple-User Reinvented Toilet (MURT)” systems. Advanced decentralized non-sewered …

Coral Reef Restoration In The Tropical West Atlantic Amid The Covid-19 Pandemic, Linden Cheek

USF Tampa Graduate Theses and Dissertations

Climate change is increasing threats to coasts, both from storm surge and sea level rise. Healthy coral reefs provide reduction in storm surges, wave energy, coastal flooding and everyday erosion, and are found across a variety of spatial scales. Given the state of coral reefs worldwide, active Coral Reef Restoration (CRR) in emerging as a necessary component of coastal protection. CRR can be classified as a nature-based solutions (NbS) for coastal protection that also provides a multitude of ecosystem-based services to both humans and other life. Nearly all literature on coral restoration efforts assume a steady-state of human-ecological interactions, but …

Effect Of The C-Source And Cod/N On Nitrite And Partial Nitrate Denitrification, Ahmed Fathy Elyas Badia

Electronic Thesis and Dissertation Repository

The main objectives of this study were: (i) to investigate dynamic specific denitrification rates (SDNR) from nitrite at various chemical oxygen demand (COD) / nitrogen (N) ratios using municipal wastewater (MWW) and acetate, and to study the kinetic parameters, (ii) to investigate the dynamic specific denitrification rates (SDNRs) from nitrite at various COD/N ratios in a system that uses methanol as a complementary carbon source, and studying the effect in case if nitrate replaced nitrite, and (iii) to investigate and compare between the nitrite shunt and N-PDN-anammox technologies through studying the dynamic specific denitrification rates (SDNRs) from nitrate and nitrite …

Water-Energy Nexus: Studies On Salinity Gradient Energy Harvest And Desalination, Guangcai Tan

LSU Doctoral Dissertations

Water and energy are fundamentally linked, and both are important for the development of human society. The demand for renewable energy and freshwater are two global challenges in the 21^st century. Herein, a novel chloride-ion (Cl⁻) concentration flow cell (CFC) based on two symmetrical electrodes (BiCl₃, CoCl₂, VCl₃, or BiOCl) separately by a cation-exchange membrane was used as an efficient method to recover salinity gradient (SG) energy. The CFC with metal chloride electrodes (BiCl₃, CoCl₂, and VCl₃) was based on Cl⁻ extraction/insertion, and that …

P-Cresol Biogenesis During Bioremediation Aimed At Stimulating Chlorinated Solvent Dehalogenation, Alexis Gathings

LSU Master's Theses

The broad goal of the research described in this thesis was to better understand the potential for biologically mediated production of p-cresol in groundwater at a Superfund site located in south Louisiana. Previous literature reports that microorganisms known to carry out the transformation from L-tyrosine to p-cresol occur in diverse environments.

In the research described in this thesis, studies were conducted utilizing groundwater from the Superfund site during the course of enhanced in situ bioremediation practices aimed at stimulating reductive dehalogenation of chlorinated solvent contamination. Microbial communities established with groundwater sampled from the Superfund site were observed to …

Chemically Enhanced Primary Treatment: Modelling And Resources Recovery, Wenjuan Mu

Electronic Thesis and Dissertation Repository

The chemically enhanced primary treatment (CEPT) process is gaining momentum for carbon redirection, thereby lowering the downstream liquid train load and maximizing energy recovery from the primary sludge. CEPT technique enhances coagulation and flocculation, that enable faster settling of particulate and colloidal solids and dissolved ions such as phosphate to enhance removal efficiency. Comprehending the dynamic behaviour of CEPT clarifiers is critical to not only develop a reliable whole plant simulation but also fully understand the efficacy of the treatment plant performance. To achieve such purposes, a great amount of efforts has been contributed to the advancement of primary clarifier …

Performance Of A Drinking Water Treatment System For A Small Community In Rural Ghana, West Africa, Xiya Xu

Electronic Thesis and Dissertation Repository

In many African countries, the shortage of water resources is a common phenomenon. Providing safe and adequate water is an issue that must be considered by community leaders and municipal authorities. The present project investigated the performance of a small drinking water treatment system in a small community at Enyan Abaasa, Central Region, Ghana, through sampling and laboratory testing. The treatment system, which is fed by a deep borehole, consists sequentially of polypropylene (PP) yarn pre-filter, sand filter, layered activated carbon-softener resin filter, PP yarn micron filter, reverse osmosis (RO) membrane, PP yarn final filter and two ultraviolet (UV) disinfection …

Effect Of Membrane Aging And Operating Conditions On The Rejection Of Trace Organics For Potable Reuse, Jose Pedro Hernandez

Civil Engineering ETDs

The aim of this study is to provide a better understanding of the effect that membrane degradation and operating conditions have on the removal of selected organic compounds via reverse osmosis (RO). Originally, the study included laboratory experiments in which ESPA2-LD membranes from Hydranautics were to be chemically damaged and the passage of the suite of trace organics through the membranes was to be evaluated. Unfortunately, the degradation experiments were cut short due to lab closures associated with the COVID-19 pandemic. The study then changed direction to provide insight into the role operating conditions have on the removal of trace …

Sustainable Smouldering For Waste-To-Energy: Scale, Heat Losses, And Energy Efficiency, Tarek L. Rashwan

Electronic Thesis and Dissertation Repository

Applied smouldering combustion is emerging as a highly energy efficient approach towards waste-to-energy. This thesis aims to better understand this potential by addressing a critical knowledge gap between laboratory scale smouldering research and large-scale applications. Altogether, new understanding in provided on the complex and dynamic interactions between the reaction zone (smouldering front) and the cooling zone (treated inert porous media) by integrating theory, experiments, analytical modelling, and global energy balance calculations. The experiments spanned a range of reactor sizes and smouldering conditions (from weak to robust) with dry (carbon) and wet (sludge) fuels mixed in sand. This work revealed that …

The Seasonal Effects Of Photovoltaic Cells On Sedum Eco Roof Substrate Moisture, Brook M. Thompson

University Honors Theses

This paper investigates a combined PV eco roof system and analyzes the soil moisture levels in front of the panels and directly underneath the PV Cells on an experimental ecoroof platform in Portland, Oregon. The purpose of the study was to examine how PV Cells create differences in the moisture level of the soil on the ecoroof. Four moisture sensors were set in different quadrants in four experimental testbeds, and the moisture level data was recorded from October 18^th, 2018 to September 10^th, 2019. The study found that in with heavy rainfall, the front of the …

Analysis Of Semi-Arid Riparian Environments Using Satellite Imagery, Kira Overin

Graduate Theses & Non-Theses

Semi-arid riparian environments are at risk of being over-exploited or degraded due to increased water usage associated with growing housing demands. Trends surrounding these developments can be monitored using freely available Landsat satellite imagery in conjunction with seasonal stream discharge rates. This project focuses on a stream system located southwest of Ennis, Montana, where population is growing rapidly. It aims to characterize the connection between variable discharge rates in small-scale riparian environments and adjoining vegetation health, while considering possible implications of continued urbanization. Methods for preventing riparian ecosystem degradation and promoting resilience are also discussed.

Assessment Of The Performance Of Field-Scale Bioretention Systems To Reduce Phosphorus Loads From Urban Stormwater, Jaeleah J. Goor

Electronic Thesis and Dissertation Repository

High nutrient loading can degrade surface water quality worldwide. Bioretention systems are low impact development stormwater management features designed to remove pollutants, including phosphorus (P), from urban stormwater runoff. In this study, two field-scale bioretention systems installed in London, Ontario, Canada were monitored to develop detailed understanding of P behaviour and the hydro-biogeochemical mechanisms that govern overall P retention. Net retention of total P and dissolved organic P, and net release of soluble reactive P (SRP) and total dissolved P were observed. Prolonged input of road de-icing salts (NaCl) in winter and early spring may result in high P release …

Biomechanics Of Trees Under Extreme Wind Loading Events, Mojtaba Dargahi

Electronic Thesis and Dissertation Repository

For urban planners, arborists and foresters, understanding tree stability under self-weight and applied loads from wind and snow is important when developing management strategies to reduce the risk of damage from these abiotic agents. Current predictive approaches are generally empirical and based on a posteriori surveys of failures. A more rigorous engineering approach to understanding response phenomenon in trees subjected to extreme winds has been attempted herein. The size of trees and their architecture (shape and structure) greatly influence their mechanical stability under dynamic loading. Considering trees as porous media, wind loads on them are affected by their resistance to …

Development Of Zeolitic Imidazolate Frameworks For Enhancing Post-Combustion Co2 Capture, Dustin Lee

Master's Theses

Post-combustion CO₂ capture is a promising approach for complementing other strategies to mitigate climate change. Liquid absorption is currently used to capture CO₂ from post-combustion flue gases. However, the high energy cost required to regenerate the liquid absorbents is a major drawback for this process. As a result, solid sorbents have been investigated extensively in recent years as alternative media to capture CO₂ from flue gases. For example, metal organic frameworks (MOFs) are nanoporous materials that have high surface areas, large pore volumes, and flexible designs. A large number of MOFs, however, suffer from 1) low CO …