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Full-Text Articles in Engineering
Characterization Of Jet Fuel Combustion Emissions During A C-130 Aeromedical Evacuation Engines Running Onload, Michelle L. Page
Characterization Of Jet Fuel Combustion Emissions During A C-130 Aeromedical Evacuation Engines Running Onload, Michelle L. Page
Theses and Dissertations
The purpose of this research was to characterize jet fuel combustion emissions (JFCE) in an occupational setting. Prior research demonstrated that aircraft emit hazardous species, especially at engine start-up and ground idle. Complaints of eye, nose, and throat irritation from occupational exposures near aircraft exist. In this study JFCE were tested during an aeromedical evacuation engines running patient onload (ERO) on a C-130 Hercules at the 179th Airlift Wing, Mansfield-Lahm Air National Guard. Ultrafine particles, VOC, formaldehyde, carbon monoxide (CO), sulfuric acid, and metals were sampled simultaneously in approximate crew and patient breathing zones. Testing methods were portable condensation …
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Dynamics Of Chemical Degradation In Water Using Photocatalytic Reactions In An Ultraviolet Light Emitting Diode Reactor, John E. Stubbs
Theses and Dissertations
This work examined ultraviolet (UV) light emitting diodes (LED) and hydrogen peroxide in an advanced oxidation process in support of a USAF installation net zero water initiative. A UV LED reactor was used for degradation of soluble organic chemicals. There were linear relationships between input drive current, optical output power, and first order degradation rate constants. When drive current was varied, first order degradation rates depended on chemical identities and the drive current. When molar peroxide ratios were varied, kinetic profiles revealed peroxide-limited or radical-scavenged phenomena. Molar absorptivity helped explain the complexity of chemical removal profiles. Degradation kinetics were used …
Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt
Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt
Theses and Dissertations
This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …
Toxicological Differences Between Perfluoroalkyl Substances (Pfas) Isomers Using Developmental Biomarkers, Gabriel A. Cantu
Toxicological Differences Between Perfluoroalkyl Substances (Pfas) Isomers Using Developmental Biomarkers, Gabriel A. Cantu
Theses and Dissertations
Perfluoroalkyl substances (PFAS) are metabolically stable synthetic chemicals that have been manufactured for commercial and industrial purposes since the 1950s. PFAS possess surfactant properties that make them ideal to fight hydrocarbon fires and are therefore present in aqueous film forming foams (AFFF). Furthermore, AFFF may contain blends of both linear and branched PFAS isomers. Research suggests that branched PFAS isomers have greater relative placental transfer efficiencies than their linear counterpart, but few studies have evaluated their toxicity. Therefore, the sustained use of AFFF in the U.S. Air Force presents a risk of branched PFAS exposures in pregnant females. This study …