Engineering Commons^™

Development Of Inconel 718f And Inconel 718e Powders For Parts Manufacturing Utilizing Binder Jet Three-Dimensional Printing And Compressed Pellet Methods, Duncan Eric Manor Ii

Graduate Theses, Dissertations, and Problem Reports

Alloy Inconel 718 is a Ni based superalloy used for high temperature applications including turbine blades, turbocharger rotors and nuclear reactors. Inconel 718 is a popular commercial atomized powder that has limitations in performance for use in additive manufacturing applications due to poor part quality and efficiency of current fabrication methods. Developing new compositions and additive manufacturing (AM) methodologies of IN718 is critical to improve the quality and the efficiency of IN718 parts manufacturing. Developing new additive manufacturing methodology that produces higher quality parts made of IN718 as compared to current methods has the potential to greatly impact industry, academia, …

Valorization Of Xylan In Agroforestry Waste Streams, Harrison Appiah

Graduate Theses, Dissertations, and Problem Reports

Valorization of Xylan in Agroforestry Waste Streams.

Harrison Appiah

Microwave-assisted deep eutectic solvent and gamma-valerolactone metallic chloride catalyzed conversion of xylan to furfural were investigated using a 2x3 factorial experimental design at two levels of percent microwave power, reaction time, and catalyst concentration. The levels of each factor studied were (20%, 60% microwave power, 2, 4 minutes, and 10, 20mg) respectively. The effect of three metallic chloride catalysts (LiCl, FeCl3.6H20, CuCl2) on the conversion of xylan to furfural was also investigated. The gamma-valerolactone-ferric chloride sent system exhibited the highest mean yield of furfural (56.50%). The next highest furfural yield of …

Timber Bridge Pile Splicing With Fiber Reinforced Polymer Wraps, Drew L. Damich

Graduate Theses, Dissertations, and Problem Reports

Timber pile repair using splicing is widely used but little research has been done to determine their strength capacity after repair using this method. Current timber pile splicing mechanisms utilize various steel or wooden components. Fiber Reinforced Polymer (FRP) wraps can be utilized as replacement to conventional materials in splicing of timber piles. This study evaluated the strength capacities of traditional splicing mechanisms in relation to FRP wrap splice mechanisms. Traditional splicing mechanisms consisted of flat steel plate, C-channel steel plate, and wooden plate splices. The FRP wrap splice consisted of unidirectional glass/epoxy composite with three layers of fabric as …

Static And Dynamic Analysis Of Composite Plates Using The Monna Finite Element, Mohamed Omar

Graduate Theses, Dissertations, and Problem Reports

Composite materials are replacing metals in many fields due to their favorable qualities such as strength-to-weight ratio, fatigue characteristics, and corrosion resistance. An efficient, versatile, and accurate composite plate element applicable to the dynamic analysis of composite plates would help the advancement of composites tremendously.

The objective of this research is to analyze composite plates using the classical laminated plate theory (CLPT), first-order deformation theory (FSDT), and higher-order deformation theory (HSDT) with the applicable finite element modeling (FEM) for each theory. This thesis investigates which theory is more efficient and accurate and evaluates the benefits of using an h-p-version …

The Role Of Structure Evolution For Prbaco2o6-Δ In Oxygen Reduction Reaction Kinetics At Sofc Cathode, Nan Zhang

Graduate Theses, Dissertations, and Problem Reports

Mixed ion and electron conductive materials especially those with perovskite-related structures have been widely used as cathode and anode of solid oxide fuel cells (SOFC). Double perovskite LnBaCo₂O_6-δ (Ln=Pr, Nd, Sm, Nd, Y) cathodes have been shown better performance than single perovskite Ln_0.5Ba_0.5CoO_3-δ in SOFC cathode studies. However, the effect of different double perovskite phases on oxygen transport properties has not been investigated. In this study, the electrochemical performance of different double perovskite materials PrBaCo₂O_6-δ (PBCO), NdBaCo₂O_6-δ (NBCO), YBaCo₂O_6-δ (YBCO), and single perovskite …

Dry Reforming Of Methane Using Microwave Irradiated Metal Oxide/Coal Char Catalysts, Anthony Carter

Graduate Theses, Dissertations, and Problem Reports

This research focuses on the synthesis of both shaped and amorphous powder materials, the combination of these materials with dried Powder River Basin (PRB) coal char, and their reactionary properties with methane and carbon dioxide gasses with conventional and microwave (MW) heating. The first goal of this project was to synthesize shaped micro and nano sized particles with ideal dielectric properties for converting electromagnetic energy into heat and proven capabilities of activating methane. These particles were synthesized via solvothermal, hydrothermal, and co-preceptory treatments alone and onto the surface of dried PRB coal char. PRB is a sub-bituminous, low-ranking coal (LRC) …

Experimental And Field Evaluation Of Frp Pedestrian Bridge Decks, Kalrav Singh Tomer

Graduate Theses, Dissertations, and Problem Reports

Traditional materials such as steel, timber, and concrete have continued to dominate their usage in civil infrastructure. They offer great advantages like strength and stiffness but at the same time they pose major issues in terms of durability and maintenance. Fiber reinforced polymer (FRP) exhibits outstanding properties like lightness, excellent corrosion and wear resistance along with superior thermo-mechanical properties. Glass FRPs (GFRPs) have emerged as one of the best alternatives in the field of civil infrastructure. It has been more than four decades since fiber reinforced polymer (FRP) composites have gained notable applications in civil infrastructure industry. However, FRPs have …

Synthesis Of Graphene Using Plasma Etching And Atmospheric Pressure Annealing: Process And Sensor Development, Andrew Robert Graves

Graduate Theses, Dissertations, and Problem Reports

Having been theorized in 1947, it was not until 2004 that graphene was first isolated. In the years since its isolation, graphene has been the subject of intense, world-wide study due to its incredibly diverse array of useful properties. Even though many billions of dollars have been spent on its development, graphene has yet to break out of the laboratory and penetrate mainstream industrial applications markets. This is because graphene faces a ‘grand challenge.’ Simply put, there is currently no method of manufacturing high-quality graphene on the industrial scale. This grand challenge looms particularly large for electronic applications where the …

Deformation Correlations And Machine Learning: Microstructural Inference And Crystal Plasticity Predictions, Michail Tzimas

Graduate Theses, Dissertations, and Problem Reports

The present thesis makes a connection between spatially resolved strain correlations and material processing history. Such correlations can be used to infer and classify prior deformation history of a sample at various strain levels with the use of Machine Learning approaches. A simple and concrete example of uniaxially compressed crystalline thin films of various sizes, generated by two-dimensional discrete dislocation plasticity simulations is examined. At the nanoscale, thin films exhibit yield-strength size effects with noisy mechanical responses which create an interesting challenge for the application of Machine Learning techniques. Moreover, this thesis demonstrates the prediction of the average mechanical responses …

Thermal-Fatigue And Thermo-Mechanical Equivalence For Transverse Cracking Evolution In Laminated Composites, Javier Cabrera Barbero

Graduate Theses, Dissertations, and Problem Reports

Carbon fiber reinforced plastics (CFRP) are potential materials for many aerospace and aeronautical applications due to their high specif strength/weight and a low coeffcient of thermal expansion (CTE) resulting in a high long-term stability. Among candidate structures, the re-entry reusable launch vehicles (RLV), the fuel oxidant storage and transportation at cryogenic temperature, space satellites, and aircraft structure (frame, wings, etc...) can be highlighted. However, CFRP are prone to internal damage as a result of high residual stresses and thermal fatigue loading. In this study, micro-cracking damage evolution in laminated composites subjected to monotonic cooling and thermal cyclic loads is developed …

Cost Model For A Small Glass Manufacturing Enterprise, Swetha Gopisetti

Graduate Theses, Dissertations, and Problem Reports

The cost model developed is for small, glass-manufacturing enterprises to help them determine their product costs. It estimates the direct cost in glass manufacturing such as material, labor and energy costs. The overhead costs were based on AACE recommended practices to determine product cost and selling price. The model was tested to estimate the costs in glass marble manufacturing. It determines the unit material cost of the product based on material mix ratio and material costs. The energy costs for the product were based on the batch processing time and gas consumption rate. The model was analyzed to predict variations …