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Theoretical Analysis Of Experimental Data Of Sodium Diffusion In Oxidized Molybdenum Thin Films, Orlando Ayala, Benjamin Belfore, Tasnuva Ashrafee, John Akwari, Grace Rajan, Shankar Karki, Deewakar Poudel, Sylvain Marsillac

Engineering Technology Faculty Publications

In this work, the diffusion process of sodium (Na) in molybdenum (Mo) thin films while it was deposited on soda lime glass (SLG) was studied. A small amount of oxygen was present in the chamber while the direct-current (DC) magnetron sputtering was used for the deposition. The substrate temperatures were varied to observe its effect. Such molybdenum films, with or without oxidations, are often used in thin film solar cells, either as back contact or as hole transport layers. Secondary ion mass spectrometry (SIMS) was used to quantify the concentration of the species. A grain diffusion mechanistic model incorporating the …