Engineering Commons^™

Enhancing Thermal Stability Of Perovskite Solar Cells With A Polymer Through Grain Boundary Passivation, Tanzila Tasnim Ava

Electrical & Computer Engineering Theses & Dissertations

Organic-inorganic halide perovskite solar cells have emerged as a promising photovoltaic technology due to their superb power conversion efficiency (PCE) and very low material costs. While perovskite solar cells are expected to eventually compete with existing silicon-based solar cells on the market, their long-term stability has become a major bottleneck. In particular, perovskite films are found to be very sensitive to external factors such as air, UV light, light soaking, thermal stress and others. Among these stressors, light, oxygen and moisture-induced degradation can be slowed by integrating barrier or interface layers within the device architecture. However, the most representative perovskite …

Highly Transmissive Scalable Colored Coatings For Architectural Photovoltaic Panels, Akbar Ali Syed

Electrical & Computer Engineering Theses & Dissertations

Highly transmissive coatings were developed by fabricating thin films using SiO₂ and SiO₂/TiO₂ core/shell nanoparticles on glass substrates and on the photovoltaic cell glass covers. This coating is to maintain an attractive color appearance of the exterior surface for architecturally integrated photovoltaics and can be coated on fabricated photovoltaic panels. The color and optical properties of the nanoparticle coating was investigated for different nanoparticle diameters of 200-400 nm for SiO₂ nanoparticles and core/shell nanoparticles having SiO₂/TiO₂ structure with 300 ± 11 nm diameter, and SiO₂/TiO₂/SiO₂ structure with …

Optimization Of Top Contact For Cu(In,Ga)Se2 Solar Cells, Grace Cherukara Rajan

Electrical & Computer Engineering Theses & Dissertations

As world energy demands continue to increase, the need to generate electricity from a broader variety of sources, including renewables, is more critical than ever. With costs still 30% higher than those of natural gas, solar energy is a viable contender, but more progress is needed to level the playing field with other forms of energy generation. The overall energy security can be enhanced by diversifying the energy supply. Among them, Cu(In,Ga)Se₂ (CIGS) has gained significant momentum as a possible high efficiency and low cost thin film solar cell material. The capacity to scale up any photovoltaic technology is …

Study Of Modified Deposition Process For Cu(In,Ga)Se2 Solar Cell Back Contact, Tasnuva Ashrafee

Electrical & Computer Engineering Theses & Dissertations

As the worldwide demand for renewable energy is increasing, growth of the global share of alternative energy sources would improve overall energy security as well as bring environmental benefits. So far, solar cells - the devices that convert direct sunlight into electricity - are dominated by silicon devices. Another alternative is thin film solar cell, whose main inspiration is to reduce the electricity production cost. Cu(In, Ga)Se₂ (CIGS) solar cells are considered to have a great prospective because of reduced material and energy consumption during manufacturing. Many CIGS solar cell manufacturers are already exhibiting GW-scale production capacity. With the …

Diffusion Modeling Of Impurities Through The Molybdenum Back Contact Of Cigs Solar Cells, Chinedum John Akwari

Electrical & Computer Engineering Theses & Dissertations

CIGS is a major technology in photovoltaics and depends heavily, as any other PV technology, on the capacity to achieve the highest efficiency possible to compete on the market. Alkaline elements, notably sodium and potassium, play a key role in this matter as they enhance the open circuit voltage and the fill factor of the CIGS solar cells. However, this effect exists only for very specific concentration of sodium and potassium. These impurities typically diffuse through the soda-lime glass substrate.

Via modeling of the SIMS data, we try to understand and predict the diffusion mechanisms of these impurities from the …

Modification Of Deposition Process Parameters For Uniform Indium Layer Deposition, Isaac Butt

Electrical & Computer Engineering Theses & Dissertations

The need for more efficient light to energy converting cells has long been a subject of research and development. With abundant availability of solar energy that the earth receives, the photovoltaic industry has sought materials that could serve the purpose of great energy conversion. The photovoltaic industry is mainly dominated by Silicon owing to its abundant availability, reliability and economic cost. However, due to limitations on efficiency improvements, some focus has shifted toward III-V based solar cells with a great potential for attaining higher efficiency and multi-junction applications. However, the cost of the III-V materials is extremely high due to …

Improving The Efficiency Of Organic Solar Cells By Varying The Material Concentration In The Photoactive Layer, Kevin Anthony Latimer

Electrical & Computer Engineering Theses & Dissertations

Polymer-fullerene bulk heterojunction solar cells have been a rapidly improving technology over the past decade. To further improve the relatively low energy conversion efficiencies of these solar cells, several modifications need to be made to the overall device structure. Emerging technologies include cells that are fabricated with interfacial layers to facilitate charge transport, and tandem structures are being introduced to harness the absorption spectrum of polymers with varying bandgap energies.

When new structures are implemented, each layer of the cell must be optimized in order for the entire device to function efficiently. The most volatile layer of these devices is …

Hybrid Inorganic/Organic Nanostructured Tandem Solar Cells: Simulation And Fabrication Methods, Patrick Michael Boland Jr.

Electrical & Computer Engineering Theses & Dissertations

Organic solar cell technologies continue to be an extremely active area of scientific research. With their promise of providing low-cost, easily-processable, multi-application photovoltaics, these devices could very possibly be the most viable and practical form of renewable energy among many being explored. However, significant technological obstacles remain that must be overcome if this technology is to successfully realize the goal of providing abundant energy while simultaneously reducing dependence on fossil fuel-based sources. Compared with inorganic solar photovoltaics, power conversion efficiencies in organics are still too low to compete economically.

Much research has been accomplished over the past three decades in …