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Molecular To Macroscopic Understanding Of Chloroaluminate Anion Intercalation In Rechargeable Aluminum-Graphite Batteries, Jeffrey Xu
Dissertations and Theses
Today’s global energy challenges pose an urgent need to electrify transportation and better store intermittent renewable energy sources (e.g., solar and wind energy). For such large-scale battery applications, aluminum batteries are a promising “beyond lithium-ion” technology due to the high volumetric capacity, earth abundance, low-cost, and inherent safety of aluminum metal. However, there are very few compatible positive electrode materials that exhibit high energy density and cycling stability, in part due to the challenges of electrochemically intercalating highly charged Al3+ cations. Recently, graphite has been demonstrated as a promising positive electrode material in non-aqueous rechargeable aluminum batteries, which store …
Nuclear Magnetic Resonance Studies On Lithium And Sodium Electrode Materials For Rechargeable Batteries, Tetiana Nosach
Nuclear Magnetic Resonance Studies On Lithium And Sodium Electrode Materials For Rechargeable Batteries, Tetiana Nosach
Dissertations, Theses, and Capstone Projects
In this thesis, Nuclear Magnetic Resonance (NMR) spectroscopic techniques are used to study lithium and sodium electrode materials for advanced rechargeable batteries. Three projects are described in this thesis. The first two projects involve 6Li, 7Li and 31P NMR studies of two cathode materials for advanced rechargeable batteries. The third project is a study of sodium titanate cathode materials for Na-ion batteries, where 1H, 7Li, and 23Na static and magic angle spinning NMR were used in order to obtain detailed information on the chemical environments.