Engineering Commons^™

Quantitative Detection Of Complex Mixtures Using A Single Chemical Sensor: Analysis Of Response Transients Using Multi-Stage Estimation, Karthick Sothivelr, Florian Bender, Fabien Josse, Edwin E. Yaz, Antonio J. Ricco

Electrical and Computer Engineering Faculty Research and Publications

Most chemical sensors are only partially selective to any specific target analyte(s), making identification and quantification of analyte mixtures challenging, a problem often addressed using arrays of partially selective sensors. This work presents and experimentally verifies a signal-processing technique based on estimation theory for online identification and quantification of multiple analytes using only the response data collected from a single polymer-coated sensor device. The demonstrated technique, based on multiple stages of exponentially weighted recursive least-squares estimation (EW-RLSE), first determines which of the analytes included in the sensor response model are absent from the mixture being analyzed; these are then eliminated …