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Computational Chemistry

Journal of Electrochemistry

Fuel cell

Publication Year

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Full-Text Articles in Engineering

Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Li Shang, Zhou Fen, Chen Lei, Pan Mu Apr 2016

Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Li Shang, Zhou Fen, Chen Lei, Pan Mu

Journal of Electrochemistry

It is an urgent need to reduce the Pt loading in electrode for practical fuel cell applications worldwide. Herein, we theoretically investigate the oxygen distribution, generated current, and minimum Pt loading of Pt/C electrode for practical applications based on kinetic model of oxygen reduction reaction. The results indicate that with increasing electrode effective thickness to 40 mm, serious concentration polarization is expected for Pt/C electrode. To generate a power density of 1.4 W•cm-2 (2.1A•cm-2 @0.67 V) for fuel cell, the cathode catalyst layer thickness in PEMFC should be as thin as 3 mm. The minimum Pt loading will …


Steady State Simulation Of Ysz Intermediate-Temperature Fuel Cell, Zi-Jing Lin, Ye Gu, Xiao-Hua Zhang Nov 2002

Steady State Simulation Of Ysz Intermediate-Temperature Fuel Cell, Zi-Jing Lin, Ye Gu, Xiao-Hua Zhang

Journal of Electrochemistry

With a coupled 2D electrochemical and thermal modeling software, the characteristics of the steady state operation of the intermediate-temperature fuel cell with thin yttria-stabilized zirconia(YSZ) electrolyte was analyzed. The parameters of I-V equation were obtained from fitting the experiment results and the choice of grid points was determined by balancing the accuracy requirement and computational efficiency. The temperature fields at different operation circumstances such as flow designs, material choices for interconnect, were examined. The dependences of the output power and cell efficiency on the operating voltage at different temperatures were studied. Based upon the analysis of the temperature profile, it …