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Full-Text Articles in Engineering

Modeling Unimodal/Bimodal Soil-Water Retention Curves Considering The Influence Of Void Ratio Under Capillarity And Adsorption, Zhi-Qiang Lin, Jian-Gu Qian, Zhen-Hao Shi Dec 2021

Modeling Unimodal/Bimodal Soil-Water Retention Curves Considering The Influence Of Void Ratio Under Capillarity And Adsorption, Zhi-Qiang Lin, Jian-Gu Qian, Zhen-Hao Shi

Rock and Soil Mechanics

The constitutive relationship between suction and degree of saturation is of great significance for estimating the shear strength and deformation behavior of unsaturated soils. A unimodal/bimodal soil-water retention curve (SWRC) is proposed considering the effects of various pore structures and the effects of void ratio on capillarity and adsorption. The different mechanisms of water retention through capillarity and adsorption are explicitly distinguished in the proposed model. The relationship between the capillary degree of saturation and suction is described as a specific function related to the characteristics of pore-size distribution, while the adsorptive degree of saturation is modeled considering the effect …


Develop A Multi-Functional Green Pervious Concrete (Mgpc) Pavement With Polycyclic Aromatic Hydrocarbons (Pahs) Removal Function., Hong Shang Aug 2021

Develop A Multi-Functional Green Pervious Concrete (Mgpc) Pavement With Polycyclic Aromatic Hydrocarbons (Pahs) Removal Function., Hong Shang

Electronic Theses and Dissertations

Stormwater runoff induced Polycyclic Aromatic Hydrocarbons (PAHs) contaminant increasingly imperils the groundwater quality and the sustainable development of human society due to the potential carcinogenic risks. Pavement can be considered as the first line of defense for contaminant removal of the stormwater runoff. New construction materials with stormwater runoff quantity and quality control are in urgent demand for updating the existing pavement system. An innovative material called Multi-functional Green Pervious Concrete (MGPC) was developed in the department of Civil and Environmental Engineering at University of Louisville. This material uses organoclay as the amendment to enhance the PAHs removal capacity of …


Silica-Based Materials For Water Treatment Applications: Adsorption And Supported Noble Metal-Based Catalysis, Xiaopeng Min Aug 2021

Silica-Based Materials For Water Treatment Applications: Adsorption And Supported Noble Metal-Based Catalysis, Xiaopeng Min

Theses and Dissertations

Various contaminants have been widely detected in aquatic systems due to both natural and anthropogenic activities, such as conventional and emerging organic pollutants (e.g., nitroarenes, per- and poly-fluoroalkyl substances (PFAS)), and toxic oxyanions (e.g., chlorate, selenate). The presence of these contaminants may pose negative effects on both human health and water systems. Therefore, it is of great desire to develop novel materials and technologies to treat these waterborne pollutants.Catalytic treatment using noble metal (e.g., Pd)-based catalysts has emerged as a promising method for reduction of waterborne contaminants. Silica-based supports may enhance the reactivity and sustainability of Pd-based catalysts by improving …


Synthetic Wastewater Treatment Using Agro-Based Adsorbents, Saisantosh Vamshi Harsha Madiraju, Yung-Tse Hung, Howard Paul May 2021

Synthetic Wastewater Treatment Using Agro-Based Adsorbents, Saisantosh Vamshi Harsha Madiraju, Yung-Tse Hung, Howard Paul

Civil and Environmental Engineering Faculty Publications

This study was undertaken to determine the treatment a binary mixture of dye wastewater (containing Naphthol Green B) and the sugar industry wastewater for removal of color. The specific treatment in the current research consists of adsorption using low-cost adsorbents and microfiltration using Whatman-41 microfilters. Considerations of this treatment process are to take the samples using batch adsorption and avoid coagulation with further dilution. Numerous runs are made, with the ideal waste samples prepared in the laboratory. As a 1st step in the study, different dye concentrations are considered using different concentrations of sugar wastewater. Samples are treated with 3 …


Removal Of Heavy Metals Using Novel Adsorbent Materials, Lesley Joseph Apr 2021

Removal Of Heavy Metals Using Novel Adsorbent Materials, Lesley Joseph

Theses and Dissertations

Heavy metal contamination is a growing concern throughout the world, particularly as industrial and urban activities have increased. Inadequate water and wastewater treatment, coupled with increased industrial activity, have led to increased heavy metal contamination in rivers, lakes, and other water sources in developing countries. To address these concerns, a significant amount of research has been conducted on various novel adsorbents to evaluate their ability to remove heavy metals. Thus, in this study, MIL-100(Fe) and MIL-101(Cr) are fabricated and investigated to determine their ability to remove copper (Cu2+), cadmium (Cd2+), and lead (Pb2+) from aqueous solution. The experimental data fit …


Understanding The Leaching Mechanism For Lead (Pb) Found In Components Of Locally Manufactured Handpumps In Eastern Madagascar, Nidhi Shah Mar 2021

Understanding The Leaching Mechanism For Lead (Pb) Found In Components Of Locally Manufactured Handpumps In Eastern Madagascar, Nidhi Shah

USF Tampa Graduate Theses and Dissertations

This research sought to determine the lead leaching mechanism impacted by an inorganic scale observed from lead valve weights of the pitcher pump systems used in Tamatave, Madagascar. Based on previous research, these valve weights are considered to be a major source for high lead levels in pump water consumed by the residents. As a part of the study, Raman Spectroscopy, X-ray Fluorescence Spectroscopy (XRF) and Energy Dispersive Spectroscopy with Scanning Electron Microscope (SEM-EDS) were performed to address the objectives of this research. The pump component samples for the analysis were selected based on the amount and visual characteristics of …


Drastic Enhancement Of Co2 Adsorption Capacity By Negatively Charged Sub-Bituminous Coal, Hussein R. Abid, Stefan Iglauer, Ahmed Al-Yaseri, Alireza Keshavarz Jan 2021

Drastic Enhancement Of Co2 Adsorption Capacity By Negatively Charged Sub-Bituminous Coal, Hussein R. Abid, Stefan Iglauer, Ahmed Al-Yaseri, Alireza Keshavarz

Research outputs 2014 to 2021

Climate change is a key problem of the 21st century. Climate change is mainly caused by anthropogenic CO2 emissions, and one solution to this problem is to capture and store CO2 in deep coal seams, where it is immobilized by adsorption to the coal surface. Here we propose to modify the coal with methyl orange (MO), a typical dye that is also a major pollutant of the hydrosphere and removed thereby. Thus, raw and MO-modified coals were characterized to investigate their thermal stabilities, textural properties, carbon contents, surface characteristics, and CO2 adsorption on the coal samples was …


A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague Jan 2021

A Speciation Modeling Study Of Heavy Metal Adsorption To Plastic In Municipal Wastewater Treatment Plant Units, Kaitlyn Hague

Electronic Theses and Dissertations

Microplastics are an emerging concern due to their harmful effect to organisms and their ability to facilitate transport of contaminants including heavy metals. Microplastics can enter the environment through wastewater treatment plants, landfill leachate, and littering. Once in the environment microplastics can be distributed throughout rivers, the ocean, and lakes. In order to understand the adsorption of heavy metals to microplastics a geochemical modeling study was completed using Visual Minteq. Lab tests were completed to better understand what constituents are available in wastewater at four different locations: influent, clarifiers, digesters, and effluent. These constituents were then used to observe how …