Engineering Commons^™

Effect Of Land Use Type And Stormwater Control Measures On Non-Point Source Phosphorus Concentrations And Loads In A Cold Climate Urban Subwatershed, Dillon H. Vyn

Electronic Thesis and Dissertation Repository

Non-point source phosphorus (P) exports from urban areas including contributions from different urban land use types and seasonal variations are not well understood, especially for cold climates. Additionally, the effectiveness of different stormwater control measures (SCMs) in reducing P concentrations and loads are poorly quantified with assessments rarely considering total watershed P loads. To address these gaps, detailed field monitoring of total P (TP), soluble reactive P (SRP), total suspended solids (TSS), and water quantity was conducted over a 19-month period in a mixed urban watershed in London, ON. Monitoring sites were located at watershed outlets, at the outlets of …

Comparing Phosphorus Removal Efficiencies And Mechanisms Via Two Cost-Effective Specialty Adsorbents In A Cascade Upflow Filtration System, Sydney Kilgus-Vesely

Honors Undergraduate Theses

Finding solutions to treat water that contains phosphorus is an important effort due to the harmful impacts it presents to both human health and the environment. Phosphorus is considered a limiting factor in water oftentimes and therefore controls the growth of algal bloom in a water body. The increase of algal populations due to wastewater effluent, stormwater runoff, and agricultural discharge in Florida waters has a direct link to the event of harmful algal blooms such as red tide in coastal regions, eutrophication of waterbodies, and fish kills. Finding low cost, energy efficient, and low maintenance green sorption media (GSM) …

Nutrient Removal From Recirculating Aquaculture System Water, Eliza M. Costigan

Electronic Theses and Dissertations

Recirculating aquaculture systems (RAS), where only approximately 10% of the total system water is exchanged per day, have grown in popularity in recent years due to their potential to provide a high-quality protein source in a contained environment. With increased production comes the need for RAS water treatment to mitigate recirculation and discharge of nutrients produced by fish; mainly phosphorus and nitrogen. When discharged, nutrients can contribute to eutrophication in surrounding water bodies, harming the fish and other aquatic life. Therefore, RAS effluent should be treated before discharge. One method of phosphorus removal is adsorption, a surface phenomenon that is …

Exploring Valuable And Potentially Harmful By-Products Formed And/Or Released From Smouldering Treatment Of Sewage Sludge, Taryn Ashley Fournie

Electronic Thesis and Dissertation Repository

The presence of potentially toxic elements (PTEs) and emerging contaminants (e.g., per- and polyfluoroalkyl substances (PFAS)) makes sewage sludge management challenging. Due to their hazards, there is significant interest in thermal treatment technologies that can destroy these compounds, like incineration. However, incineration still poses several risks due to forming and/or releasing hazardous emissions (e.g., polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and PTEs). More recently, the use of smouldering has been introduced as a potential treatment technique for managing sewage sludge. Smouldering presents several advantages over traditional incineration due to its lower energy and pre-treatment requirements and potential for beneficial …

Assessing The Role Of Magnetite In Municipal Wastewater Treatment, Patricia Ayaa

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Some municipal wastewater treatment (MWWT) facilities have adopted magnetite in their treatment processes through a technology called BioMag® to meet effluent regulatory requirements for total nitrogen and total phosphorus. However, there is limited information on the mechanisms and efficiency of magnetite in the removal of nitrogen (N) and phosphorus (P) from wastewater. This research, therefore, estimated its effectiveness in the removal of these nutrients, with a case study of the Marlay-Taylor Water Reclamation Facility in Maryland. The intervention analysis model was used, but a new forecasting approach to the model was proposed to fit the data in this study and …

Evaluation Of The Impacts Of De-Icing Salts On The Performance Of Bioretention Media In Retaining Phosphorus From Urban Stormwater, Brennan S. Donado Visbal

Electronic Thesis and Dissertation Repository

Bioretention systems are a low impact development system that can remove pollutants such as phosphorus (P) from urban stormwater. P retention in bioretention systems is complicated in cold climate regions due to factors such as inputs of road de-icing salts. This study evaluates the impact of prolonged and periodic salt inputs on P retention by conducting column experiments using three different bioretention media with and without an amendment added. Non-amended columns showed net P release, whereas amended columns showed net P retention. While some non-amended columns showed prolonged salt exposure increases P release, the largest P release for all columns …

Spatio-Temporal Variability Of Phosphorus Near The Groundwater-Stream Interface, Meghan Vissers

Electronic Thesis and Dissertation Repository

Agricultural practices can cause excess inputs of soluble reactive phosphorus (SRP) to freshwater catchments leading to eutrophication. This study evaluates spatio-temporal variability of SRP in an agricultural streambed including the influence of groundwater-stream interactions, and examines the associated geochemical and hydrological controls. High porewater SRP (>1000 µg/L) and high SRP sediment fractions were observed in low groundwater discharge zones, specifically in the shallow (≤ 0.1 m) streambed sediments. Porewater SRP concentrations were linked to iron redox cycling with SRP concentrations concordant with more reducing conditions. Porewater SRP varied temporally but distinct seasonal changes were not observed. The conditions in …

Potential Water Treatment Residual Used For Eutrophication Prevention: Varying Bake Time And Wet-Dry Release Experiments, Noor Fahoum

Williams Honors College, Honors Research Projects

A challenge faced today in water ways is the excessive growth of algae due to eutrophication. These harmful algal blooms create problems for the environment and safety concerns for the use of water for drinking purposes. An increase in limiting nutrients such as nitrogen and phosphorus are one of the factors that contribute to eutrophication. This is a concern for the Akron Water Treatment plant where preventative measures are being taken to avoid the potential formation of harmful algal blooms and the cyanotoxins they may release in the water. Through various studies, water treatment residuals (WTR) have been found to …

Recovery Of Phosphorus From Florida Phosphatic Waste Clay, Amir Eskanlou

Graduate Theses, Dissertations, and Problem Reports

This MS thesis examines the recovery of phosphorus (P) from Florida waste clay (WC). A comprehensive literature review revealed that: (i)-The most important values being lost to WC are P and rare earth elements (REEs). For the recovery of these values from WC, two crucial attempts are the removal of extremely fine-sized clays, followed by the recovery of phosphate content, which can pave the path for the recovery of REEs; (ii)-Any scientific/ technological solution should, at the same time, be economically and environmentally attractive to the industry. As such, moving from mostly chemical separation processes to the primarily physical/ physicochemical …

Upcycling Dairy Manure Fine Solids Captured By Dissolved Air Flotation As Part Of A Phosphorus Recovery And Reuse Strategy, Katherine Keith Porterfield

Graduate College Dissertations and Theses

Dissolved air flotation (DAF) has shown potential to substantially improve phosphorus (P) mass balance on dairy farms by capturing P associated with fine solids from liquid manure, enabling new management options. However, at < 25% total solids, further dewatering and other upcycling is necessary to facilitate export of recovered fine solids off farm for use in bagged or bulk products. I generated plant foods using DAF-captured dairy manure fine solids thermally dried to 45% total solids blended with other organic residuals. Dry biomass of tomato and marigold seedlings amended with 6% v/v plant food was six-times greater than the unamended control and not significantly different from a market alternative treatment. Because thermal dewatering can be prohibitively costly, I generated a second batch of plant foods using DAF-captured dairy manure fine solids conditioned with 3, 4.5 and 6% (w/w) quicklime or lime kiln dust (LKD) and dewatered using a benchtop press for comparison with thermally dried fine solids. Tomato seedling biomass was similar for thermally dried and LKD plant foods, but quicklime plant foods had no effect compared to the unamended control. Quicklime and LKD conditioned fine solids contained approximately 30 and 10 times less plant-available P than thermally dried fine solids, respectively—likely due to precipitation of Ca-P minerals. These studies indicate that DAF-captured dairy manure fine solids could be upcycled to bagged horticultural products with substantial agronomic value, however sustainable materials drying remains a key challenge to realizing this potential.

Assessment Of The Performance Of Field-Scale Bioretention Systems To Reduce Phosphorus Loads From Urban Stormwater, Jaeleah J. Goor

Electronic Thesis and Dissertation Repository

High nutrient loading can degrade surface water quality worldwide. Bioretention systems are low impact development stormwater management features designed to remove pollutants, including phosphorus (P), from urban stormwater runoff. In this study, two field-scale bioretention systems installed in London, Ontario, Canada were monitored to develop detailed understanding of P behaviour and the hydro-biogeochemical mechanisms that govern overall P retention. Net retention of total P and dissolved organic P, and net release of soluble reactive P (SRP) and total dissolved P were observed. Prolonged input of road de-icing salts (NaCl) in winter and early spring may result in high P release …

Quantification Of Septic System Contribution To Nutrient Loads In Surface Waters, Archana Tamang

Electronic Thesis and Dissertation Repository

Freshwater systems worldwide are threatened by excessive nutrient (nitrogen and phosphorus) loading. This study evaluated the contribution of septic systems to stream nutrient loads in nine subwatersheds. Stream sampling was conducted during low and high discharge conditions, with samples analyzed for total phosphorus (TP), soluble reactive phosphorus (SRP), nitrate (NO₃-N), and acesulfame (ACE; wastewater tracer). Higher septic effluent reached the subwatershed outlets during high discharge conditions. Subwatersheds with newer households had a lower percentage of septic effluent reaching the stream compared with subwatersheds with older households. Seasonal and event-based ACE concentration-discharge relationships revealed that the hydrological pathways delivering …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Samantha Zidd, Sara Kidd, Ronald Simpson

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bioavailable phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Preliminary studies indicate that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss (2007). Further research was conducted using higher quality concentration measurements to determine what grades of steel wool (0000, 000, 00) and types of activated carbon (GAC, PAC, EAC) …

Modeling Response Of Water Quality To Land-Use And Climate Change In Lake Auburn, Me, Nicholas Messina

Electronic Theses and Dissertations

Lake Auburn, Maine, USA, is a historically unproductive lake that has experienced multiple algal blooms since 2011. The lake is the water supply source for a population of ~60,000. We modeled past temperature, and concentrations of dissolved oxygen (DO) and phosphorus (P) in Lake Auburn by considering the watershed and internal contributions of P as well as atmospheric factors, and predicted the change in lake water quality in response to future climate and land-use changes. A stream hydrology and P-loading model (SimplyP) was used to generate input from two major tributaries into a lake model (MyLake) to simulate physical mixing, …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Kristin Moore

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Estimating Suspended Solids And Phosphorus Loading In Urban Stormwater Systems Using High-Frequency, Continuous Data, Anthony A. Melcher

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The introduction of pavement, buildings, and other impervious surfaces to urban landscapes greatly influences the quantity and quality of urban stormwater runoff. In this study, we designed and implemented modern stormwater monitoring technologies to establish a “smart” stormwater sensor network within the Northwest Field Canal (NWFC), an urban water conveyance located in Logan, Utah, USA. This network was designed to collect flow and water quality data at high frequencies and simultaneously at multiple locations. The observatory’s innovative method of inter-site communication and changing sampling frequencies during storm events was able to capture short duration events at the upstream and downstream …

Removal And Reuse Of Phosphorus As A Fertilizer From Cafo Runoff, Hannah Young

Chemical Engineering Undergraduate Honors Theses

Eutrophication is the process in which nutrient saturated waters promote algal blooms on the surface of the water. This limits the amount of dissolved oxygen content in the water, effectively limiting the range of species that can survive in a body of water. Concentrated animal feeding operations (CAFO) can contribute to this issue. The animals in a CAFO produce large amounts of nutrient-rich waste streams that can enter natural waterways if not properly managed and increase the problem of eutrophication. The ability to treat these waste streams and recover the excess nutrients would allow for not only the reduction of …

Estimation Of Nutrient Loads From Septic Systems To Tributaries In The Lake Erie Basin, Lauren Oldfield

Electronic Thesis and Dissertation Repository

Septic systems are often cited as an important source of nutrient loading to surface waters; however, there is limited quantitative evidence supporting this. To address phosphorus (P) load reduction targets for Lake Erie that were set by the Canadian and United States governments, there is a need to quantify the contribution of septic systems to P tributary loads. Doing so is challenging due to the diffuse nature of this nonpoint source, the lack of septic system inventory across Ontario, and the complexity of P transport in the environment. In this study, the artificial sweetener acesulfame, a tracer for human wastewater, …

Modeled Affinity Constants For Phosphorus Adsorption And Desorption Due To Saltwater Intrusion, Yasemin Taşcı

USF Tampa Graduate Theses and Dissertations

It is important to understand the processes that regulate phosphorus (P) fluxes to coastal environments, because P is an important nutrient in coastal ecosystems. Phosphorus adsorbs to the surface of minerals in sediment and bedrock, and an influx of seawater can cause some of that P to desorb, raising the P concentration of ambient water. Although seawater-induced P desorption is thought to be an important source of P to coastal environments, the chemical reactions that underlie it have not been established. Previous work provides some relevant surface reactions and associated affinity constants between various aqueous P species and the surface …

Prevention Of Harmful Algal Blooms By The Mitigation Of Phosphorus Nutrient Loading Via Filtration By Steel Wool And Activated Carbon, Ronald Simpson, Sara Kidd, Samantha Zidd

Williams Honors College, Honors Research Projects

Harmful Algal Blooms (HABs) are a devastating ecological and economic consequence of the abundance of nutrient-rich agricultural runoff entering aquatic ecosystems (Baker et al. 2014). Bio-available phosphorus from synthetic fertilizers is one of the major nutrients contributing to this global issue. Previous studies indicated that dissolved phosphorus can be removed from an aqueous environment when passed through a composite mixture of granular steel wool particles and activated carbon (Erickson, Gulliver, and Weiss, 2007). In this project, we conducted experiments using higher quality concentration measurements to determine what grades of steel wool (SW-0000, SW-000, SW-00) and types of activated carbon (granulated …

Controls On Phosphorus Export From An Agricultural Watershed: Amsden Brook, Fort Fairfield, Maine Usa., Gregory J. Mcdonald

Electronic Theses and Dissertations

This study explores the sources and mechanisms of phosphorus (P) mobilization during base flow within the Amsden Brook watershed, Fort Fairfield, Maine, USA. Amsden Brook is an agriculturally dominated watershed drained by a spring-fed and perennial first- to second-order stream. We characterized the P concentrations within the watershed to investigate connections between soils, stream sediment, surface water, and groundwater. Waters were monitored monthly during the 2017 snow-free period for temperature, pH, dissolved oxygen, conductivity, soluble reactive P (SRP), total P, strong acid anions, strong base cations, dissolved organic carbon (DOC), Al, Fe, and Mn. Phosphorus speciation within soils and sediment …

The Impact Of Phosphorous Species On Dewaterability Of Wastewater Solids, Erik Anderson

Master's Theses (2009 -)

Phosphorus regulations are causing Water Resource Recovery Facilities (WRRFs) to implement new technologies to remove phosphorus (P) before they discharge liquid effluent. Enhanced Biological Phosphorus Removal (EBPR) is often employed to remove P from water. However, sludges from EBPR plants have shown decreases in dewaterability soon after EBPR was initiated. This decline in dewaterability is not well understood, nor is the best way to improve the dewatering EBPR sludge. Specifically, the role of different P species on sludge dewaterability is not well understood. Several laboratory experiments were conducted at the Marquette University Water Quality Center with the following objectives: i) …

Measuring And Calculating Current Atmospheric Phosphorous And Nitrogen Loadings On Utah Lake Using Field Samples, Laboratory Methods, And Statistical Analysis: Implication For Water Quality Issues, Jacob Milton Olsen

Theses and Dissertations

Atmospheric nutrient loading and transport though precipitation and dry deposition is one of the least understood yet one of the most important pathways of nutrient transport into many lakes. These nutrients, phosphorus and nitrogen, are essential for aquatic life and often play major roles in algae blooms that occur in lakes and reservoirs. Often heavy algal growth intensifies a variety of water quality problems. Utah Lake may be even more susceptible to atmospheric deposition due to its large surface area to volume ratio and proximity to Great Basin dust sources. In this study, eight months of atmospheric deposition data were …

Hydrology And Phosphorus Model For Agricultural Watershed: Swat Simulation Of Discharge And Nutrient Flux In The Medway Creek Watershed, Omar El Abusanina

Electronic Thesis and Dissertation Repository

High nutrient concentrations in surface water have been a serious concern that impacts water quality and ecology. High Phosphorus levels in Medway Creek indicate the presence of a pollution source in the watershed that needs to be identified and quantified. To investigate this issue, the Soil and Water Assessment Tool (SWAT) program has been used in this study with the Geographic Information System (GIS) to model the Medway Creek watershed and assess stream flow and nutrient flux. In this research, the SWAT model has been built, calibrated, and validated using two independent observed data sets to evaluate the SWAT efficiency …

Modeling Canopy Effect In The Great Lakes Cladophora Model, Ankita Bakshi

Dissertations, Master's Theses and Master's Reports

Cladophora glomerata is a filamentous green alga native to the Great Lakes. However, its nuisance growth in phosphorus rich waters negatively affects the lakes’ aesthetic and water quality. The Great Lakes Cladophora Model (GLCM) v1, developed in 1982, was the first mechanistic model to simulate Cladophora growth basing phosphorus availability and environmental conditions followed by Cladophora Growth Model and GLCM v2. In this study, the light and temperature mediation factors for Cladophora net growth are revised as a necessary step prior to the development of a self-shading algorithm. The concept of a fixed-value, maximum achievable biomass (carrying capacity) employed in …

Holistic Approach In Microalgae Conversion To Bioproducts And Biofuels Through Flash Hydrolysis, Ali Teymouri

Civil & Environmental Engineering Theses & Dissertations

In recent years, the demand for renewable energy, mainly biomass has increased. The U.S. Energy Information Administration reported that more than 13.3% of the total energy production in the first seven months of 2017 was produced from a biomass source. Among all biomass resources, microalgae has brought a lot of attention due to their numerous advantages such as higher growth rate and productivity compared with the conventional energy crops, higher energy conversion efficiency by photosynthesis, and less water requirement than terrestrial crops. However, its development is far behind industrial production. Several research efforts across the globe have been concerned with …

The Role Of Al And Fe In Controlling Internal P Loading, Lake Auburn, Me, Heather Doolittle

Electronic Theses and Dissertations

Lake Auburn, Maine, U.S.A. is a historically oligotrophic lake serving as the primary drinking water source to a population of 40,000. In 2011 and 2012 the local water district observed decreasing water quality, evidenced by increasing epilimnetic total phosphorus (P) concentrations, increasing lake turbidity and the appearance of cyanobacteria. These conditions are especially concerning due to Lake Auburn’s exemption from filtration by the EPA. The decline in water quality has been linked to widespread hypolimnetic summer anoxia, causing internal P loading from the lake sediment. This study evaluated the chemical P speciation in hypolimnetic sediment from Lake Auburn following the …

Nutrient Recovery From Anaerobic Membrane Bioreactor Permeate Using Ion Exchange, Patrick Mullen

Master's Theses (2009 -)

Phosphorus is a common element in wastewater streams and traditional treatment processes are often designed remove it to achieve low effluent limits. Such processes often do not often consider the potential value of the nutrient. Currently, production of phosphate fertilizers has dramatically risen causing concern for the depletion of phosphate rock reserves, bringing about exploration into alternative sources of phosphorus for agricultural use. Combining the needs of phosphorus removal from wastewaters and securing alternate sources of the nutrient provide an opportunity for recovery. This project evaluated a nutrient recovery process through ion exchange with beneficial recovery as precipitated struvite using …

Diffuse Nutrient Pollution From Residential Catchments, Melissa Rachelle Butcher

USF Tampa Graduate Theses and Dissertations

Nonpoint source nutrient pollution is diffuse pollution lacking discrete origin and conveyance. This thesis synthesizes and critically reviews research on residential nitrogen and phosphorus loss to stormwater runoff and leaching. The evaluation pulls from research covering influential socio-demographic indicators, such as use of lawn maintenance services and homeowner fertilizer practices. The extent to which such social and economic factors may influence the prevalence and fate of diffuse nutrients in stormwater runoff from residential areas has not been adequately established. Understanding the source and influencing factors of diffuse nutrient pollution is important in order to effectively protect surface and groundwater resources. …

Phosphorus Mobility In The Shallow Unconfined Aquifer At Pineview Reservoir, Utah, Christine Rumsey

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Significant phosphorus transport is occurring in the groundwater surrounding Pineview Reservoir. A set of investigations was completed to identify factors contributing to phosphorus mobility. Water quality monitoring was conducted to understand groundwater characteristics and phosphorus movement. Several water quality parameters were evaluated to specifically determine whether septic systems influence groundwater quality. Results indicate that septic systems pollute at least two locations in the aquifer around the reservoir. Given this information, it may be necessary to implement advanced septic system treatment options to reduce the amount of phosphorus in groundwater.

Experiments were conducted on two aquifer sediment types to identify factors …