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Full-Text Articles in Engineering
Metalloporphyrin Catalyzed Degradation Of Pce: Effects Of Reductants, Buffers And Cosolvent Concentration, Sowmya Suryanarayanan
Metalloporphyrin Catalyzed Degradation Of Pce: Effects Of Reductants, Buffers And Cosolvent Concentration, Sowmya Suryanarayanan
All Theses
Reductive dechlorination of chlorinated organic contaminants using metalloporphyrins as catalysts may be an effective approach to treat widespread contamination. However, most previous studies have examined water-soluble rather than insoluble metalloporphyrins despite the fact that the latter category makes up the largest fraction found in nature. Recent studies have shown that addition of different cosolvents to water can activate otherwise non-reactive metalloporphyrin catalysts and facilitate the reduction of tetrachloroethylene (PCE), presumably by the mere process of making the otherwise insoluble metalloporphyrins dissolve in solution. Therefore, solubility has been advanced as a key factor in the ability of metalloporphyrins to catalyze organic …
Evaluation Of A Computer Vision Traffic Surveillance System, Robert Graham
Evaluation Of A Computer Vision Traffic Surveillance System, Robert Graham
All Theses
This thesis presents an evaluation of the accuracy of a novel computer vision traffic sensor - developed by the Clemson University Electrical and Civil Engineering Departments - capable of collecting a variety of traffic parameters. More specific, the thesis examines how the camera height and distance from the travel way affects the accuracy. The details of the quantitative and qualitative evaluations used to validate the system are provided. The parameters chosen to evaluate were volume, vehicle classification, and speed. Experimental results of cameras mounted at heights of 20 and 30 feet and a lateral distance of 10 and 20 feet …
Bacterial Auto-Aggregation And Co-Aggregation In Activated Sludge, Fei Chen
Bacterial Auto-Aggregation And Co-Aggregation In Activated Sludge, Fei Chen
All Theses
Microbial auto-aggregation and co-aggregation, leading to biofilm or floc formation, widely occur in natural systems. This study was conducted to investigate the extent of bacterial auto-aggregation and co-aggregation in activated sludge and their contributions in activated sludge floc formation. In this study, an activated sludge sample was separated into a supernatant part (planktonic community) and a sediment part (floc community) by centrifugation at 650_g for 2 minutes. 197 strains were isolated from both communities. These isolates belong to 18 phylotypes based on molecular identifications. Similar phylogenetic distributions of these isolates were observed in planktonic and floc communities, suggesting a similar …
Laboratory Evaluation Of Microbial Aggregation In Activated Sludge, Xiaoling Liu
Laboratory Evaluation Of Microbial Aggregation In Activated Sludge, Xiaoling Liu
All Theses
Microbial aggregation was investigated in this study using the activated sludge process as a model system, the performance of which is highly dependent on effective bioaggregation. This research includes two experiments. First, four laboratory-scale activated sludge sequencing batch reactors (SBRs) were constructed in order to evaluate the effect of solids retention time (SRT) on microbial aggregation. These SBRs were operated at SRT of 4, 8, 16, and 32 days, respectively, fed with a protein-based synthetic wastewater, and monitored over a period of 268 days for performance and sludge settling characteristics including soluble COD in the effluent (sCOD), sludge volume index …
Seismic Fragility Curves For A Typical Highway Bridge In Charleston, Sc Considering Soil-Structure Interaction And Liquefaction Effects, Matthew Bowers
Seismic Fragility Curves For A Typical Highway Bridge In Charleston, Sc Considering Soil-Structure Interaction And Liquefaction Effects, Matthew Bowers
All Theses
Evidence from historical earthquakes suggests that the vulnerability of highway bridges is significantly affected by large permanent ground deformations caused by liquefaction as well as soil-structure interaction (SSI). The vulnerability of a typical multi-span simply-supported (MSSS) concrete girder bridge found in Charleston, South Carolina, is evaluated with consideration for liquefaction and SSI effects. In general, existing bridges in this region were not originally designed with consideration for seismic events or liquefaction of underlying soils. Fragility curves that represent the probability of exceeding predefined performance levels of damage given an earthquake of a particular intensity are used to evaluate the effects …
Cosolvent Effects On The Reductive Dechlorination Of Tetrachloroethylene Catalyzed By Iron Tetraphenyl Porphyrin Chloride, Lavanya Ramasubramanian
Cosolvent Effects On The Reductive Dechlorination Of Tetrachloroethylene Catalyzed By Iron Tetraphenyl Porphyrin Chloride, Lavanya Ramasubramanian
All Theses
Abiotic electron transfer mediated reductive dechlorination reactions have been studied extensively in the past decade. Porphyrins and metalloporphyrins are common electron transfer mediators used. Past studies have shown that some metalloporphyrins play a key role in increasing the rate of reaction in the presence of cosolvents. There have also been suggestions that organic cosolvents enhance the rate of reduction by increasing the solubility of metalloporphyrins.
The primary objective of this project was to examine the effect of cosolvents on the metalloporphyrin-catalyzed reductive dechlorination of tetrachloroethylene (PCE). Subsequently, experiments were also conducted to test the hypothesis that metalloporphyrin solubility is linked …
Assessing Asr Potential Of Hardened Concrete And The Use Of Rice Husk Ash To Mitigate Asr, David Wingard
Assessing Asr Potential Of Hardened Concrete And The Use Of Rice Husk Ash To Mitigate Asr, David Wingard
All Theses
This two part research study was created to first develop a new process using existing test methods to determine the Alkali-Silica Reaction (ASR) potential of hardened concrete that is exposed to external alkalis and secondly to determine the ASR mitigation potential of using rice husk ash (RHA) as a supplementary cementitious material (SCM). The first part of the research study was completed by using a new aggregate extraction procedure that uses a combination of hydrochloric acid treatments and abrasion to remove the cement paste from the aggregate. This extracted aggregate was then crushed down to the specified sizes and used …
A Pilot Study On The Effects Of Temperature On The Material Properties Of Prestressed Concrete And The Use Of Thermogravimetric Analysis In The Assessment Of Heat-Affected Concrete, Kacie Caple
All Theses
An understanding of the material property changes in building materials due to exposure to a fire is needed for accurate damage assessment of a structure. Discussion pertaining to material property changes and the bond between concrete and prestressing steel following elevated temperature exposures is presented. Evaluation of the use of thermogravimetric analysis (TGA) as a post-fire analysis tool to determine the maximum temperature exposure of concrete is also included.
Heated concrete cylinders were tested to determine the compressive strength and modulus of elasticity changes of concrete. Heated steel prestressing strands were tested in tension to determine changes in the ultimate …
Experimental And Analytical Application Of The Hodd Method For The Detection Of Damage, Jacob Merkley
Experimental And Analytical Application Of The Hodd Method For The Detection Of Damage, Jacob Merkley
All Theses
Detecting damage location and severity in civil engineering structures has become an important research topic in the past several decades. Various non-destructive damage identification methods using dynamic properties from ambient and forced vibration have been developed. Researchers have shown that higher order derivatives of mode shapes of the 2nd and 4th order can be effective in detecting damage in civil engineering structures. Furthermore, these higher order derivatives are sensitive to small changes in global stiffness facilitating the detection of small degrees of damage.
In this study a modal analysis is performed on analytical and experimental simply supported beams using the …
Performance Based Contracting And Improving The Current Contracting Process, Troy Berkland
Performance Based Contracting And Improving The Current Contracting Process, Troy Berkland
All Theses
The primary objective of the research described in this report was to suggest improvements to the maintenance contracting process currently utilized by the South Carolina Department of Transportation (SCDOT). A secondary research objective was to examine to what extent SCDOT could migrate more toward performance based, as opposed to method based, highway maintenance specifications.
A comprehensive literature review indicated some states had successfully implemented performance based specifications for a wide range of maintenance activities whereas others had not. Some states have adopted performance based specifications as part of a comprehensive asset management program whereby the contractor typically performs all routine …
Achiral And Chiral Analysis Of Polychlorinated Biphenyls (Pcbs) In The Aquatic And Riparian Food Webs In Twelve Mile Creek, South Carolina., Viet Dang
All Theses
Polychlorinated biphenyls (PCBs) contamination in the Twelve Mile Creek arm of Lake Hartwell, South Carolina, has been an issue for decades. Lake Hartwell, which is a reservoir located on the border between the states of South Carolina and Georgia, was contaminated with an estimated 440,000 pounds of PCBs. PCBs were released from the Sangamo-Weston capacitor plant located on Town Creek, which feeds into Twelve Mile Creek and ultimately Lake Hartwell. The Twelve Mile Creek tributary connecting the Sangamo-Weston plant to Lake Hartwell has had little attention. Understanding PCBs contamination in the aquatic and riparian food webs of Twelve Mile Creek …
Assessment Of Driver Speeds, Compliance In Rural School Zones: Comparison Of Speed By School Level And Time Of Day, Stuart Day
All Theses
TThis study analyzed driver's speeds prior to entering school zones as well as the speeds traveling through school zones. A comparison was conducted to determine if drivers complied with school speed zones using only the standard school sign arrangement found in the Manual on Uniform Traffic Control Device. Two rural school zones in Oconee County, South Carolina were analyzed in this study as rural areas tend to have higher speeds and fewer other factors that could contribute to changes in driver behavior. In order to gather data, data collection devices known as Hi-Stars were placed in the roadway on both …
Steer It And Clear It: Effectiveness Of Quick Clearance Legislation, Amy Carol Hamlin
Steer It And Clear It: Effectiveness Of Quick Clearance Legislation, Amy Carol Hamlin
All Theses
Innovative incident management strategies have been sought by transportation professionals to minimize the impacts of incidents on traffic operation and safety. Some current quick clearance strategies such as 'Steer It and Clear It' legislation in South Carolina, which requires driver(s) of involved vehicle(s) in a minor incident to move vehicles promptly from the traveled roadway prior to the arrival of the first responders, can potentially reduce the duration of an incident. The research detailed in this paper endeavored to measure the benefit of the Steer It and Clear It law on a section of I-85 in South Carolina. A simulation …
Comparison Of Effectiveness Of Roadway Design Treatments For Transitioning From Rural Areas To Urban Areas Using A Driving Simulator, Candice Hein
All Theses
Traffic fatalities are a leading cause of death in the United States. Rural roads are especially hazardous as they account for 60 percent of all traffic fatalities in the United States. Three main reasons for the rural road problems are high speeds, low volumes, and reduced driver awareness. This is particularly problematic where these roads navigate through communities requiring reduced speeds. Drivers who aren't alert and are driving too fast often miss the reduced speed warning signs and often don't slow until after they have entered the community. Therefore, engineers must do something to the design of the roadway environment …
Approaches To Mitigate The Impact Of Dissolved Organic Matter On The Adsorption Of Synthetic Organic Contaminants By Activated Carbon, Abhishek Yadav
Approaches To Mitigate The Impact Of Dissolved Organic Matter On The Adsorption Of Synthetic Organic Contaminants By Activated Carbon, Abhishek Yadav
All Theses
The main objective of this study was to conduct a systematic investigation of various approaches to mitigate the competition of dissolved organic matter (DOM) on the adsorption of synthetic organic contaminants (SOCs) by activated carbons. TCE and atrazine were selected as the target SOCs because they are known to adsorb in different pore size regions. TCE adsorbs in the primary micropore region (i.e., <10 ) which is inaccessible to the majority of the DOM components, while atrazine adsorbs in the secondary micropore region (i.e., 10-20 ) which is partially accessible to some DOM components. The adsorbents used in this study consisted of four activated carbons (OLC, CRC, F400He, and HD4000ST) and one activated carbon fiber (ACF: ACF10). All sorbents were basic and hydrophobic in nature and represented a set of activated carbons with gradually widening pore size distribution, from the extremely microporous carbons (ACF10 and OLC) to carbons with some amount of mesopores (CRC and F400He) and finally a predominantly mesoporous (HD4000ST) carbon.
Isotherms were performed as single solute and after preloading with a dissolved organic matter (5 mg DOC/L and 20 mg DOC/L) for both TCE and atrazine and using the five activated carbons. Single solute isotherm results showed …
Development And Evaluation Of An Enrichment Culture For Bioaugmentation Of The P-Area Chlorinated Ethene Plume At The Savannah River Site, Elizabeth Wood
Development And Evaluation Of An Enrichment Culture For Bioaugmentation Of The P-Area Chlorinated Ethene Plume At The Savannah River Site, Elizabeth Wood
All Theses
The Twin Lakes chlorinated ethene plume at the Department of Energy's
Savannah River Site (SRS) emerges in a wetland in which trichloroethene (TCE) is
completely reduced to ethene and ethane. Novel strains of Dehalococcoides have been
detected from the wetland area. The objectives of this study were 1) to develop an
enrichment culture capable of completely dechlorinating TCE and tetrachloroethene
(PCE) to ethene using samples from the wetland; 2) to evaluate the use of lactate,
emulsified vegetable oil and corn syrup as possible electron donors for biostimulation of
the P-area chlorinated ethene plume at SRS that is not undergoing natural …
Characterization Of The Ibc Technologies Superlig¨ 620 Solid Phase Extraction Resin With Applications For Automated Process Monitoring, John Clements
Characterization Of The Ibc Technologies Superlig¨ 620 Solid Phase Extraction Resin With Applications For Automated Process Monitoring, John Clements
All Theses
Characterization of the IBC Advanced Technologies SuperLig¨ 620 solid phase extraction resin was performed in order to develop an automated strontium-90 process monitor. The main focus was on strontium separation from barium, with the goal of developing an automated separation process for strontium-90 in Hanford high-level tank wastes. High-level waste tanks contain significant cesium-137 activities, of which barium daughters are of great concern as interferences to strontium quantification. A number of complexants were studied in a series of batch distribution coefficient experiments, as SuperLig¨ 620 was not previously known to elute strontium in typical mineral acids. The optimal separation was …
Evaluation Of Different Contra-Flow Strategies For Hurricane Evacuation In Charleston, South Carolina, Liz Stephen
Evaluation Of Different Contra-Flow Strategies For Hurricane Evacuation In Charleston, South Carolina, Liz Stephen
All Theses
The number of category four and five hurricanes has nearly doubled over the past decade. Charleston, the second most populous city in South Carolina, is located on a very low peninsula, making it susceptible to floods during hurricanes and storm surges. In the event of a hurricane, the population at-risk must be evacuated to safety as quickly as possible. The Interstate system is the primary mode to evacuate at-risk population out of Charleston. Effective traffic management strategies are needed to manage the significant increase in demand on highways during the evacuation and contra-flowing traffic has been applied as a strategy …
Application Of Classical Versus Bayesian Statistical Methods To On-Line Radiological Monitoring, Amy Attardo
Application Of Classical Versus Bayesian Statistical Methods To On-Line Radiological Monitoring, Amy Attardo
All Theses
The on-line monitoring for illicit radioactive material with a minimum number of false detections is a critical need for homeland security. The primary objectives of this work were to apply both Bayesian and classical statistical process control chart techniques to the on-line monitoring of radiological data and to then compare the Type I and Type II error incidence rates. Two versions of the cumulative sum (CUSUM) and Shiryayev-Roberts (S-R) procedures known as total reset and alarm reset methods were developed. The best method in terms of Type I errors was the S-R total reset method. In terms of Type II …