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Civil and Environmental Engineering

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University of Massachusetts Amherst

2023

: Alkali activation; Carbon-based nanomaterials; Cavitation; Isothermal adsorption; Nanoindentation; Organosilanes; Sol-gel; Surface hierarchical; Superhydrophobicity

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Functionalizing Three-Dimensional Superhydrophobic Materials, Li He Apr 2023

Functionalizing Three-Dimensional Superhydrophobic Materials, Li He

Doctoral Dissertations

Traditional bulk superhydrophobic materials are usually characterized by high porosity, low fracture toughness, and extremely low strength due to the low surface energy on the internal surface. Therefore, it is very challenging to achieve a bulk superhydrophobic material with high strength and mechanical durability. This dissertation presents an experimental study of strengthening a superhydrophobic siloxane using carbon-based nanomaterials, emphasizes the effects of microscale dispersion and macroscale distribution of reinforcing graphene on the uniformity and strength of the composite, studies the impact factors on the water adsorption for hydrophilic and hydrophobic materials, and applies chemical modification modify the surface of clay …