Engineering Commons^™

Fabrication Of Size-Tunable Metallic Nanoparticles Using Plasmid Dna As A Biomolecular Reactor, Jacopo Samson, Irene Piscopo, Alex Yampolski, Patrick Nahirney, Andrea Parpas, Amit Aggarwal, Raihan Saleh, Charles Michael Drain

Publications and Research

Plasmid DNA can be used as a template to yield gold, palladium, silver, and chromium nanoparticles of different sizes based on variations in incubation time at 70 °C with gold phosphine complexes, with the acetates of silver or palladium, or chromium acetylacetonate. The employment of mild synthetic conditions, minimal procedural steps, and aqueous solvents makes this method environmentally greener and ensures general feasibility. The use of plasmids exploits the capabilities of the biotechnology industry as a source of nanoreactor materials.

A Modified Surface On Titanium Deposited By A Blasting Process, Caroline O' Sullivan, Peter O'Hare, Greg Byrne, Liam O'Neill, Katie B. Ryan, Abina M. Crean

Publications

Abstract

: Hydroxyapatite (HA) coating of hard tissue implants is widely employed for its biocompatible and osteoconductive properties as well as its improved mechanical properties. Plasma technology is the principal deposition process for coating HA on bioactive metals for this application. However, thermal decomposition of HA can occur during the plasma deposition process, resulting in coating variability in terms of purity, uniformity and crystallinity, which can lead to implant failure caused by aseptic loosening. In this study, CoBlast™, a novel blasting process has been used to successfully modify a titanium (V) substrate with a HA treatment using a dopant/abrasive regime. …

Thirdhand Tobacco Smoke: Emerging Evidence And Arguments For A Multidisciplinary Research Agenda, Georg E. Matt, Penelope J. Quintana, Hugo Destaillats, Lara A. Gundel, Mohamad Sleiman, Brett C. Singer, Peyton Jacob, Jonathan P. Winickoff, Prue Talbot, Suzaynn Schick, Yinsheng Wang, Bo Hang, Manuela Martins-Green, James F. Pankow, Melbourne F. Hovell, Neal L. Benowitz, Virender K. Rehan, Jonathan M. Samet

Civil and Environmental Engineering Faculty Publications and Presentations

There is broad consensus regarding the health impact of tobacco use and secondhand smoke exposure, yet considerable ambiguity exists about the nature and consequences of thirdhand smoke (THS). We introduce definitions of THS and THS exposure and review recent findings about constituents, indoor sorption-desorption dynamics, and transformations of THS; distribution and persistence of THS in residential settings; implications for pathways of exposure; potential clinical significance and health effects; and behavioral and policy issues that affect and are affected by THS. Physical and chemical transformations of tobacco smoke pollutants take place over time scales ranging from seconds to months and include …

Miniature Mass Spectrometry: Rf Amplitude Control System Design, Matthew Allen Kirleis

Purdue Polytechnic Masters Theses

This thesis covers the methods used to construct and characterize a custom digital RF amplitude control system. Many types of mass spectrometers exist, but few have been miniaturized as much as the Mini instruments developed at Purdue University. The goal of this research was to improve upon an earlier amplitude control system consisting of analog circuits first implemented in the Mini 11.5 mass spectrometer developed at Purdue University.

A custom set of control and data acquisition electronics were developed for testing the digital and analog control systems in a Mini 11.5 mass spectrometer chassis. A MATLAB Simulink simulation was done …

Using Nanotechnology To Detect Nerve Agents, Mark N. Goltz, Dong-Shik Kim, Leeann Racz

Faculty Publications

Nanotechnology has opened a wide range of opportunities having potential impacts in areas as diverse as medicine and consumer products. In collaboration with researchers at the University of Toledo UT, Air Force Institute of Technology AFIT scientists are exploring the possibility of using a nanoscale organic matrix to detect organophosphate OP nerve agents. Current techniques for detecting OP compounds are expensive and time consuming. Developing a nanoscale organic matrix sensor would allow for direct, real-time sensing under field conditions. This article describes the science behind such a sensor and its possible applications. High-performance sensors are needed to protect Soldiers and …

Effect Of Freshman Chemistry On Student Performance In Sophomore Engineering Courses, Michael A. Collura, Shannon Ciston, Nancy Ortins Savage

Chemistry and Chemical Engineering Faculty Publications

The role of first year chemistry courses in engineering programs varies somewhat across programs and disciplines. Clearly most engineering majors will encounter chemistry topics of a general nature in some of their upper-level course work. The purpose of requiring chemistry in the first year, however, goes well beyond learning chemical concepts. As a quantitative science, chemistry requires the use of math, principally algebra, on a regular basis in solving various problems. Students should gain an appreciation of the importance of units in solving problems should come to understand the difference between implicit and explicit properties and should develop other quantitative …

Unlv Stars Unabridged Report, University Of Nevada, Las Vegas

Reports (USI)

University of Nevada, Las Vegas, by earning a 2011 Silver Rating in the Sustainability Tracking, Assessment & Ratings System (STARS), is ahead of the curve among public universities – and improving.

STARS is a voluntary, self–reporting framework developed by the Association for the Advancement of Sustainability in Higher Education (AASHE) to help measure sustainability performance over time and among colleges and universities nationwide. The UNLV Sustainability Council oversaw STARS, which by measuring sustainability can help UNLV to reduce energy consumption and waste, improve education, attract research, and generate jobs.

A rating of Silver puts UNLV in great company – with …

Impacts Of The Species Elaeagnus Umbellate On The Soil And Water Quality Of The Pierce Cedar Creek Institute Ecosystem, Yacoub Aljobeh, Kristin Engerer

Symposium on Undergraduate Research and Creative Expression (SOURCE)

The species Elaeagnus umbellate, more commonly known as autumn olive, is a shrub that is invasive to the United States and indigenous to East Asia. Even though the autumn olive is not native to North America, it was able to thrive and adapt to the new environment by using its ability to fix nitrogen. Nitrogen-fixing is a process where plants intake molecular nitrogen from the atmosphere and convert it into other forms of nitrogen that can be used by the plants. One of the nitrogen-fixing by-products is nitrate. Excessive amounts of nitrate can easily leach from the plant’s root …

Fabrication Of Poly(Vinylidene Fluoride) (Pvdf) Nanofibers Containing Nickel Nanoparticles As Future Energy Server Materials, Faheem A. Sheikh, Travis Cantu, Javier Macossay-Torres, Hern Kim

Chemistry Faculty Publications and Presentations

In the present study, we introduce Poly(vinylidene fluoride) (PVDF) nanofibers containing nickel (Ni) nanoparticles (NPs) as a result of an electrospinning. Typically, a colloidal solution consisting of PVDF/Ni NPs was prepared to produce nanofibers embedded with solid NPs by electrospinning process. The resultant nanostructures were studied by SEM analyses, which confirmed well oriented nanofibers and good dispersion of Ni NPs over them. The XRD results demonstrated well crystalline feature of PVDF and Ni in the obtained nanostructures. Physiochemical aspects of prepared nano-structures were characterized for TEM which confirmed nanofibers were welloriented and had good dispersion of Ni NPs. Furthermore, the …

Institute Overview, Morton Sternheim

STEM Digital

Digital cameras and computers are widely available for students and teachers. However, they are mainly used for documentation: creating PPT presentations, handouts, posters, etc. STEM DIGITAL shows how digital image analysis can be applied to environmental (and other) research in STEM courses. Application to studies of air quality, water quality, arsenic contamination, climate change, diffusion, etc.

Digital Camera Basics, Stephen Schneider

STEM Digital

No abstract provided.

Measuring Lengths And Areas With Adi. Student Guide, Morton Sternheim

STEM Digital

No abstract provided.

Measuring G With Movie Tracker, Stephen Schneider

STEM Digital

No abstract provided.

Detecting And Mixing Colors, Rob Snyder

STEM Digital

How can Analyzing Digital Images software reveal the differences between primary colors of light and primary colors of paints or pigments?

Measuring The Acceleration Of Falling Objects, John Pickle

STEM Digital

Earth's gravity pulls all objects toward its center, and near the Earth's surface. Objects in free fall accelerate at 9.8 m/s² vertically downward, provided air resistance is negligible. This value of acceleration is often referred to as "g". There are many ways to measure this rate of acceleration, and most require a timing device. Typically, stopwatches are the least expensive technology, so these are commonly available in high school science classrooms. With the recent addition of movie cameras on cell phones and digital cameras, another timing tool is available at moderate cost (free if the school policy …

Leaf Leaching Experiment, David Reckhow

STEM Digital

Water treatment engineers and public health officials need to pay careful attention to the presence of dissolved organic matter in water supplies selected for human consumption (i.e., raw drinking waters).

Measuring Albedo With Adi - An Intensity Application, Morton Sternheim

STEM Digital

Why are Polar Regions more affected by global warming than other parts of the globe? One reason (there are others) is that as sea ice melts and more open water appears, more energy is absorbed, and warming accelerates. This is a form of positive feedback and it makes the polar climate change faster than the climate in temperate areas. Increasing vegetation on land also has a similar positive feedback effect. This effect is a change in the albedo – the fraction of the incident sunlight that is reflected back to space.

Stem Digital And Adi In The Classroom, Jennifer Welborn

STEM Digital

Applications of ADI by students at Amherst Regional Middle School

Co2 Diffusion Through Gelatin Experiment, Jennifer Welborn

STEM Digital

An example of measuring lengths.

Natural Organic Matter In Water, David Reckhow

STEM Digital

Formation in Watersheds and Removal in Water Treatment

Using Adi To Quantify A Color Change In Crayfish, Jennifer Welborn

STEM Digital

Do Crayfish Change Color If Their Environment Changes? A Guided Inquiry Lab for 7th grade Life Science

Background: There is anecdotal evidence from bass fisherman that crayfish are able to change color depending on their surroundings. A (cursory) literature review of this phenomenon showed that no formal research has been done in this area. Students had an additional informal lesson about research funding (or lack thereof) because of this finding.

Students designed and conducted a controlled experiment to see the effect of changing environment color on crayfish color.

ADI was used to quantify a color change.

Human Variation In Skin Color And Race As A Social Construct, Jennifer Welborn

STEM Digital

This lesson is part of evolution unit which follows heredity and genetics

The lesson is interdisciplinary in nature in that I discuss the concept of race as a social construct and the idea that there are “black, white, red, yellow” skinned people is something that people developed. It is not based on biology. Race groupings are human-made groups.

Students first learn about mixing light and how to determine black and white from an ADI analysis. They learn that red and green = yellow, etc.

They then photograph each other’s forearms and analyze the images using ADI.

We then discuss skin …

Air Quality: Carbon Dioxide, Deborah Carlisle, Stephen Schneider

STEM Digital

Measuring CO2 with BTB and ADI.

Measuring Angles With Adi, Stephen Schneider

STEM Digital

No abstract provided.

Analyzing Digital Images (Adi) Resources, Rob Snyder

STEM Digital

Basic introduction to installing and using ADI

Arsenic Project Topics, Julian Tyson

STEM Digital

How do analytical chemists make light work in tracking potentially harmful chemicals?

Water Treatment Experiments, David Reckhow

STEM Digital

•The water industry spends a lot of money and effort on removal of natural organic matter (NOM) from drinking waters •Problems with NOM (the more NOM the bigger problem) –NOM interferes with the ability of water treatment systems to remove substances that cause disease •Pathogenic organisms •Toxic chemicals –NOM reacts with chlorine‐based disinfectants forming carcinogenic organic byproducts

Experimental Design For Ozone Projects, Deborah Carlisle, Stephen Schneider

STEM Digital

No abstract provided.

Computational Models Of Chemical Systems Inspired By Braess’ Paradox, Dante Lepore, Carl Barratt, Pauline Schwartz

Chemistry and Chemical Engineering Faculty Publications

Systems chemistry is a new discipline which investigates the interactions within a network of chemical reactions. We have studied several computational models of chemical systems inspired by mathematical paradoxes and have found that even simple systems may behave in a counterintuitive, non-linear manner depending upon various conditions. In the present study, we modeled a set of reactions inspired by one such paradox, Braess’ paradox, an interesting phenomenon whereby the introduction of additional capacity (e.g. pathways) in some simple network systems can lead to an unexpected reduction in the overall flow rate of “traffic” through the system. We devised several chemical …

The Impact Of Driving Conditions On Phev Battery Performance, Nathan Christensen, John Patten, Steven Srivastava, Gary P. Nola

Green Manufacturing Research Journal

The battery performance of a modified Prius with a 5 kWh plug-in battery was documented for a year to determine the impact of environmental conditions and user attributes on vehicle performance. Both fuel economy and pure electrical efficiency were compared to ambient temperature. The fuel economy has a positive relationship with ambient temperature until approximately 70˚F where the efficiency begins to drop. Electrical performance has a positive linear relationship with ambient temperature. With the emergence of electric vehicles (EVs) and PHEVs from a variety of automotive manufacturers, information on EV and PHEV performance for consumers will become more important.