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Articles 1 - 20 of 20
Full-Text Articles in Engineering
Using Slow-Release Permanganate Candles To Remove Tce From A Low Permeable Aquifer At A Former Landfill, Mark D. Christenson, Ann Kambhu, Steve D. Comfort
Using Slow-Release Permanganate Candles To Remove Tce From A Low Permeable Aquifer At A Former Landfill, Mark D. Christenson, Ann Kambhu, Steve D. Comfort
School of Natural Resources: Faculty Publications
Past disposal of industrial solvents into unregulated landfills is a significant source of groundwater contamination. In 2009, we began investigating a former unregulated landfill with known trichloroethene (TCE) contamination. Our objective was to pinpoint the location of the plume and treat the TCE using in situ chemical oxidation (ISCO). We accomplished this by using electrical resistivity imaging (ERI) to survey the landfill and map the subsurface lithology. We then used the ERI survey maps to guide direct push groundwater sampling. A TCE plume (100-600 µg L-1) was identified in a low permeable silty-clay aquifer (Kh = 0.5 …
Rat Brain Pro-Oxidant Effects Of Peripherally Administered 5 Nm Ceria 30 Days After Exposure, Sarita S. Hardas, Rukhsana Sultana, Govind Warrier, Mo Dan, Rebecca L. Florence, Peng Wu, Eric A. Grulke, Michael T. Tseng, Jason M. Unrine, Uschi M. Graham, Robert A. Yokel, D. Allan Butterfield
Rat Brain Pro-Oxidant Effects Of Peripherally Administered 5 Nm Ceria 30 Days After Exposure, Sarita S. Hardas, Rukhsana Sultana, Govind Warrier, Mo Dan, Rebecca L. Florence, Peng Wu, Eric A. Grulke, Michael T. Tseng, Jason M. Unrine, Uschi M. Graham, Robert A. Yokel, D. Allan Butterfield
Chemistry Faculty Publications
The objective of this study was to determine the residual pro-or anti-oxidant effects in rat brain 30 days after systemic administration of a 5 nm citrate-stabilized ceria dispersion. A ∼4% aqueous ceria dispersion was iv-infused (0 or 85 mg/kg) into rats which were terminated 30 days later. Ceria concentration, localization, and chemical speciation in the brain was assessed by inductively coupled plasma mass spectrometry (ICP-MS), light and electron microscopy (EM), and electron energy loss spectroscopy (EELS), respectively. Pro- or anti-oxidant effects were evaluated by measuring levels of protein carbonyls (PC), 3-nitrotyrosine (3NT), and protein-bound-4-hydroxy-2-trans-nonenal (HNE) in the hippocampus, cortex, and …
Method And Apparatus For Jet-Assisted Drilling Or Cutting, David A. Summers, Klaus Woelk, Kenneth Doyle Oglesby, Greg Galecki
Method And Apparatus For Jet-Assisted Drilling Or Cutting, David A. Summers, Klaus Woelk, Kenneth Doyle Oglesby, Greg Galecki
Mining Engineering Faculty Research & Creative Works
An abrasive cutting or drilling system, apparatus and method, which includes an upstream supercritical fluid and/or liquid carrier fluid, abrasive particles, a nozzle and a gaseous or low-density supercritical fluid exhaust abrasive stream. The nozzle includes a throat section and, optionally, a converging inlet section, a divergent discharge section, and a feed section.
Effects Of Thiophene Units On Substituted Benzothiadiazole And Benzodithiophene Copolymers For Photovoltaic Applications, Ping Ding, Yingping Zou, Cheng-Che Chu, Dequan Xiao, Chain-Shu Hsu
Effects Of Thiophene Units On Substituted Benzothiadiazole And Benzodithiophene Copolymers For Photovoltaic Applications, Ping Ding, Yingping Zou, Cheng-Che Chu, Dequan Xiao, Chain-Shu Hsu
Chemistry and Chemical Engineering Faculty Publications
Two conjugated copolymers, P1 and P2, comprising of benzodithiophene and 5, 6-dioctyloxy-benzothiadiazole (DOBT) derivatives with/without thiophene unit, were synthesized via Stille cross-coupling polymerization reaction. These copolymers are promising for the applications in BHJ solar cells due to their good solubilities， proper thermal stability and moderate hole mobility as well as low bandgap. The photovoltaic properties of the copolymers were investigated based on the blend of the different polymer/PC71BM weight ratio under AM1.5G illumination, 100 mW/cm2. The device with ITO/PEDOT:PSS/P2: PC71BM (1:2, w/w)/Ca/Al gave relatively better photovoltaic performance, with a power conversion efficiency of 1.55%.
Investigation Of Spillover Effect To Enhance Hydrogen Storage, Sarah C. Corrigan, Lin Simpson, Thomas Gennett
Investigation Of Spillover Effect To Enhance Hydrogen Storage, Sarah C. Corrigan, Lin Simpson, Thomas Gennett
STAR Program Research Presentations
Hydrogen is an attractive energy option because of its low
environmental impact, but a critical problem is its low energy
density, which makes it difficult to store. For example, the US
Department of Energy (DOE) hydrogen plan for fuel cell powered
vehicles requires a gravimetric density of 6.5 wt%. There are several
existing hydrogen storage methods, including compressed gas,
liquefaction, metal hydrides, and physisorption, but at present, none
of these technologies comes close to achieving the targets set by the
DOE. Although chemical storage methods have been claimed to be the
most promising hydrogen storage technology, and activated carbons the …
En Route Towards Α-Benzotriazoyl Nitroso Derivatives, Jean-Christophe M. Monbaliu, Lucas K. Beagle, Judit K. Beagle, Matthias Zeller, Christian V. Stevens, Alan R. Katritzky
En Route Towards Α-Benzotriazoyl Nitroso Derivatives, Jean-Christophe M. Monbaliu, Lucas K. Beagle, Judit K. Beagle, Matthias Zeller, Christian V. Stevens, Alan R. Katritzky
Chemistry Faculty Publications
A new class of geminally-substituted nitroso compounds, i.e., α-benzotriazoyl nitroso derivatives, is presented. These compounds display a rather different behavior than other related nitroso compounds bearing a geminal electron-withdrawing group. An unexpected and spontaneous oxidation to the nitro analog is observed in solution.
Data Mining Of Protein Databases, Christopher Assi
Data Mining Of Protein Databases, Christopher Assi
Department of Computer Science and Engineering: Dissertations, Theses, and Student Research
Data mining of protein databases poses special challenges because many protein databases are non-relational whereas most data mining and machine learning algorithms assume the input data to be a relational database. Protein databases are non-relational mainly because they often contain set data types. We developed new data mining algorithms that can restructure non-relational protein databases so that they become relational and amenable for various data mining and machine learning tools. We applied the new restructuring algorithms to a pancreatic protein database. After the restructuring, we also applied two classification methods, such as decision tree and SVM classifiers and compared their …
Transparent Conducting Films Of Cdse(Zns) Core(Shell) Quantum Dot Xerogels, Lasantha Korala, Li Li, Stephanie L. Brock
Transparent Conducting Films Of Cdse(Zns) Core(Shell) Quantum Dot Xerogels, Lasantha Korala, Li Li, Stephanie L. Brock
Chemistry Faculty Research Publications
A method of fabricating sol–gel quantum dot (QD) films is demonstrated, and their optical, structural and electrical properties are evaluated. The CdSe(ZnS) xerogel films remain quantum confined, yet are highly conductive (10−3 S cm−1). This approach provides a pathway for the exploitation of QD gels in optoelectronic applications.
Concentration Effects And Ion Properties Controlling The Fractionation Of Halides During Aerosol Formation, Marcelo I. Guzman, Richa R. Athalye, Jose M. Rodriguez
Concentration Effects And Ion Properties Controlling The Fractionation Of Halides During Aerosol Formation, Marcelo I. Guzman, Richa R. Athalye, Jose M. Rodriguez
Chemistry Faculty Publications
During the aerosolization process at the sea surface, halides are incorporated into aerosol droplets, where they may play an important role in tropospheric ozone chemistry. Although this process may significantly contribute to the formation of reactive gas phase molecular halogens, little is known about the environmental factors that control how halides selectively accumulate at the air-water interface. In this study, the production of sea spray aerosol is simulated using electrospray ionization (ESI) of 100 nM equimolar solutions of NaCl, NaBr, NaI, NaNO(2), NaNO(3), NaClO(4), and NaIO(4). The microdroplets generated are analyzed by mass spectrometry to study the comparative enrichment of …
Nanoenergetic Composite Based On I2o5/Al For Biological Agent Defeat, Mkhitar Hobosyan, Alexander V. Kazanksy, Karen S. Martirosyan
Nanoenergetic Composite Based On I2o5/Al For Biological Agent Defeat, Mkhitar Hobosyan, Alexander V. Kazanksy, Karen S. Martirosyan
Physics and Astronomy Faculty Publications and Presentations
The risk of bioterrorism events involving the intentional airborne release of contagious agents has led to development of new approaches for bio agent defeat technologies both indoors and outdoors. This report describes nanoenergetic gas generators (NGG) system that exhibit long term stability and superior release of biocidal substances for destruction of pathogenic bacteria. The effect of iodine vaporization on destroying of Escherichia coli (E-coli, HB101 K-12 strain) by using expressing Green Fluorescent Protein (GFP) was investigated. HB101 K-12 has been genetically modified to prevent its growth unless grown on an enriched medium. To obtain quantitative data we used pGLO transformation …
The Solar Thermal Decoupled Electrolysis Of Water Process: An Investigation Of The Electrochemistry In A Base, Jessica Guertin
The Solar Thermal Decoupled Electrolysis Of Water Process: An Investigation Of The Electrochemistry In A Base, Jessica Guertin
Symposium on Undergraduate Research and Creative Expression (SOURCE)
The solar research team at Valparaiso University is developing solar thermal chemical processes that will transform solar energy into economically viable and reusable energy forms. One subgroup is working on the Solar Thermal Decoupled Electrolysis of Water Process. In this multi-step process, the electrolysis of water to generate hydrogen occurs at room temperature outside of the solar reactor, and it is facilitated by the oxidation of magnetite (Fe3O4) to hematite (Fe2O3). The hematite is then pumped to the solar reactor where it is reduced back to magnetite at high temperatures with the liberation of oxygen. This cycle is then repeated. …
One-Pot Synthesis In Polyamines For Preparation Of Water-Soluble Magnetite Nanoparticles With Amine Surface Reactivity, Haiou Qu, Hui Ma, Aurélien Riviere, Weilie Zhou, Charles J. O'Connor
One-Pot Synthesis In Polyamines For Preparation Of Water-Soluble Magnetite Nanoparticles With Amine Surface Reactivity, Haiou Qu, Hui Ma, Aurélien Riviere, Weilie Zhou, Charles J. O'Connor
Chemistry Faculty Publications
Magnetite nanoparticles with hydrophilic surface coating are prepared in polyamine solvents. The resulting products are highly stable in polar solvent. The surface amine groups are available for secondary reactions.
Analysis Of The Penney-Ante Game Using Difference Equations: Development Of An Optimal And A Mixed-Strategies Protocol, Carl Barratt, Pauline Schwartz
Analysis Of The Penney-Ante Game Using Difference Equations: Development Of An Optimal And A Mixed-Strategies Protocol, Carl Barratt, Pauline Schwartz
Chemistry and Chemical Engineering Faculty Publications
Penney-Ante is a well known two-player (Player I and Player II) game based on an information paradox. We present a new approach, using difference-equations, to analyzing the outcome for each player. One strategy yields a winning outcome of 75% for Player II, the player playing second. The approach also permits investigation of non-optimal strategies, and demonstrates how mixing of such strategies can be used to tune the winning edge of either player. We generalize the analysis to accommodate the possibility of a biased coin.
Development Of Tailor-Designed Gold-Platinum Nanoparticles Binary Catalysts For Efficient Formic Acid Electrooxidation, Islam M. Al-Akraa Dr, Ahmad M. Mohammad Prof, Mohamed S. El-Deab Prof, Bahgat E. El-Anadouli Prof
Development Of Tailor-Designed Gold-Platinum Nanoparticles Binary Catalysts For Efficient Formic Acid Electrooxidation, Islam M. Al-Akraa Dr, Ahmad M. Mohammad Prof, Mohamed S. El-Deab Prof, Bahgat E. El-Anadouli Prof
Chemical Engineering
The modification of a glassy carbon (GC) electrode with platinum (PtNPs) and gold (AuNPs) nanoparticles is targeted to fabricate efficient anodes for the electrooxidation of formic acid (FA). A proper adjustment of the deposition sequence of PtNPs and AuNPs could eventually enhance the electrocatalytic activity of the electrode in such a way that suppresses the CO poisoning effect during FA oxidation. The highest catalytic activity is obtained at the Au/Pt/GC electrode (with PtNPs firstly deposited on the GC electrode followed by AuNPs). This superb enhancement is quantified by comparing the relative ratio of the direct vs. the indirect oxidation peaks …
Tunable Gold Nanostructures With Nanocapsules As Template Reaction Vessels, Balasubramanian Ramjee, Srujana Prayakarao, Sangbum Han, Wei Cao
Tunable Gold Nanostructures With Nanocapsules As Template Reaction Vessels, Balasubramanian Ramjee, Srujana Prayakarao, Sangbum Han, Wei Cao
Chemistry & Biochemistry Faculty Publications
Hollow, polymeric, thiol-ene resorcinarene nanocapsules can act as template reaction vessels for the synthesis of gold nanoshells or spherical aggregates of gold nanoparticles depending on the reaction conditions. The spherical nanoparticle aggregates were evaluated as catalysts in the biphasic reduction of 4-nitrophenol.
Kinetic Models Of The Prebiotic Replication Of Dsrna Under Thermal Cycling Conditions, Pauline Schwartz, Dante M. Lepore, Carl Barratt
Kinetic Models Of The Prebiotic Replication Of Dsrna Under Thermal Cycling Conditions, Pauline Schwartz, Dante M. Lepore, Carl Barratt
Chemistry and Chemical Engineering Faculty Publications
We present computational models for the replication of double stranded RNA (dsRNA) or related macromolecules under thermal cycling conditions that would reflect prebiotic (i.e. non-enzymatic) environments. Two models of the replication of dsRNA are represented as multi-step chemical systems. The objective of this investigation was to better understand the kinetic features of such chemical systems. It is shown that thermal cycling in a chemical system is advantageous (relative to a fixed temperature) if there are two competing reactions, one favored at high temperature and one favored at low temperature. For the prebiotic replication of dsRNA, a high temperature favors formation …
Overview Of The 2010 Carbonaceous Aerosols And Radiative Effects Study (Cares), Rahul A. Zaveri, William J. Shaw, Daniel J. Cziczo, Beat Schmid, Richard Ferrare, M. Lizabeth Alexander, Raul Alvarez, W. Patrick Arnott, Dean B. Atkinson, Sunil Baidar, Robert M. Banta, James Barnard, Josef Beranek, Larry K. Berg, Fred Brechtel, W. Alan Brewer, John F. Cahill, Brian Cairns, Christopher D. Cappa, D. Chand, S. China, Jennifer M. Comstock, Manvendra K. Dubey, Robert C. Easter, M. H. Erickson, Jerome Fast, Cody Floerchinger, B. Flowers, Edward C. Fortner, Jeffrey S. Gaffney, Mary K. Gilles, Kyle Gorkowski, William Gustafson, Madhu Gyawali, J. Hair, R. M. Hardesty, Joseph Harworth, Scott C. Herndon, Naruki Hiranuma, Chris Hostetler, John M. Hubbe, John T. Jayne, H. Jeong, B. Tom Jobson, Evgueni Kassianov, Lawrence I. Kleinman, C. Kluzek, W. Berk Knighton, Katheryn R. Kolesar, Chongai Kuang, Alena Kubátová, Andrew O. Langford, Alexander Laskin, N. Laulainen, Richard D. Marchbanks, Claudio Mazzoleni, Fan Mei, Ryan C. Moffet, Dan Nelson, Michael Obland, Hilke Oetjen, Timothy B. Onasch, I. Ortega, Matteo Ottaviani, Mikhail Pekour, Kimberly A. Prather, James Gregory Radney, Raymond R. Rogers, Scott P. Sandberg, Arthur J. Sedlacek, Christoph J. Senff, Gunnar I. Senum, Ari Setyan, John E. Shilling, Manishkumar Shrivastava, C. Song, Stephen R. Springston, R. Subramanian, Kaitlyn Suski, Jason Tomlinson, Rainer M. Volkamer, H. W. Wallace, Jian Wang, A. M. Weickmann, Douglas R. Worsnop, Xiao-Ying Yu, Alla Zelenyuk, Qi Zhang
Overview Of The 2010 Carbonaceous Aerosols And Radiative Effects Study (Cares), Rahul A. Zaveri, William J. Shaw, Daniel J. Cziczo, Beat Schmid, Richard Ferrare, M. Lizabeth Alexander, Raul Alvarez, W. Patrick Arnott, Dean B. Atkinson, Sunil Baidar, Robert M. Banta, James Barnard, Josef Beranek, Larry K. Berg, Fred Brechtel, W. Alan Brewer, John F. Cahill, Brian Cairns, Christopher D. Cappa, D. Chand, S. China, Jennifer M. Comstock, Manvendra K. Dubey, Robert C. Easter, M. H. Erickson, Jerome Fast, Cody Floerchinger, B. Flowers, Edward C. Fortner, Jeffrey S. Gaffney, Mary K. Gilles, Kyle Gorkowski, William Gustafson, Madhu Gyawali, J. Hair, R. M. Hardesty, Joseph Harworth, Scott C. Herndon, Naruki Hiranuma, Chris Hostetler, John M. Hubbe, John T. Jayne, H. Jeong, B. Tom Jobson, Evgueni Kassianov, Lawrence I. Kleinman, C. Kluzek, W. Berk Knighton, Katheryn R. Kolesar, Chongai Kuang, Alena Kubátová, Andrew O. Langford, Alexander Laskin, N. Laulainen, Richard D. Marchbanks, Claudio Mazzoleni, Fan Mei, Ryan C. Moffet, Dan Nelson, Michael Obland, Hilke Oetjen, Timothy B. Onasch, I. Ortega, Matteo Ottaviani, Mikhail Pekour, Kimberly A. Prather, James Gregory Radney, Raymond R. Rogers, Scott P. Sandberg, Arthur J. Sedlacek, Christoph J. Senff, Gunnar I. Senum, Ari Setyan, John E. Shilling, Manishkumar Shrivastava, C. Song, Stephen R. Springston, R. Subramanian, Kaitlyn Suski, Jason Tomlinson, Rainer M. Volkamer, H. W. Wallace, Jian Wang, A. M. Weickmann, Douglas R. Worsnop, Xiao-Ying Yu, Alla Zelenyuk, Qi Zhang
Chemistry Faculty Publications and Presentations
Substantial uncertainties still exist in the scientific understanding of the possible interactions between urban and natural (biogenic) emissions in the production and transformation of atmospheric aerosol and the resulting impact on climate change. The US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) program’s Carbonaceous Aerosol and Radiative Effects Study (CARES) carried out in June 2010 in Central Valley, California, was a comprehensive effort designed to improve this understanding. The primary objective of the field study was to investigate the evolution of secondary organic and black carbon aerosols and their climate-related properties in the Sacramento urban plume as it was …
A Simple Approach For Synthesis, Characterization And Bioactivity Of Bovine Bones To Fabricate The Polyurethane Nanofiber Containing Hydroxyapatite Nanoparticles, Faheem A. Sheikh, M. A. Kanjwal, Javier Macossay-Torres, N. A. M. Barakat, H. Y. Kim
A Simple Approach For Synthesis, Characterization And Bioactivity Of Bovine Bones To Fabricate The Polyurethane Nanofiber Containing Hydroxyapatite Nanoparticles, Faheem A. Sheikh, M. A. Kanjwal, Javier Macossay-Torres, N. A. M. Barakat, H. Y. Kim
Chemistry Faculty Publications and Presentations
In the present study, we had introduced polyurethane (PU) nanofibers that contain hydroxyapatite (HAp) nanoparticles (NPs) as a result of an electrospinning process. A simple method that does not depend on additional foreign chemicals had been employed to synthesize HAp NPs through the calcination of bovine bones. Typically, a colloidal gel consisting of HAp/PU had been electrospun to form nanofibers. In this communication, physiochemical aspects of prepared nanofibers were characterized by FE-SEM, TEM and TEM-EDS, which confirmed that nanofibers were well-oriented and good dispersion of HAp NPs, over the prepared nanofibers. Parameters, affecting the utilization of the prepared nanofibers in …
In Situ And Ex Situ Studies Of Molybdenum Thin Films Deposited By Rf And Dc Magnetron Sputtering As A Back Contact For Cigs Solar Cells, K. P. Aryal, H. Khatri, R. W. Collins, S. Marsillac
In Situ And Ex Situ Studies Of Molybdenum Thin Films Deposited By Rf And Dc Magnetron Sputtering As A Back Contact For Cigs Solar Cells, K. P. Aryal, H. Khatri, R. W. Collins, S. Marsillac
Electrical & Computer Engineering Faculty Publications
Molybdenum thin films were deposited by rf and dc magnetron sputtering and their properties analyzed with regards to their potential application as a back contact for CIGS solar cells. It is shown that both types of films tend to transition from tensile to compressive strain when the deposition pressure increases, while the conductivity and the grain size decreas. The nucleation of the films characterized by in situ and real time spectroscopic ellipsometry shows that both films follow a Volmer-Weber growth, with a higher surface roughness and lower deposition rate for the rf deposited films. The electronic relaxation time was then …
Identification Of The Biogenic Compounds Responsible For Size-Dependent Nanoparticle Growth, Paul M. Winkler, John Ortega, Thomas Karl, Luca Cappellin, Hans R. Friedli, Kelley Barsanti, Peter H. Mcmurry, James N. Smith
Identification Of The Biogenic Compounds Responsible For Size-Dependent Nanoparticle Growth, Paul M. Winkler, John Ortega, Thomas Karl, Luca Cappellin, Hans R. Friedli, Kelley Barsanti, Peter H. Mcmurry, James N. Smith
Civil and Environmental Engineering Faculty Publications and Presentations
The probability that freshly nucleated nanoparticles can survive to become cloud condensation nuclei is highly sensitive to particle growth rates. Much of the growth of newly formed ambient nanoparticles can be attributed to oxidized organic vapors originating from biogenic precursor gases. In this study we investigated the chemical composition of size-selected biogenic nanoparticles in the size range from 10 to 40 nm. Particles were formed in a flow tube reactor by ozonolysis ofα-pinene and analyzed with a Thermal Desorption Chemical Ionization Mass Spectrometer. While we found similar composition in 10 and 20 nm particles, the relative amounts of …