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Full-Text Articles in Engineering
Hydrodeoxygenation Of Anisole In A Novel Externally Agitated Reactor, Brett Pomeroy
Hydrodeoxygenation Of Anisole In A Novel Externally Agitated Reactor, Brett Pomeroy
Electronic Thesis and Dissertation Repository
Bio-oil upgrading via hydrodeoxygenation (HDO) was investigated using anisole, a model compound, in a novel Externally Agitated (EA) reactor which is expected to enhance gas-liquid-solid mixing. Operating conditions were established based on anisole HDO with 10 wt.% Ni on silica, γ-alumina, and δ-alumina while varying temperatures between 160 to 280oC, and reaction times between 30 – 90 minutes. Mild temperatures of 220oC and 45 minutes for reaction time with γ-alumina were selected for subsequent work since γ-alumina demonstrated the highest HDO activity. HDO was then investigated with varying Ni-Cu and Ni loadings. Despite the improved reducibility …
Model For The Evolution Of Pore Structure In A Lignite Particle During Pyrolysis. 2. Influence Of Cross-Linking Reactions, Molten Metaplast, And Molten Ash On Particle Surface Area, He Yang, Thomas H. Fletcher, Sufen Li, Haoquan Hu, Lijun Li
Model For The Evolution Of Pore Structure In A Lignite Particle During Pyrolysis. 2. Influence Of Cross-Linking Reactions, Molten Metaplast, And Molten Ash On Particle Surface Area, He Yang, Thomas H. Fletcher, Sufen Li, Haoquan Hu, Lijun Li
Faculty Publications
A model for the evolution of the pore structure in a lignite particle during pyrolysis was established previously based on the chemical percolation devolatilization (CPD) model, using coal polymer network parameters to calculate the surface area and porosity of the particle. In this paper, to get the accurate surface area of coal particle at high pyrolysis temperature, the previous model was improved by considering the effects of cross-linking reactions, molten Metaplast, and ash. The good agreement of the predicted surface area with experiments at temperature below 1200 K in the previous model is maintained, and model accuracy is improved at …
The Formation Of Polycyclic Aromatic Hydrocarbons From The Pyrolysis Of Model 1-Alkene Fuels, Eva Christine Caspary
The Formation Of Polycyclic Aromatic Hydrocarbons From The Pyrolysis Of Model 1-Alkene Fuels, Eva Christine Caspary
LSU Doctoral Dissertations
To understand the role of 1-alkenes and allylic radicals in the reaction pathways leading to the formation and growth of polycyclic aromatic hydrocarbons (PAH), pyrolysis experiments have been performed with three 1-alkene fuels—propylene (CH₂=CH–CH₃), 1-butene (CH₂=CH–CH₂–CH₃), and 1-pentene (CH₂=CH–CH₂–CH₂–CH₃)—at temperatures of 600 – 1000 °C and a fixed residence time of 0.31 s. The experiments are carried out in an isothermal laminar-flow quartz-tube reactor. Analyses of the pyrolysis products by gas-chromatographic and high-pressure liquid-chromatographic techniques reveal that the three fuels differ in: 1) their conversion behavior, 2) the relative amounts of the major C₂ – C₄ species produced, and 3) …