Engineering Commons^™

Engineering Design Of An Anaerobic-Aerobic System To Treat Chlorophenols, Chih-Ju Jou

Dissertations

The present work was aimed at determining the effect of the main operating parameters on the performance of an anaerobic-aerobic reactor system to degrade toxic chlorinated compounds. In previous work conducted in the Biological Treatment Lab at NJIT it was shown that this system is capable of achieving the complete degradation of chlorophenols. In that system, reductive dehalogenation took place in the first anaerobic reactor, which was followed by a second aerobic reactor in which the degradation products of the first reactor were mineralized. In the present work the role of a number of parameters that can have a significant …

Pyrolysis And Oxidation Of Chloromethanes Experiment And Modeling, Wenpin Ho

Dissertations

An experimental study on pyrolysis and oxidation of CH₂Cl₂ and CH₃Cl in oxygen/hydrogen or oxygen/methane mixtures and argon bath gas was carried out at 1 atmosphere pressure in tubular flow reactors. Degradation of CH₂Cl₂, or CH₃CI, along with the formation and destruction of intermediate and final products was analyzed systematically over 873 to 1273°K, with average residence times of 0.2 to 2.0 seconds.

Thermochemical parameters: enthalpy, entropy, and heat capacities for many chloro-oxy-carbon products and intermediates are calculated using the techniques of group additivity and the THERM computer code. …

Kinetic Study Of Decomposition Of Azo Dyes And Phenol In Advanced Oxidation Processes Reaction Mechanisms, Pathways And Intermediates, Hung-Yee Shu

Dissertations

Advanced Oxidation Processes (AOP) are an emerging technology for treatment of various hazardous organics in wastewater and groundwater. However, the kinetics and mechanisms for AOP have not been well understood. A mechanism including light intensity was studied for the decomposition of azo dyes and phenol in an AOP reactor with a 5,000 watt low pressure mercury lamp. UV light absorption is an important parameter. The effect of pH, hydrogen peroxide dosage, and dye concentration on the decomposition of azo dyes in an H₂O₂/UV reactor were also studied. Reaction pathways and intermediates of phenol oxidation by different …

Competition Between Two Microbial Populations In A Sequencing Fed-Batch Reactor And Its Implications For Waste Treatment Applications, Sitaram Dikshitulu

Dissertations

Pure and simple competition between two microbial populations in a sequencing fed-batch reactor (SFBR) was studied both at the theoretical and experimental level. Competition occurred for a single chemical pollutant which could serve as the sole carbon and energy source for both competitors. A mathematical model describing the process under inhibitory kinetics (as is usually the case with hazardous and toxic substances) was derived and theoretically analyzed. The model predicts that the dynamics of a SFBR, and the kinetics of biodegradation, result in a complex set of operating regimes in which neither species, only one species, or both species survive …

Analysis Of The Optimum Extraction System Design For The Separation And Purification Of Rare Earths, Kenneth Yeon-Kang Chan

Dissertations

A mathematical model for the liquid-liquid equilibrium of the lanthanide and yttrium oxides in the nitric acid - water - tributyl phosphate (HNO₃-H₂O-TBP) two-phase system has been developed. This model is based on the interrelationships of chemical reactions, phase equilibrium, and material balance. The chemical reactions were modelled using experimentally derived empirical equations for components involved. The distribution coefficients of 16 rare earths which were experimentally determined. by UK Harwell Laboratory were used to evaluate the parameters of this equilibrium model. Once model parameters are determined, material balance for all species in the HNO₃-H …

Investigation Of Reactor Design Parameters Towards Optimizing Biodegradation Of Chlorophenols By Phanerochaete Chrysosporium, Nirupam Pal

Dissertations

The biodegradation of 2,4,6-trichlorophenol (246-TCP) and 2,4,5-trichiorophenol (245-TCP) by Phanerochaete chrysosporium was studied in batch and in continuous systems. Contrary to most of the previous reports from the literature, this study shows that degradation of both TCPs can occur in the absence of any measurable ligninase activity. The microorganism did not retain its degradative ability for more than about two weeks

In order to better understand the degradation process, the individual contributions of both the biomass and the extracellular proteins were studied separately. The results show that neither the biomass nor the extracellular proteins alone can completely degrade 246-TCP, but …