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Effect Of Platinum Particle Size On The Sulfur Deactivation Of Hydrogenation, Lyndsey Michelle Baldyga

USF Tampa Graduate Theses and Dissertations

A large concern of the fossil fuel and renewable energy industries is the sulfur poisoning of catalysts. In the case of noble metals, such as platinum, it is seen that there is a size trend associated with the level of activity in the presence of sulfur. Smaller nanoparticles could be more tolerant due to sulfur surface vacancies. On the other hand, larger particles could have less deactivation because the sulfur is more attracted to the smaller particles and the sulfur molecules bind stronger to these smaller particles.

The size effect of sulfur deactivation was investigated by testing four sizes of …