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Dispersion Of Spherical Silicon Dioxide Nanoparticles In Poly(Styrene-B-Methyl Methacrylate) Diblock Copolymer Domains, Joshua C. Obinwa
Dispersion Of Spherical Silicon Dioxide Nanoparticles In Poly(Styrene-B-Methyl Methacrylate) Diblock Copolymer Domains, Joshua C. Obinwa
Master's Theses
Polymer-nanoparticle hybrids are nanomaterials in which the unique properties of the nanosized structures can be precisely tuned by choosing an appropriate combination of the polymer and the nanoparticle. However, nanoparticle dispersion in a polymer is challenging due to the aggregation tendency of nanoparticles. To improve nanoparticle dispersion and control the location of nanoparticles in block copolymer assemblies, the nanoparticle surface is modified with surface ligands compatible with the block copolymer. In this thesis, hydroxyl-terminated poly(styrene-b-methyl methacrylate) (PS-b-PMMA) was utilized to functionalize the nanoparticle surface, covalently anchoring the hydroxylterminated end of the polymer onto the silicon dioxide nanoparticles. The silicon dioxide …
Molecular Weight And Heating Value Of Lignin Extracted Using Deep Eutectic Solvent., Ekugbere Owen Owhe
Molecular Weight And Heating Value Of Lignin Extracted Using Deep Eutectic Solvent., Ekugbere Owen Owhe
Master's Theses
The molecular weight of lignin helps us to determine how lignin can be applied accurately in industry. The molecular weight can predict the behavior of lignin, and how it will function when combined with other materials. This thesis discusses how the molecular weight of lignin can be found with gel permeation chromatography (GPC) after acetylation with acetic anhydride and pyridine. Different lignins gave different number average molecular weight and weight average molecular weight values, which were likely due to the biomass source, type of extraction and solubility in the solvent of choice. How the structure of lignin changed after derivatization …