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Catalysis and Reaction Engineering

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Full-Text Articles in Engineering

Hydrogen Generation From Eosin Y-Sensitized Pt/Zno Under Solar Light Irradiation, Tianfang Tian May 2018

Hydrogen Generation From Eosin Y-Sensitized Pt/Zno Under Solar Light Irradiation, Tianfang Tian

Electronic Thesis and Dissertation Repository

Hydrogen is a promising alternative energy carrier. Generating hydrogen via photocatalysts is clean and energy saving comparing to the current technology for hydrogen generation. ZnO has been proved to have photocatalytic activities for wastewater treatment by multiple studies. However, there are not enough studies to investigate its potential to generate hydrogen as the photocatalyst under light irradiation. Therefore, we will investigate the photocatalytic ability of Pt/ZnO to generate hydrogen. Triethanolamine (TEOA) was used as sacrificial reagent while Eosin Y was used as sensitizer. Pt/ZnO was characterized and tested for its activity for hydrogen generation in different conditions, which are platinum …


Enhanced Solar Photocatalytic Hydrogen Generation And Water Treatment Using Hetero-Structure Photocatalysts, Ghodsieh Malekshoar Feb 2016

Enhanced Solar Photocatalytic Hydrogen Generation And Water Treatment Using Hetero-Structure Photocatalysts, Ghodsieh Malekshoar

Electronic Thesis and Dissertation Repository

Among different approaches to overcome current environmental concerns, heterogeneous photocatalysis is recognized as a promising one. While there are various applications of photocatalysis including water splitting and water treatment, the overall efficiency of this process is still fairly low due to the two dominant drawbacks of current semiconductors, namely wide band gap and fast recombination of photo-generated charges, which restrict the photocatalytic reactions. Designing a hybrid photocatalyst composed of semiconductor hetero-junctions is a viable approach to address these challenges.

The objective of this research project is developing efficient photocatalysts via simple and practical synthesis methods in order to enhance the …


A Comprehensive Study Of Cd(Ii) Removal From Aqueous Solution Via Adsorption And Solar Photocatalysis, Samindika Athapaththu Dec 2013

A Comprehensive Study Of Cd(Ii) Removal From Aqueous Solution Via Adsorption And Solar Photocatalysis, Samindika Athapaththu

Electronic Thesis and Dissertation Repository

As the increase in industrial technology continue to progress, it results in the increase in heavy metal pollution, creating harmful effects on humans, plants, and animals. Since toxic metals do not degrade easily, they accumulate over time, posing greater danger to living organisms. Removal of these heavy metals is therefore, of great importance. Though many research studies successfully utilized UV photocatalysis with TiO2 catalyst for the removal of Cd2+, none have performed the photoreduction of Cd2+ under visible light using eosin-y dye-sensitized TiO2. The objective of the present research is to study the photocatalytic …


Solar And Visible Light Driven Photocatalysis For Sacrificial Hydrogen Generation And Water Detoxification With Chemically Modified Ti02, Pankaj Chowdhury Aug 2012

Solar And Visible Light Driven Photocatalysis For Sacrificial Hydrogen Generation And Water Detoxification With Chemically Modified Ti02, Pankaj Chowdhury

Electronic Thesis and Dissertation Repository

Photocatalysis is a recognized approach where light energy is employed to excite the semiconductor material producing electron/hole pair which eventually involves in the detoxification of pollutants and/or water splitting producing hydrogen. Existing photocatalysts suffer from poor activity or no activity in visible light irradiation which restricts them from solar light utilization. This work is focused on two key applications of photocatalysis (i) sacrificial hydrogen generation, and (ii) phenol degradation in visible and/or solar light. Platinum was loaded on TiO2 photocatalyst by solar photo-deposition method. Eosin Y dye was used as a sensitizer for sensitization of platinum loaded TiO2 …