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Full-Text Articles in Engineering

Production Of Bio-Oil With Different Oxygen Content And Characterization Of Catalytic Upgrading To Transportation Fuel, Mubarak Mohammed Khlewee Dec 2017

Production Of Bio-Oil With Different Oxygen Content And Characterization Of Catalytic Upgrading To Transportation Fuel, Mubarak Mohammed Khlewee

Electronic Theses and Dissertations

The world’s increasing population requires an increase in transportation fuel production. The lack of production of transportation fuels due to the shortage of fossil fuel resources combined with concerns about global emissions of carbon dioxide from fossil fuel combustion are the two major issues that have driven researchers to actively pursue alternative sources for oil production. Biomass is being considered as an alternative feedstock to produce fuel and chemicals due to its abundance and renewability. It has many features that make it suitable as a source of transportation fuel production. However, the bio-oil produced by the fast pyrolysis process has …


Characterization Of Catalysts For Hydrodeoxygenation Of Bio-Oils Using Phenol As A Model Compound, Abdulazeez Mohammed Khlewee Aug 2017

Characterization Of Catalysts For Hydrodeoxygenation Of Bio-Oils Using Phenol As A Model Compound, Abdulazeez Mohammed Khlewee

Electronic Theses and Dissertations

Due to the environmental considerations, depletion of fossil fuel reserves and fluctuating non-renewable fuel price, converting non-edible lignocellulosic biomass into renewable energy resources has gained significant importance. Phenol has been chosen as a model compound for catalytic screening because it is abundant in bio-oil composition and shows a high resistance to oxygen removal during hydrodeoxygenation (HDO) reactions. HDO of phenol produces chemicals that can be used as transportation fuels (Aromatics) or fuel additives. Theoretically, HDO of phenol has two distinct reduction pathways: direct deoxygenation (DDO) and hydrogenation (HYD). The previous results published by our group showed a precedent activity and …


Creating Renewable Tunable Polymers From Hydroxymethylfurfural, Meredith C. Allen Aug 2017

Creating Renewable Tunable Polymers From Hydroxymethylfurfural, Meredith C. Allen

Electronic Theses and Dissertations

The research here deals with the conversion of 5-hydroxymethylfurfural (HMF) into a tunable polymer. HMF is a known derivative that can be acquired from biomass via hydrolysis of cellulose followed by isomerization and finally selective dehydration. The process considered here is being developed to create tunable polymers from HMF and involves several different steps, three of which are covered here. The first step, an etherification, is the reaction of HMF with an alcohol. This step is significant because in this step the R-group from the alcohol is added to HMF and the branching portion formed is carried over to the …