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Science and Mathematics Education

Doctoral Dissertations

Theses/Dissertations

2013

Organotrifluoroborates

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Microwave-Enhanced Chemistry Of Organotrifluoroborates, Vitali Ilia Coltuclu Aug 2013

Microwave-Enhanced Chemistry Of Organotrifluoroborates, Vitali Ilia Coltuclu

Doctoral Dissertations

This dissertation contains a summary of the research efforts focused on the utiliza- tion of microwave technology in organoborate chemistry. More specifically, the cen- tral topic is focused on the chemistry of potassium organotrifluoroborate compounds that have recently attracted a lot of attention as useful reagents for diverse transfor- mations in organic synthesis such as, cross-coupling, homocoupling, as well as 1,2- and 1,4-addition reactions. The use of microwave radiation in these and other reac- tions is particularly appealing for improving and facilitating synthetic procedures by reducing reaction times, minimizing by-product formation, and increasing reaction yields. In this dissertation, we combine …