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Insights Into Factors Influencing Radical Coupling Chemistry Of Monolignols During Lignification And Induced Changes In Plant Secondary Metabolism, Rachel Poornima Sutherland

Theses and Dissertations--Chemistry

Lignin is a complex aromatic biopolymer and an important constituent in plant cell walls. The process of lignin biosynthesis, known as lignification, is poorly understood and challenging to study but has important implications in a variety of fields including sustainable energy, bioengineering, and materials science and is therefore of interest to pursue. In the final stage of lignification, H-, G-, and S-monolignols are oxidized by laccase and peroxidase enzymes to generate radical species that couple to form dimers and further oligomeric species to ultimately produce the lignin polymer. Biomimetic lignin model systems utilize in vitro oxidative coupling reactions as an …

Development And Prototyping Of A Modular Quadruped Towards Testing Standardization For Legged Robot Stability, Michael Conner Larsen

Graduate Research Theses & Dissertations

Legged robots are well-suited for navigating uneven and unmapped terrain, making them valuable in various robotics applications. Maintaining balance and stability in such environments relies on a combination of sensors, control strategies, and mechanical design. However, selecting the most effective sensing and control method for a given use case remains challenging. Previous studies have explored various approaches, integrating combinations of joint angle measurement, inertial measurement units (IMUs), torque-based control, leg force measurement, image processing, and machine learning, paired with numerous controller designs, which can contribute to stability. However, direct comparisons of these methods are often limited by the need for …

Academic Entitlement: Why Gen Z Students Believe They Deserve Good Grades For Academic Success Regardless Of Their Performance, Clinton Stephen Mawusi

Graduate Research Theses & Dissertations

This thesis explores how Generation Z college students at Northern Illinois University (NIU) understand, negotiate, and express academic expectations and experiences, particularly concerning their sense of academic entitlement. Drawing from semi-structured interviews with 20 full-time undergraduate students across diverse academic disciplines, this qualitative study employed Braun and Clarke’s (2006) six-phase thematic analysis approach to identify patterns in students’ perspectives on grades, effort, and faculty relationships. The findings reveal detailed tensions between students’ desire for recognition of effort and their awareness of institutional standards of academic merit. Participants shared insights into classroom interactions, grading policies, use of campus resources, and the …

Thai Pre-Service And Early-Career Teachers' Professional Identity Formation, Duangkamon Winitkun

Graduate Research Theses & Dissertations

Beginning teachers, including pre-service (PSTs) and early-career teachers (ECTs), face various types of challenges such as classroom management, instructional planning, building relationships with school stakeholders, adjusting to school culture, and limited resources (Kozikoglu, 2017). Many studies focus on these challenges as technical issues, neglecting the role of teacher identity in how educators experience and address these difficulties (e.g., Burden, 2020; Doyle, 1990; Hoy & Weinstein, 2013). Moreover, most teacher identity studies are predominantly conducted in Western contexts where sociocultural values and systemic constraints shape teachers’ professional roles differently from those in Eastern contexts. This three-manuscript dissertation investigates the identity formation …

Cut It Out And Cut Us In: The Evolution Of Chicago’S Militant African-American Youth Activism During The 1950s And 1960s, Sultaan Edward Byrd

Graduate Research Theses & Dissertations

This dissertation tracks the development of a militant core in Chicago’s African American youth community following the lynching of one of the city’s native sons, Emmett Till, in 1955, through the rise of the fight against housing and school segregation and culminating in demands for racial equity in the building trades in 1969. This dissertation will trace how events in Mississippi helped plant the seeds of resistance and shape the trajectory of black activism in Chicago, revealing a powerful link between Southern racial violence and Northern political awakening. The coalitions that emerged in response to Till’s murder laid the foundation …

Characterization Of A Large-Scale Electrohydrodynamic Vortex Confinement Flow For Particle Agglomeration, Sanjay Dangi

Graduate Research Theses & Dissertations

With industrialization and the increasing use of microplastics and nanoparticle-based products, the concentration of fine particulate matter (PM2.5) in the biosphere has increased due to the disposal of manufacturing waste and expired parts. If inhaled, PM2.5 can have detrimental health effects, as these particles can travel deep into the lungs and even penetrate blood vessels. Conventional fabric filters used for indoor air quality control have drawbacks, including the need for periodic filter replacement and a high-pressure drop across the filter over time, which leads to increased power consumption. In power plants, electrostatic precipitators (ESPs) are primarily used to collect fly …

Piv Visualization Of A Sinusoidal Ehd Confinement Flow Induced By Variation In Ion Density For Electrostatic Particle Agglomeration, Md Eyasin Hossain

Graduate Research Theses & Dissertations

Long-term exposure to PM2.5, which is responsible for four million cardiovascular-related deaths worldwide, is a major concern as people spend 90% of their time indoors. Fabric filters have been commonly utilized for particle pollution control in indoor settings. However, the maintenance cost of fabric filters is relatively high, as particle accumulation on filters can lead to higher pressure drops (45 ∼ 300 Pa) and energy consumption, as well as the growth of biological organisms and the generation of airborne pathogens. An electrostatic precipitator (ESP) is filterless and widely used in the electric power industry for collecting coal fly ash. ESPs …

Md Simulation Of Femtosecond Laser-Controlled Melting Of Multiple Core-Shell Nanoparticle Systems, Shivansh Patel

Graduate Research Theses & Dissertations

This thesis presents a molecular dynamics (MD) simulation study of femtosecond laser-induced melting and heat transfer in multiple Cu–Al core–shell nanoparticle systems. The research builds upon previous single-particle studies and extends the investigation to multiple interacting nanoparticles to better understand nanoscale thermal transport and melting behavior under ultrafast laser irradiation. Understanding this process is essential for improving laser-based additive manufacturing and sintering of metal matrix nanocomposites (MMNCs), where precise control of heat flow and particle bonding determines the final material quality. The simulations were performed using the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) integrated with the Modified Two-Temperature Model (MTTM). …

Simulated Efficiency Of A Modified Bmw I3 Traction Motor Operating As An Isolated Dc-Dc Converter, Shayne Taylor

Graduate Research Theses & Dissertations

Battery electric vehicles are currently fighting to have any advantage over internal combustion engine powered vehicles to reduce global transportation greenhouse gas emissions. Electric motors are typically deemed as the largest source of loss in many vehicles but have recently become more efficient on average than the AC-DC converter used to charge the vehicle. This paper investigates the potential for a dual three phase electric traction motor based on a BMW i3 electric vehicle traction motor to take the place of an isolated DC-DC converter, an important part of the AC-DC converter. This electric machine in simulations produced a similar …

Towards Automating The Study And Discovery Of Electroactive Π-Conjugated Molecules, Rebekah Ann Duke-Crockett

Theses and Dissertations--Chemistry

Chemistry is entering a new paradigm of automation and data-driven discovery. Automated discovery is grounded in well-curated “big data.” As generative and predictive models fueled by simulation data see growing success, emerging robotic automation enables the generation of unprecedented volumes of experimental data. Automation-powered, data-driven approaches hold tremendous potential for groundbreaking insights and innovations, particularly in the study and discovery of electroactive π-conjugated molecules. Realizing this potential, however, requires democratizing chemical data and the automation needed to generate and use it. There is a need to expand access to the tools for findable, accessible, interoperable, and reusable (FAIR) data management …

Machine Learning Models For Molecular-Based Functional Organic Materials, Moses Ogbaje

Theses and Dissertations--Chemistry

Organic semiconductors (OSC) are of interest for a wide range of flexible optoelectronics applications, including transistors, solar cells, and sensors, to name a few. Despite their promise, the design and optimization of OSC pose significant challenges due to the complexity of the structures of the molecular building blocks, varied packing configurations of these building blocks in the solid state, which impacts the optical and electronic response, and sensitivity of the solid-state packing to material processing conditions. Accurately predicting the solid-state properties of OSC traditionally requires high-level quantum mechanical methods. These methods, however, can be computationally demanding, particularly for large molecules …

For Her Horror: Sociopsychological Gratifications Obtained By Fem Fans Of The Slasher, Brooke Eaglesong Wilson

Masters Theses

Those who side with the unjustified killer in slasher films are doing so to fulfill sociopsychological needs that are not being met in social reality. There were three main findings found in this study. First, participants sided with the unjustified killer in slasher films to gratify needs that were not being fulfilled in their careers such as the need to perform without having to consult mentors, not unlike how the unjustified killer murders victims without discussing with others. Second, participants sided with the unjustified killer in slasher films to gratify needs in their romantic relationships such as the need to …

The Impacts Of International Students’ Membership In Co-National Student Organizations, Krofaa Otuo-Srebour

Masters Theses

This study explores the impact of international students' membership in co-national student organizations on their adjustment to U.S. higher education institutions. Despite significant literature on the psychological predictors of adjustment, there is a gap in examining the social support gained through non-academic student organizations composed of individuals from the same country or region. Using a qualitative phenomenological approach, the study investigated challenges international students face in the U.S. and how culturally specific groups impact their adjustment. The findings underscore the importance of co-national student organizations in supporting international students’ adjustment processes and suggest practical implications for university administrators to enhance …

Sustainable Hemp Industrial Panels (Ship) And Its Industrial Possibilities For The Replacement Of Oriented Strand Board (Osb), Anthony Ollins

Masters Theses

This study explores the feasibility of using industrial hemp fiber to create composite panels—termed Sustainable Hemp Industrial Panels (SHIP) as a potential competitor for oriented strand board (OSB), a commonly used structural wood product. Given hemp's historical and environmental advantages, including rapid growth, carbon sequestration capacity, and material strength, this research investigates its performance when combined with Urea-Formaldehyde (UF) resin, and in a hybrid form with Southern Yellow Pine (SYP). Two hemp-based composites were produced and tested: one with hemp and UF, and another with hemp and SYP. Using a custom-built hydraulic press, composite panels were fabricated and subjected to …

Effects Of Perceived Procedural Justice On The Relationship Between Visa Application Outcome And Psychological Distress: Evidence From Ghanaians And Nigerians Applying For U.S. Student Visas, Harriet Swanzy-Baffoe

Masters Theses

Visa interviews are not just bureaucratic processes; they can have significant psychological effects on applicants. This study examined the impact of U.S. student visa outcomes on psychological distress among West African applicants, with particular attention to perceptions of procedural justice during the interview process. The study surveyed 203 Ghanaian and Nigerian individuals who had previously applied for a U.S. student visa. Psychological distress was measured using the Impact of Event Scale-Revised (IES-R), and perceptions of fairness were measured with a custom-developed Procedural Justice Scale. Independent samples t-tests showed that denied applicants reported significantly higher distress, although elevated symptoms were also …

Optimization Of Transformation And Regeneration In The Sunflower (Helianthus Annuus), Sara M. Kilar

Masters Theses

In addition to their value as prized ornamentals, sunflowers are important crop species due to the nutritional value and high oil content of the seeds. Sunflower oil is a significant contributor to global seed oil production, which can be used as a food additive and cooking agent as well as a raw material for biodiesel production. While traditional breeding efforts have led to the development of many unique cultivars, genetically modified variations have proven more difficult due to the recalcitrance of sunflower plants to genetic transformation. As a result, facile and efficient transformation methods for sunflowers have the potential to …

Influence Of Thermophilic Biofilms On Proliferation Of Opportunistic Pathogens In Domestic Water Systems, Olajumoke Akinbami

Masters Theses

Domestic hot-water systems quietly grow biofilms under elevated temperatures that can serve as shelter to Opportunistic Premise Plumbing Pathogens. Although focus has been placed on microbes in domestic systems, there has been no clear conclusion on the mechanism of survival and persistence of opportunistic pathogens despite various disinfection strategies. In this study, we determined the distinction between showerhead and drip-flow biofilms at the whole-community level and analyzed the coexistence of thermotolerant organisms with opportunistic genera, such as Legionella. We sampled eight showerheads and simulated four biofilm samples in the laboratory using the drip-flow biofilm reactor.

We observed a strong …

Targeted Mitigation Strategies To Reduce Secondary Emissions In Co2 Capture Systems, Keemia Abad

Theses and Dissertations--Chemistry

Global CO₂ emissions from industrial, power generation and transportation sources has led to the call for increased implementation of carbon capture strategies. The most developed of these is point source carbon capture, which refers to the process of capturing CO₂ directly from large (point) source emitters, before the CO₂ is released into the atmosphere. The challenge becomes separating CO₂ from the other components of the emitted gas, mainly nitrogen. These CO₂ capture processes typically involve the use of aqueous solutions of amines to absorb (capture) CO₂ from the gas stream, where the CO₂ and the …

Exploring The Relationships Between Molecular Structure And Crystal Packing In Small-Molecule Organic Semiconductor Materials, Dean A. Windemuller

Theses and Dissertations--Chemistry

Organic semiconductor materials (OSCs) are rapidly becoming a vital part of the technological landscape. They possess unique properties that make them attractive for the electronics industry. Relatively low-temperature and low-cost processing are a large part of the promise of OSCs. Perhaps more importantly, organic materials can be modified in a relatively straightforward manner, presenting an opportunity for them to be tuned and adapted to a variety of purposes and applications. Polycyclic aromatic hydrocarbons (PAHs) form a large group within the field of OSC research. Some of the most promising high-performance materials in this category to-date are acenes and heteroacenes. This …

Effects Of A-Site Cation Structure And B-Site Metal On Optical And Electronic Properties Of 2d Ruddlesden-Popper Phase Tin-Based Hybrid Perovskites, Henry Pruett

Theses and Dissertations--Chemistry

Organic metal halide perovskites (HPs) are attractive materials for a variety of electronic applications due to their low cost, tunable band gaps, excellent charge transport properties, and high photoluminescence efficiency. As such, HPs are being investigated for use in solar cells, photodetectors, X-ray detectors, light emitting diodes, field effect transistors, lasers, resistive random-access memory, etc. Currently the most popular metal used in HPs is lead, but the use of lead comes with the potential for heavy metal exposure. Tin-based perovskites offer a less hazardous alternative, but their optoelectronic properties lag behind those of lead and less work has been done …

Limitations Of Scientific Articles And Navigated Future Directions With Llm And Rag, Ibrahim Al Azher

Graduate Research Theses & Dissertations

Traditional Topic Modeling approaches, as well as zero-shot, few-shot, and fine-tuned Large Language Models (LLMs), have struggled to generate topics alongside relevant text from diverse sources, particularly sections such as Limitations. This thesis investigates automated methods for analyzing and synthesizing key sections of scientific articles using LLMs, exploring multiple dimensions of scientific text analysis.

First, LimTopic is introduced as a method for extracting and modeling the limitations sections of research papers. By integrating LLM-based topic generation with BERTopic, the approach generates descriptive titles and concise summaries that highlight the boundaries and shortcomings of studies, ultimately guiding future research directions.

Second, …

Spatial Temporal Patterns Of Us Landslides In Recent Decades And Climate Change, Karissa Duff

Graduate Research Theses & Dissertations

The frequency and intensity of extreme rainfall events are on the rise in recent decades around the world due to climate change and the trend is projected to continue. Intensified rainfall is a well-known trigger for landslide hazards. The impact of climate change on landslide hazards is a research question of practical importance, as landslides can cause billions of dollars in damage and significant loss of human lives annually. However, previous studies have often focused on specific events with limited spatial and temporal scales. Here we report our preliminary results of leveraging modern geospatial statistical tools in GIS using both …

X-Ray Standing-Wave Fluorescence Study Of The Interaction Of An Anti-Microbial Peptide With A Supported Phospholipid Bilayer, Gobind Basnet

Graduate Research Theses & Dissertations

To understand the mechanism by which anti-microbial peptide penetrates biological membranes,the study uses artificial supported lipid bilayers (SLBs) deposited on solid substrates. These bilayers were prepared from a lipid mixture of 1,2-dimyristoyl-sn-glycero-3- phosphocholine (DMPC)and 1,2-dimyristoyl-sn-glycero-3-phospho-(1’-rac-glycerol (DMPG) in a 10:1 molar ratio and were incubated both with and without indolicidin. Additionally, bilayers were studied after incubation with a labeled form of indolicidin, which involved attaching a 1.8 nm diameter gold nanoparticle to the peptide’s terminal arginine group.

X-ray reflectivity (XRR) was employed to identify structural differences between SLBsincubated with indolicidin and those without it. The introduction of gold labeling facilitated the …

Design, Synthesis, And Evaluation Of Di-Peptide Probes For Stoichiometric Quantitative Analysis Of Antibodies, Taylor Gladson

Graduate Research Theses & Dissertations

Quantitative information on biomarkers is a decisive factor in a wide range of situations concerning individual and public well-being. Under certain circumstances, the availability of accurate quantitative information can even become a matter of life or death. Therefore, the ability to make quantitative measurements in point-of-care (POC), do-it-yourself (DIY), and limited resource settings (LRS) is crucial for diagnostics, disease management, food safety, biomedical research, forensics, and other areas.In the work, we develop a POC/DIY/LRS-compatible platform for unambiguous (yes/no type) quantitative analysis of antibodies. The heart of the approach is negative cooperativity-based target – probe binding. The binding modality yields a …

Meaningful Legislative Conflict: The Role Of Party Competition, Nader Omar Alghoul

Graduate Research Theses & Dissertations

This dissertation explores the influence of legislative conflict, defined by party polarization, relational animosities, and majority size, on legislative productivity in the U.S. Congress. While prior studies have focused on party polarization, divided government, and relational conflict, this research broadens the analysis by incorporating majority size as a key determinant of legislative accomplishment. The research will affirm that moderate polarization sharpens policy debates and enhances productivity, while extreme polarization, particularly when combined with significant relational conflict, results in legislative gridlock. Importantly, this research adds majority size to the amalgam of conflict and uncovers a curvilinear pattern: modest majorities improve legislative …

Investigating The Social Effects Of Doomscrolling, Sean Daniel Hronek

Graduate Research Theses & Dissertations

This study investigates the social effects of doomscrolling, a behavior characterized by the compulsive consumption of negative content on social media, which has become increasingly prevalent. The research explores how doomscrolling may contribute to adverse social outcomes. Three hypotheses are proposed: (H1) doomscrolling correlates with increased acceptance of authoritarian behaviors, (H2) doomscrolling correlates with decreased trust in news media, and (H3) doomscrolling correlates with reduced interpersonal trust. A mixed-methods approach was employed, combining quantitative surveys and qualitative interviews with 108 (n=108) participants. Results indicate modest correlations between doomscrolling and the hypothesized social effects. Qualitative interviews further revealed that users often …

The Roots Of Empire And Industry: The Transnational History Of The Soviet Rubber Industry, Alexander Hinnov Craver

Graduate Research Theses & Dissertations

Global rubber shortages and market instability in the early 20th century drove the United States, Soviet Union, and Nazi Germany to collaborate in an overwhelming drive to secure domestically producible sources of rubber, either from plants that could grow outside the tropics, or from synthetic rubber processes. The Soviet Union was an indispensable part of this converging, transnational “quest for rubber.” Russian scientists created the first factories to produce synthetic rubber, and Russian agronomists had discovered a dandelion in Central Asia that yielded latex suitable for manufacture. Consequently, both discoveries were disseminated across the world. Sometimes they were shared: the …

Gaming The System: A Study Of The Effect Of Simulation-Gaming On The Performance Of First-Year Writing College Students, Jen L. Justice

Graduate Research Theses & Dissertations

This dissertation explores the impact of digital simulation-gaming on the writing performance of first-year college students enrolled in Northern Illinois University’s First-Year Composition (FYC) program. Using the video game Minecraft as a development platform, the study engaged students in a semester-long simulation where they acted as employees of the NIU admissions office tasked with creating a digital campus map to attract and support students. The project aimed to investigate whether simulation-based learning could enhance students' motivation, foster real-world connections in their writing, and improve academic performance compared to traditional composition courses.

The study involved 115 students across five sections of …

Leveraging Synthetic Data For Efficient Training Of Ai Models For Real-World Object Detection, Reinaldo A. Moraga

Graduate Research Theses & Dissertations

Modern computer vision (CV) systems largely depend on real-world data for training, which is costly in terms of time, materials, and resources. As industries push toward automation and Artificial Intelligence (AI) -driven solutions, the need for enabling more efficient model training is growing. The primary aim of this work is to explore a framework tailored for industrial applications that uses synthetic images generated from 3D models to train a CV model capable of real-world object detection. This approach seeks to reduce the time, cost, and resources typically required for training AI models with real-world data. This work presents a method …

Norm Conflicts In International Criminal Tribunals, Megan Schaefer

Graduate Research Theses & Dissertations

What explains an increase in sexual violence prosecutions brought before international criminal tribunals? I investigate this question by examining three cases: The International Military Tribunal of Nuremberg, the International Criminal Tribunal of the Former Yugoslavia, and the Extraordinary Chambers in the Courts of Cambodia. There are international norms present within these cases. One of these norms treats sexual violence as a natural consequence of war, while the other norm acknowledges that this violent behavior is wrong and demands accountability. I identify a prioritization of the second of these norms and argue this has impacted the global response to wartime sexual …