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Expanding Tailorable Nanomaterial Synthesis With Persistent Micelle Templates, Eric R. Williams Apr 2023

Expanding Tailorable Nanomaterial Synthesis With Persistent Micelle Templates, Eric R. Williams

Theses and Dissertations

The control of block polymer micelle dimensions while in solution is critical for a range of emerging applications in diverse fields from drug delivery and nanoreactors to use as sacrificial templates for porous nanomaterials. When under kinetic control, micelles will maintain a constant average size and thus aggregation number (Nagg) through the suppression of chain exchange mechanisms. Such kinetic control effectively enables the decoupling of micelle dimensions from solution conditions. In other words, kinetically trapped micelles can resist reorganizations brough about by e.g., the addition of metal nanoparticles. However, such micelles are traditionally governed by a fickle �� …


Rhetorical New Materialism, Queers, And Cringe, Katherine Anne Schell Apr 2023

Rhetorical New Materialism, Queers, And Cringe, Katherine Anne Schell

Theses and Dissertations

Cringe, the negative reflexive reaction we experience when we witness something embarrassing or awkward, has a bad reputation in the queer community. In online and physical queer spaces, there is a pervading belief that “cringe culture” must be antithetical to queerness, that no queer community could possibly achieve liberation until it has eradicated the threat of cringe. This thesis revises that cringe vs. queer positioning by reimagining cringe as its own rhythm of queerness and examining the productive aspects of cringe through engagement with thinkers like Karen Barad and Eve Kosofsky Sedgwick. The thesis, formatted as a response to a …


An Examination Of Celebrity Product Involvement And Endorsement Effectiveness, Eric Nichols Apr 2023

An Examination Of Celebrity Product Involvement And Endorsement Effectiveness, Eric Nichols

Theses and Dissertations

The purpose of this study was to investigate celebrity product involvement and its relationship with endorsement effectiveness. Due to the increased leverage in creating their own brands, celebrity athletes are increasingly engaging in entrepreneurial endeavors such as collaborations on product development, an investment relationship, and outright ownership and creation of a brand or product. This paper also studied the extent which parasocial interactions and athlete identification may moderate endorsement effectiveness in the form of brand attitudes as well as what role product congruence may play.

Participants were recruited to complete an online survey that exposed them to manipulations of narrative …


Advancing The Engineering Workforce By Enhancing Diversity, Equity, And Inclusion In The Engineering Classroom, Phoneia Hughes Myers Apr 2023

Advancing The Engineering Workforce By Enhancing Diversity, Equity, And Inclusion In The Engineering Classroom, Phoneia Hughes Myers

Theses and Dissertations

Society’s dependence on engineered products is steadily increasing. This dependence requires the engineering workforce to continually innovate and design new advancements. In pursuit of this, engineering employers are implementing diversity, equity, and inclusion initiatives to attract prime candidates and retain employees. For employers to achieve the goals of their initiatives, engineering colleges and universities must produce a diverse pool of graduates. The purpose of this thesis report is to investigate how the diversity, equity, and inclusion concept can be implemented into engineering education to assist with producing diverse graduating classes. A universal methodology is proposed to provide a roadmap on …


Planting Rhizomes: Roots And Rhizomes In Maryse Condé’S Traversée De La Mangrove And Calixthe Beyala’S Le Petit Prince De Belleville, Rume Kpadamrophe Apr 2023

Planting Rhizomes: Roots And Rhizomes In Maryse Condé’S Traversée De La Mangrove And Calixthe Beyala’S Le Petit Prince De Belleville, Rume Kpadamrophe

Theses and Dissertations

For centuries, migration has played a crucial role in the development of human civilization, with the transplantation of cultures from one region to another shaping identities worldwide. The African diaspora, beginning with the Atlantic Slave Trade, saw the forced transportation of around 12 million Africans across the ocean, resulting in the creation of creole identities in the Antilles. Literature has long reflected the experiences of migrants. In Maryse Condé's Traversée de la Mangrove and Calixthe Beyala's Le Petit Prince de Belleville, the complexity of Antillean and Afro-French identities is explored. This thesis delves into how Condé's work highlights the …


The Impact Of Interactivity On Information Processing For Virtual Tourist Destinations, Hongxiao Yu Apr 2023

The Impact Of Interactivity On Information Processing For Virtual Tourist Destinations, Hongxiao Yu

Theses and Dissertations

The rapid development of virtual reality (VR) platforms offers great potential for the widespread consumption of VR tourism offerings. This creation of tourism experiences through VR significantly impacts tourism marketing strategies. Nevertheless, unprecedented development presents research challenges to better understand the effectiveness of VR interactivity in providing dynamic virtual experiences and shaping consumers’ intention to visit actual tourism destinations. Moreover, destination marketing managers face challenges in designing interactive features to leverage VR technology to influence consumers’ decision-making. To address these challenges, this dissertation extends the heuristic-systematic model to investigate how VR interactivity influences visit intention through engaging experiences with technology …


The Impact Of Cognitive Coaching On High School English Teachers’ Implementation Of Metacognitve Reading Strategies, Charrai Hunter Apr 2023

The Impact Of Cognitive Coaching On High School English Teachers’ Implementation Of Metacognitve Reading Strategies, Charrai Hunter

Theses and Dissertations

The problem that this action research study addressed was the ineffective facilitation strategies used in professional development for teachers. The purpose of the study was to determine whether reflective practices impact teachers’ instructional decisions. The study used Cognitive Coaching, a reflective coaching model, as its intervention. To gather data the study used classroom observations, coaching conversations, and an eight-question structured survey administered at the end of the study. This qualitative case study included three high school English teachers as its participants and the study was conducted at two different high schools in a suburban school district in the Southeast. The …


An Investigative Analysis Of Fernando Sor’S Introduction And Variations On “O Cara Armonia” From Mozart’S The Magic Flute, Luke James Nolan Apr 2023

An Investigative Analysis Of Fernando Sor’S Introduction And Variations On “O Cara Armonia” From Mozart’S The Magic Flute, Luke James Nolan

Theses and Dissertations

Fernando Sor provides directions for fingering his Introduction and Variations on “O Cara Armonia” in the specific beaming and notation of the work. Although there are numerous publications of Sor’s Op. 9, most fail to provide elegant fingerings for his difficult passages. In these editions, the editor either failed to understand Sor’s intentions rendered in the notation, or disregarded Sor’s technical practices in favor of modern technical practices. Both avenues will lead to a disastrous reproduction of the work. While the piece may offer a challenge for the guitarist, the technical difficulties of Sor’s Op. 9 should not be readily …


Exploration Into The Relationship Between Colitis And Depression: A Potential Role For The Aryl Hydrocarbon Receptor, Kasie Lynn Roark Apr 2023

Exploration Into The Relationship Between Colitis And Depression: A Potential Role For The Aryl Hydrocarbon Receptor, Kasie Lynn Roark

Theses and Dissertations

Inflammatory Bowel Disease (IBD) is a group of chronic gastrointestinal disorders with unclear etiology comprised of two defined disorders – Crohn’s Disease (CD) and Ulcerative Colitis (UC). IBD leads to chronic pain, socially isolating symptoms, and an overall reduction in patient quality of life. There is currently no cure for IBD. Due to decreased mucous production and weakening of the colonic epithelial lining, gut-microbiota and their metabolites can invade the intestinal lamina propria and circulate systemically, a term known as “leaky gut”. Recent studies show a relationship exists between peripheral inflammation, such as IBD, and depression. The gut-brain axis (GBA) …


Appalachian Dreams: Traditional Folk Songs In Concert Literature For Classical Guitar, Jackson Douglas Roberson Apr 2023

Appalachian Dreams: Traditional Folk Songs In Concert Literature For Classical Guitar, Jackson Douglas Roberson

Theses and Dissertations

Transcriptions and arrangements of works for other instruments make up a substantial portion of the concert literature for the classical guitar. Additionally, the classical guitar’s connections with folk music traditions from around the world are undeniable. While much of the folk-inspired repertoire for guitar engages with the musical traditions of Spain and Latin America, this document will examine a work for solo guitar that uses traditional Appalachian folk music as source material: John Duarte’s Appalachian Dreams.

Appalachian folk music is a primarily oral tradition, and documentation of the music did not appear until the late nineteenth century. This project …


The Effects Of Hip-Hop And Rap Music Intervention To Improve The Wellbeing Of Black And African American Men, Lanita Michelle Jefferson Apr 2023

The Effects Of Hip-Hop And Rap Music Intervention To Improve The Wellbeing Of Black And African American Men, Lanita Michelle Jefferson

Theses and Dissertations

Wellbeing affects an individual’s functioning regarding personal, interpersonal, social, and overall wellbeing (Tennant et al., 2007). This study investigated the wellbeing of mental health among African American college-aged men by reading hip-hop and rap lyrics (Gonzalez & Hayes, 2009). The study explored the effects of reading hip-hop and rap lyrics on Black and African American college-aged men's wellbeing. Through peer review articles, this study investigated the effects of reading hip-hop and rap lyrics on the wellbeing of Black and African American college-aged men. The researcher identified the lack of research on wellbeing and marginalized communities, specifically Black and African American …


Dust Production And Transport In A Long-Lived Fluvial-Eolian System In The Pampas Of South America, Blake Marcus Stubbins Apr 2023

Dust Production And Transport In A Long-Lived Fluvial-Eolian System In The Pampas Of South America, Blake Marcus Stubbins

Theses and Dissertations

Wind-blown dust from southern South America links the terrestrial, marine, atmospheric, and biologic components of Earth’s climate system. The Pampas of central Argentina (~33-40° S) contain an extensive upper Miocene to Holocene eolian record that spans the relatively warm conditions of the Late Miocene to cooler climates of the Plio-Pleistocene and Holocene. We collected 13 loess, paleosol, and fluvial samples from the upper Miocene Cerro Azul and Rio Negro Formations which resulted in n = 5129 new detrital zircon U-Pb ages. Late Miocene rivers conveyed sediment from northern Patagonia, the Andes adjacent to the Pampas, and the Sierras Pampeanas to …


Comprehensive Process Planning Optimization Framework For Automated Fiber Placement, Alex Ryan Brasington Apr 2023

Comprehensive Process Planning Optimization Framework For Automated Fiber Placement, Alex Ryan Brasington

Theses and Dissertations

Advanced composite materials came about in 1966 and have since been widely used due to the possibility of superior structural performance while also achieving weight reductions. Such opportunities have led to composite materials being used to fabricate complex components, often in the aerospace sector. Most components, especially in aviation, are on a large scale and are outside the capabilities of traditional composite manufacturing techniques. Traditional manufacturing methods are also labor intensive, time consuming, have a high level of material scrap, and are prone to human error. This has led to the need for innovative manufacturing solutions to withstand the ever-increasing …


Genetic Mechanisms Underlying Maladaptation In Specialized Species Interactions, Nitin Ravikanthachari Apr 2023

Genetic Mechanisms Underlying Maladaptation In Specialized Species Interactions, Nitin Ravikanthachari

Theses and Dissertations

Adaptation has been used as the framework to understand the power of natural selection in structuring biodiversity and driving biological interactions. However, recent examples have indicated that many organisms are maladapted to their local conditions. Maladaptation can result from various causes including rapid environmental change, novel environments, interplay of evolutionary forces (viz: gene flow-selection balance) and anthropogenic disturbance.

To dissect the genetic mechanisms underlying maladaptation, I used the interaction between Pieris macdunnoughii (Remington) (Lepidoptera: Pieridae) which lays eggs on an invasive mustard Thlaspi arvense (L.) (Brassicaceae), which is lethal to the larvae.

First, local adaptation to avoid laying eggs on …


Complex Stereotypes: Stereotypes Across The Intersections Of Gender, Sexuality, Age, Race/Ethnicity, And Social Class, Nicholas Heiserman Apr 2023

Complex Stereotypes: Stereotypes Across The Intersections Of Gender, Sexuality, Age, Race/Ethnicity, And Social Class, Nicholas Heiserman

Theses and Dissertations

Research on stereotypes and their consequences often focuses on discrete categorical stereotypes in isolation from each other (e.g. gender or race categories), and rarely centers the fact that people belong to many social categories at once (e.g. gender and race categories). I address this issue using two large factorial experiment (N=1,762 and N=1,481) designed to measure two core aspects of stereotypes, warmth and competence, across the intersections of multiple social categories: Gender, Sexuality, Age, Race/Ethnicity (Chapter 3), and Social Class (Chapter 2). In Chapter 2, I develop a framework for analyzing intersectional complexity in these data, beginning with overall measures …


A Holistic View Of Integrated Care Within Counselor Education: A Multi-Manuscript Dissertation, Alexander Mcclain Fields Apr 2023

A Holistic View Of Integrated Care Within Counselor Education: A Multi-Manuscript Dissertation, Alexander Mcclain Fields

Theses and Dissertations

The integration of behavioral health into primary care settings, otherwise known as integrated care (IC), is a movement growing in momentum and continues to challenge traditional healthcare occurring in silos. Through an IC modality, healthcare consumers receive all their care through a “one stop shop” approach and previous outcomes have suggested an overall benefit for an individual’s holistic health, as well as savings for healthcare settings. Counselors are in a prime position to join IC teams and contribute to consumer healthcare outcomes through a unique professional identity. The aim of this dissertation study, which consisted of three completed manuscripts, was …


Empowering People Who Are Homeless Or Upholding A Double Standard: Homeless Shelter Regulations, Marcie Murtha Apr 2023

Empowering People Who Are Homeless Or Upholding A Double Standard: Homeless Shelter Regulations, Marcie Murtha

University of the Pacific Law Review

No abstract provided.


Curbing Quotas: How Chapter 197 Empowers California’S Warehouse Workers, Abigail Palmquist Apr 2023

Curbing Quotas: How Chapter 197 Empowers California’S Warehouse Workers, Abigail Palmquist

University of the Pacific Law Review

No abstract provided.


Working Hard And Hardly Earning: Ab 2932 And The Need To Empower Labor, Adam D. Nir Apr 2023

Working Hard And Hardly Earning: Ab 2932 And The Need To Empower Labor, Adam D. Nir

University of the Pacific Law Review

No abstract provided.


Independent - Apr. 1, 2023, Monty Stites Apr 2023

Independent - Apr. 1, 2023, Monty Stites

The Independent (1988-present)

No abstract provided.


Factors Associated With Knowledge And Experience Of Self-Managed Abortion Among Patients Seeking Care At 49 Us Abortion Clinics, Abigail R.A. Aiken, Luisa Alejandra Tello-Pérez, Melissa Madera, Jennifer E. Starling, Dana M. Johnson, Kathleen Broussard, Elisa Padron, Carol Armelle Ze-Noah, Aleta Baldwin, James G. Scott Apr 2023

Factors Associated With Knowledge And Experience Of Self-Managed Abortion Among Patients Seeking Care At 49 Us Abortion Clinics, Abigail R.A. Aiken, Luisa Alejandra Tello-Pérez, Melissa Madera, Jennifer E. Starling, Dana M. Johnson, Kathleen Broussard, Elisa Padron, Carol Armelle Ze-Noah, Aleta Baldwin, James G. Scott

Faculty Publications

IMPORTANCE Patients attending US abortion clinics may consider or try self-managing their abortion before coming to the clinic, yet little is known about the factors associated with self-management behavior.

OBJECTIVE To examine the prevalence and factors associated with considering or attempting a self-managed abortion before attending a clinic.

DESIGN, SETTING, AND PARTICIPANTS This survey study included patients obtaining an abortion at 49 independent, Planned Parenthood, and academic-affiliated clinics chosen to maximize diversity in geographic, state policy, and demographic context in 29 states between December 2018 and May 2020. Data were analyzed from December 2020 to July 2021.

EXPOSURES Obtaining an …


Quantifying Oil And Gas Industry Related Geohazard Using Radar Interferometry And Hydro-Geomechanical Modeling, Weiyu Zheng Apr 2023

Quantifying Oil And Gas Industry Related Geohazard Using Radar Interferometry And Hydro-Geomechanical Modeling, Weiyu Zheng

Earth Sciences Theses and Dissertations

The Permian Basin, containing a large amount of oil and gas, has been intensively developed for hydrocarbon production. However, the hazards related to the oil and gas industry including surface deformation and the underlying mechanisms in this region have not been well known. My PhD study aims to monitor the geohazards in the Permian Basin and better comprehend the subsurface mechanisms with the aid of high-resolution and high-accuracy Interferometric Synthetic Aperture Radar (InSAR) images. Generally, as the pore pressure is influenced by wastewater injection/hydrocarbon production, the pressure changes can propagate to other surrounding underground and overlying rock/soil layers, resulting in …


Transfer Learning, Model Interpretation, And Dataset Bias Analysis For Automated Violence Detection From Video, Erik Clemens Apr 2023

Transfer Learning, Model Interpretation, And Dataset Bias Analysis For Automated Violence Detection From Video, Erik Clemens

Master's Theses (2009 -)

Many communities have installed surveillance cameras in an effort to deter and respond to violence.Due to the difficulty of constantly monitoring such camera feeds, these systems are rarely used to provide real-time information. To enable rapid alerts and information for first responders, this thesis develops a proof-of-concept system capable of automatically detecting violence from video footage. This system is developed by fine-tuning a convolutional neural network that has previously demonstrated success on general action recognition tasks. This thesis explores two new techniques to improve the accuracy of the fine-tuned model. The first is a data augmentation technique that generates aspect …


The Rise Of Machine Learning In Polymer Discovery, Cheng Yan, Guoqiang Li Apr 2023

The Rise Of Machine Learning In Polymer Discovery, Cheng Yan, Guoqiang Li

Faculty Publications

In the recent decades, with rapid development in computing power and algorithms, machine learning (ML) has exhibited its enormous potential in new polymer discovery. Herein, the history of ML is described and the basic process of ML accelerated polymer discovery is summarized. Next, the four steps in this process are reviewed, that is, dataset selection, fingerprinting, ML framework, and new polymer generation. Finally, a couple of main challenges for ML accelerated polymer discovery is presented and the outlooks in this field are prospected. It is expected that this review can service as a useful tool for the people who just …


Amplifying Marginal Voices Of The Global Movement For Deeper Learning: A Case Study Of A Rural K-12 Mission School In Cambodia, Mark Peter L. Lopez S.J. Apr 2023

Amplifying Marginal Voices Of The Global Movement For Deeper Learning: A Case Study Of A Rural K-12 Mission School In Cambodia, Mark Peter L. Lopez S.J.

LMU Theses and Dissertations

Several paradigms have been developed to define what constitutes deeper learning, how to foster it, and what desired outcomes or competencies can result from it. Much of the literature, however, has been based on studies in economically developed Western countries. There has been little, if any, that is based on developing country settings where culture and context can account for differences in the manner of promoting deeper learning. This qualitative case study explored the experiences of learners in the Mudita Mission School (MMS; pseudonym), a K-12 school in a rural part of northern Cambodia, and investigated how deeper learning was …


Securities And Exchange Commission Vs. Kim Kardashian, Cryptocurrencies And The "Major Questions Doctrine", Jerry W. Markham Apr 2023

Securities And Exchange Commission Vs. Kim Kardashian, Cryptocurrencies And The "Major Questions Doctrine", Jerry W. Markham

William & Mary Business Law Review

The SEC has brought some highly publicized enforcement actions against Kim Kardashian and other celebrity social media influencers who received undisclosed payments for their endorsement of cryptocurrencies. This Article describes those cases and analyzes whether the SEC exceeds its authority under the Constitutional “major questions doctrine” recently applied by the Supreme Court in West Virginia v. EPA. That doctrine prohibits a federal agency from regulating activities that raise a major question that Congress, rather than the agency, must resolve. Such a question is one in which there is major political and economic interest and over which the agency has …


The Ai Quid Pro Quo Problem: Suggesting A Framework For Patents Involving Artificial Intelligence-Assisted Or -Created Inventions, Daniel Wicklund Apr 2023

The Ai Quid Pro Quo Problem: Suggesting A Framework For Patents Involving Artificial Intelligence-Assisted Or -Created Inventions, Daniel Wicklund

William & Mary Business Law Review

Innovation involving artificial intelligence (AI) is rapidly expanding and diffusing into other areas of technology. Additionally, inventors have been using AI to assist in new technology for quite a while and have likely received patents from the United States Patent and Trademark Office (USPTO or “Office”) for their inventions without disclosing the AI involved in the patentable subject matter. As AI has become increasingly present in the implementation of new technology, the question of whether an AI can be an inventor has arisen. In Thaler v. Iancu and on appeal, the courts have affirmatively said no. However, this decision implicates …


No Equitable Relief: The Failings Of The Case Act To Protect Middle-Class Creatives From Copyright Infringement, Eliza James Unrein Apr 2023

No Equitable Relief: The Failings Of The Case Act To Protect Middle-Class Creatives From Copyright Infringement, Eliza James Unrein

William & Mary Business Law Review

Copyright law in the United States incentivizes creative activity for the public benefit by granting creators an exclusive right to control their original works. Many individuals and small businesses rely on this right and the protection of copyright law to build their reputations as artists, create a market for their work, and secure a livelihood for themselves and their families. When someone violates this right and infringes on these individuals’ and small businesses’ copyrights, the forum for seeking redress and preventing future infringement is a lawsuit in federal court. But bringing a copyright infringement claim in federal court is expensive. …


Book Review: Stick Figures Save The World: Drawing Simply To Share Jesus Well By Pam Arlund, Jason Lalonde Apr 2023

Book Review: Stick Figures Save The World: Drawing Simply To Share Jesus Well By Pam Arlund, Jason Lalonde

Great Commission Research Journal

No abstract provided.


Tribute To Professor Joan Shaughnessy, Alan M. Trammell, Joan M. Shaughnessy, Mary Z. Natkin, Brian C. Murchison, Mark H. Grunewald, Barry Sullivan, Michelle L. Drumbl Apr 2023

Tribute To Professor Joan Shaughnessy, Alan M. Trammell, Joan M. Shaughnessy, Mary Z. Natkin, Brian C. Murchison, Mark H. Grunewald, Barry Sullivan, Michelle L. Drumbl

Washington and Lee Law Review

A tribute to Professor Joan Shaughnessy, who served on the faculty of the Washington and Lee University School of Law from 1983 to 2022. A recognized scholar and teacher in areas of civil procedure, federal courts, evidence, family law, and poverty law, Shaun was appointed as W&L's inaugural Roger D. Groot Professor of Law in 2012.